Methods are provided for the removal of sulfur and other ARD/AMD-generating materials through the smoldering combustion of an organic material. The methods comprise admixing an ARD/AMD-generating porous matrix material with an organic material to produce a mixture, exposing the mixture to an oxidant, and initiating a self-sustaining smoldering combustion of the mixture. Additional embodiments aggregate the organic material or ARD/AMD-generating porous matrix material or mixture thereof in an impoundment such as a reaction vessel, depression or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

Methods are provided for the removal of sulfur and other ARD/AMD-generating materials through the smoldering combustion of an organic material. The methods comprise admixing an ARD/AMD-generating porous matrix material with an organic material to produce a mixture, exposing the mixture to an oxidant, and initiating a self-sustaining smoldering combustion of the mixture. Additional embodiments aggregate the organic material or ARD/AMD-generating porous matrix material or mixture thereof in an impoundment such as a reaction vessel, depression or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

Provided is a method of asbestos detoxification including: preparing asbestos which is a treatment target for detoxification and carbon dioxide; and pressing the asbestos and the carbon dioxide with a pressure of 1 to 5 GPa and treating the asbestos and the carbon dioxide at a temperature of 100 to 250° C., wherein since the asbestos is not subjected to chemical pre-treatment, as compared to the existing technologies in which the chemical pre-treatment is necessary, treatment cost may be reduced, and another concern for environmental contamination may be prevented in advance, and accordingly, the asbestos is appropriate for recycling through detoxification as well as waste treatment.

Provided is a method of asbestos detoxification including: preparing asbestos which is a treatment target for detoxification and carbon dioxide; and pressing the asbestos and the carbon dioxide with a pressure of 1 to 5 GPa and treating the asbestos and the carbon dioxide at a temperature of 100 to 250° C., wherein since the asbestos is not subjected to chemical pre-treatment, as compared to the existing technologies in which the chemical pre-treatment is necessary, treatment cost may be reduced, and another concern for environmental contamination may be prevented in advance, and accordingly, the asbestos is appropriate for recycling through detoxification as well as waste treatment.

A reagent system for treating heavy metal-contaminated materials is provided and includes an oxidizer, a soluble phosphate, and an alkaline hydroxide source, such as a caustic soda or lime. A method of treating mine waste bearing one or more heavy metals is also provided and includes the step of admixing a reagent system with heavy metal-containing material to preferentially reduce the leachability of heavy metals and form precipitates and complexes of low metal solubility that remain stable within the host solid matrix for long durations in acidic and abrasive conditions.

A reagent system for treating heavy metal-contaminated materials is provided and includes an oxidizer, a soluble phosphate, and an alkaline hydroxide source, such as a caustic soda or lime. A method of treating mine waste bearing one or more heavy metals is also provided and includes the step of admixing a reagent system with heavy metal-containing material to preferentially reduce the leachability of heavy metals and form precipitates and complexes of low metal solubility that remain stable within the host solid matrix for long durations in acidic and abrasive conditions.

Disclosed are stable zero-valent metal and oxidized black carbon admixtures and their use, to catalyze rapid reductive degradation reactions in aqueous solutions. The compositions and remediation methods are used in the non-explosive neutralization and decomposition of ammonium nitrate.

Disclosed herein is a method of remediating chromated copper arsenate (CCA) treated timber. Particularly, the method comprises contacting the CCA timber with an oxidative solvent and an acidic solvent which provides remediated timber and a variety of extracts containing amongst other things the metals of concern. One or more of the steps is conducted using continuous counter current extraction (CCE).

Disclosed herein is a method of remediating chromated copper arsenate (CCA) treated timber. Particularly, the method comprises contacting the CCA timber with an oxidative solvent and an acidic solvent which provides remediated timber and a variety of extracts containing amongst other things the metals of concern. One or more of the steps is conducted using continuous counter current extraction (CCE).

An asbestos waste neutralization device, that includes an acid tank and a vat containing a diluted acid solution, in which waste containing asbestos is dipped, the diluted acid solution neutralizing the waste containing asbestos during a neutralization reaction. The device further includes a filtration unit to separate, at the end of the neutralization reaction, solid inert waste from a liquid phase of the acid solution, and a regeneration unit for the liquid phase of the acid solution, which adjusts the hydrogen potential of the liquid phase of the acid solution by adding concentrated acid contained in the acid tank. In addition, the device includes an attenuation sensor for regenerated liquid phase of the acid solution from the regeneration unit, and a selective precipitation unit for the regenerated liquid phase of the acid solution, depending on the degree of attenuation the attenuation sensor senses.