A medication disposal apparatus and method of use with multiple stages of conversion operable to render a controlled substance useless.

A medication disposal apparatus and method of use with multiple stages of conversion operable to render a controlled substance useless.

A dithiocarbamate functionalized dendrimer with an alkylenediamine core, a dithiocarbamate pendant functional group and a dithiocarbamate end functional group, as a soil heavy metal immobilization amendment, and a preparation method thereof are provided. The dithiocarbamate functionalized dendrimer has a chemical formula of (CH.sub.2).sub.a{N[CH.sub.2CH.sub.2COOCH.sub.2C(C.sub.2H.sub.5)(CH.sub.2OCOCH.sub.2CH.sub.2N(CSSM)CH.sub.2(CH.sub.2).sub.bCH.sub.2N(CSS M).sub.2).sub.2].sub.2}.sub.2, wherein a is a positive integer larger than 2; b is a positive integer at a range of 0-4; and M is Na.sup.+, NH.sub.4.sup.+ or K.sup.+. The dithiocarbamate functionalized dendrimer with the alkylenediamine core is used for an in-suit immobilization remediation for soil contaminated by heavy metals, and has advantages of a small dosage, high efficiency, safety and rapidness. The dendrimer is able to effectively immobilize exchangeable and carbonated bound forms of the heavy metals, in such a manner that the immobilized heavy metals are able to resist an influence from natural environment for a long term, such as an acid rain.

A treatment method for coal fly ash, and in particular sodic fly ash, comprises 1) contacting the coal fly ash with anhydrite, and 2) contacting the coal fly ash in the presence of water with at least one additive. The material obtained from the contacting steps (1) and (2) may be dried. The steps (1) and (2) may be carried simultaneously or sequentially. The additive may comprise at least one component selected from the group consisting of strontium-containing compounds, barium-containing compounds, dolomite, a dolomite derivative such as calcined or hydrated dolomite, water-soluble sources of silicate such as sodium or potassium silicate, iron-containing compounds, and any combinations thereof. A particularly preferred additive comprises sodium silicate. The method may be effective in reducing the sodium content in the fly ash (Na.sub.2O), reducing the alkalinity of the fly ash, and/or stabilizing at least one heavy metal such as selenium and/or arsenic to reduce their leachability.

A treatment method for coal fly ash, and in particular sodic fly ash, comprises 1) contacting the coal fly ash with anhydrite, and 2) contacting the coal fly ash in the presence of water with at least one additive. The material obtained from the contacting steps (1) and (2) may be dried. The steps (1) and (2) may be carried simultaneously or sequentially. The additive may comprise at least one component selected from the group consisting of strontium-containing compounds, barium-containing compounds, dolomite, a dolomite derivative such as calcined or hydrated dolomite, water-soluble sources of silicate such as sodium or potassium silicate, iron-containing compounds, and any combinations thereof. A particularly preferred additive comprises sodium silicate. The method may be effective in reducing the sodium content in the fly ash (Na.sub.2O), reducing the alkalinity of the fly ash, and/or stabilizing at least one heavy metal such as selenium and/or arsenic to reduce their leachability.

One method of treating incinerated waste comprises: size separating at least some of the incinerated waste into a first undersize fraction comprising particles smaller than the first separation size and into a first oversize fraction comprising particles larger than the first separation size; size reducing at least some of the first oversize fraction; size separating at least some of the size-reduced first oversize fraction into a second undersize fraction comprising particles smaller than the second separation size and into a second oversize fraction comprising particles larger than the second separation size; combining at least some of the first undersize fraction and at least some of the second undersize fraction into a fine fraction; and extracting metal from at least some of the fine fraction. Another method of treating incinerated waste comprises extracting metal by froth flotation from at least some of the incinerated waste. Systems are also disclosed.

One method of treating incinerated waste comprises: size separating at least some of the incinerated waste into a first undersize fraction comprising particles smaller than the first separation size and into a first oversize fraction comprising particles larger than the first separation size; size reducing at least some of the first oversize fraction; size separating at least some of the size-reduced first oversize fraction into a second undersize fraction comprising particles smaller than the second separation size and into a second oversize fraction comprising particles larger than the second separation size; combining at least some of the first undersize fraction and at least some of the second undersize fraction into a fine fraction; and extracting metal from at least some of the fine fraction. Another method of treating incinerated waste comprises extracting metal by froth flotation from at least some of the incinerated waste. Systems are also disclosed.

A batch process of remediation of soil and sediment contaminated with toxic metals includes the steps of treating contaminated soil and sediment with a solution containing aminopolycarboxylic chelating agent, rinsing the soil/sediment solid phase to remove residues of mobilized toxic metals, treating the used process waters to recycle chelating agent and clean process solutions and placing the remediated soil/sediment on a permeable horizontal reactive barrier to prevent emission of contaminants. In the batch process, toxic metals are removed from process solutions by alkaline adsorption of polysaccharide adsorbents. By applying alkaline adsorption the efficiency of toxic metal removal from process solutions and alkaline and acidic recycling of chelating agent is significantly improved.

A treatment method for stabilizing at least a portion of at least one heavy metal contained in a sodic fly ash to reduce leachability, wherein the sodic fly ash is provided by a process whereby a sodium-based sorbent is injected in a combustion flue gas to remove pollutants therefrom. The treatment method comprises contacting the sodic fly ash with at least one water-soluble source of silicate and at least one additive comprising calcium and/or magnesium. The material obtained from the contacting step is preferably dried. The additive may be selected from the group consisting of lime kiln dust, fine limestone, quicklime, hydrated lime, dolomitic lime, dolomite, selectively calcined dolomite, hydrated dolomite, magnesium hydroxide, magnesium carbonate, magnesium oxide, and any mixture thereof. A particularly preferred additive comprises lime kiln dust and/or dolomitic lime. The heavy metal to be stabilized in the sodic fly ash may comprise selenium and/or arsenic.

A treatment method for stabilizing at least a portion of at least one heavy metal contained in a sodic fly ash to reduce leachability, wherein the sodic fly ash is provided by a process whereby a sodium-based sorbent is injected in a combustion flue gas to remove pollutants therefrom. The treatment method comprises contacting the sodic fly ash with at least one water-soluble source of silicate and at least one additive comprising calcium and/or magnesium. The material obtained from the contacting step is preferably dried. The additive may be selected from the group consisting of lime kiln dust, fine limestone, quicklime, hydrated lime, dolomitic lime, dolomite, selectively calcined dolomite, hydrated dolomite, magnesium hydroxide, magnesium carbonate, magnesium oxide, and any mixture thereof. A particularly preferred additive comprises lime kiln dust and/or dolomitic lime. The heavy metal to be stabilized in the sodic fly ash may comprise selenium and/or arsenic.