The present invention relates to a CLC and operation method thereof equipped with a loop seal separator using magnetic oxygen carrier particles and a magnetic separator. And more particularly, the present invention relates to a loop seal separator using magnetic oxygen carrier particles and a magnetic separator, wherein the loop seal separator comprises a duct into which the ash and magnetic oxygen carrier particles, discharged from a reducer, flow; a magnetic separator to separate the ash from the magnetic oxygen carrier particles, flowing into the duct, by magnetic material; an ash discharge pipe to discharge the ash, separated by the magnetic separator; and an oxygen-carrier-particle discharge pipe to encourage the magnetic oxygen carrier particles, separated by the magnetic separator, to flow into an oxidizer.

A carbonaceous feed pyrolysis apparatus is provided including two or more hot particle fluidised beds, one of which contains a combustion zone, and one or more positive displacement apparatus for the transfer of hot particles beds. Also provided is a bio-oil production process including two or more fluidised beds, a first combustion zone carried out in one or more combustion fluidised beds in which a particulate material is fluidised and heated, and a second pyrolysis zone carried out in one or more pyrolysis fluidised beds in which hot particles heated in the combustion zone are used for pyrolysis of bio-mass, the combustion zone being operated at or about atmospheric pressure at a temperature of from 400 C. to 1100 C., and the pyrolysis zone being operated at a pressure of from atmospheric to 100 Barg at a temperature of from 400 C. to 900 C.

A method and apparatus for heating a furnace using a burner system having first and second burner assemblies, each including a burner and a regenerative media bed, the method including operating the first burner assembly in a firing mode and the second burner assembly in a regeneration mode, switching the first burner assembly from the firing mode to the regeneration mode and the second burner assembly from the regeneration mode to the firing mode, and operating the second burner assembly in the firing mode and the first burner assembly in the regeneration mode. The burner assembly in the firing mode may be fired in either a first operating mode where the burner is supplied with preheated low calorific fuel and the burner is supplied with oxidizing gas or a second operating mode where the burner is supplied with preheated oxidizing gas and the burner is supplied with high calorific fuel.

The invention provides an apparatus which consists of two fluidized beds 1 and 2 separated by a vertical divides' 5. A positive displacement device such as an auger 3 moves the bed material from the reduction side to the combustion side of the device below the fluidization zone. The height of the two fluidized beds is equalized by movement of the bed material through a hole 4 In the vertical divider, from the high temperature side 1 (zone 1) to the tow temperature side 2 (zone 2). The bed material that moves through the hole 4 provides energy to drive reactions that may occur on the reduction side. Energy may also be provided to zone 2 by means of conductive and radiative heat transfer through the dividing wall 5. Energy is provided to zone 1 by means of an exothermic reaction, typically combustion of a fuel 13 using air 12.

The invention concerns a CLC process, and its installation, producing high purity dinitrogen, comprising:

(a) the combustion of a hydrocarbon feed by reduction of a redox active mass brought into contact with the feed,
(b) a first step for oxidation of the reduced active mass (25) obtained from step (a) in contact with a fraction of a depleted air stream (21b), in order to produce a high purity stream of dinitrogen (28) and a stream of partially re-oxidized active mass (26);
(c) a second step for oxidation of the stream of active mass (26) in contact with air (20) in order to produce a stream of depleted air and a stream of re-oxidized active mass (24) for use in step (a);
(d) dividing the stream of depleted air obtained at the end of step (c) in order to form the fraction of depleted air used in step (b) and a fraction complementary to the depleted air extracted from the CLC.

A method for recapturing sulfur in a chemical looping system includes receiving a flue gas stream containing a sulfur-containing species, reducing a temperature of the flue gas stream, introducing a calcium-based makeup material to the reduced temperature flue gas stream, capturing the sulfur-containing species from the reduced temperature flue gas stream, and recycling the sulfur-containing species to a reducer of the chemical looping system.

A method and apparatus for treatment of unburnts utilizing oxygen carrier particles, which may be CLOU particles, oxidized in an air reactor and transmitted to a post oxidation reactor as shown in FIG. 2. A flue gas stream containing unburnts is injected into post oxidation reactor wherein unburnts are oxidized by oxygen supplied by oxygen carriers. Reduced oxygen carriers are separated from post oxidation reactor and transmitted back to air reactor for re-oxidation. An embodiment may include a post oxidation chamber, which may be catalytic, receiving a portion of flue gas stream and oxygen from a flue gas stream of post oxidation reactor.

A dual-bed system for preventing a boiler heating surface from being contaminated comprises a fluidized bed, a cyclone separator, a coal ash distributor, an ash-coal mixer, a lower pyrolysis bed, a return feeder and a cleaner, wherein the cyclone separator is connected with the upper lateral side of the fluidized bed; the inlet end of the coal ash distributor; the two outlets of the coal ash distributor are respectively connected with the inlet of the return feeder and the inlet of the ash-coal mixer; the outlet of the ash-coal mixer is connected with the inlet of the lower pyrolysis bed; the return feeder close to the lower lateral side of the fluidized bed is connected with the inlet on the lower lateral side of the fluidized bed; and the outlet of the cleaner is connected with the inlet on the lower lateral side of the fluidized bed.

The object of the invention is a combustion method for a solid feed using a chemical loop wherein an oxygen-carrying material circulates, said method comprising at least: contacting the solid feed particles in the presence of metallic oxide particles in a first reaction zone (R1) operating in dense fluidized bed mode, carrying out combustion of the gaseous effluents from first reaction zone (R1) in the presence of metallic oxide particles in a second reaction zone (R2), separating in a separation zone (S3) the unburnt particles and the metallic oxide particles within a mixture coming from second reaction zone (R2), re-oxidizing the metallic oxide particles in an oxidation zone (R4) prior to sending them back to first zone (R1).

A system for converting fuel may include a first moving bed reactor, a second reactor, and a non-mechanical valve. The first moving bed reactor may include at least one tapered section and multiple injection gas ports. The multiple injection gas ports may be configured to deliver a fuel to the first moving bed reactor. The first moving bed reactor may be configured to reduce an oxygen carrying material with a fuel by defining a countercurrent flowpath for the fuel relative to the oxygen carrying material. The second reactor may communicate with the first moving bed reactor and may be operable to receive an oxygen source. The second reactor may be configured to regenerate the reduced oxygen carrying material by oxidation.