The present invention concerns a combustion reactor (300) for chemical looping combustion (CLC) configured to operate in a fluidised bed, comprising: a lower chamber (320) forming a first reaction zone for the combustion of a hydrocarbon feedstock in the presence of particles of an oxidation-reduction active mass, comprising a first side wall and being configured to include a dense fluidised bed; an elongate upper chamber (340) with smaller passage cross-section than that of the lower chamber, forming a second reaction zone for the combustion of gaseous effluents originating from the combustion in the lower portion, comprising a second side wall and being configured to include a dilute fluidised bed; an intermediate portion (330) connecting the two chambers, and including an inner wall forming a right angle with the side walls of the two chambers. The invention also relates to the facility and the CLC process incorporating such a reactor (300).

The present invention concerns a combustion reactor (300) for chemical looping combustion (CLC) configured to operate in a fluidised bed, comprising: a lower chamber (320) forming a first reaction zone for the combustion of a hydrocarbon feedstock in the presence of particles of an oxidation-reduction active mass, comprising a first side wall and being configured to include a dense fluidised bed; an elongate upper chamber (340) with smaller passage cross-section than that of the lower chamber, forming a second reaction zone for the combustion of gaseous effluents originating from the combustion in the lower portion, comprising a second side wall and being configured to include a dilute fluidised bed; an intermediate portion (330) connecting the two chambers, and including an inner wall forming a right angle with the side walls of the two chambers. The invention also relates to the facility and the CLC process incorporating such a reactor (300).

The invention relates to a method for starting up a fluidized bed boiler, such as a circulating fluidized bed (CFB) or a bubbling fluidized bed (BFB) boiler, for operation with a predetermined concentration of ilmenite particles in the bed material. The invention also relates to a method for pre-oxidizing ilmenite, to pre-oxidized ilmenite and to the use of pre-oxidized ilmenite in a fluidized bed boiler.

The invention relates to a method for starting up a fluidized bed boiler, such as a circulating fluidized bed (CFB) or a bubbling fluidized bed (BFB) boiler, for operation with a predetermined concentration of ilmenite particles in the bed material. The invention also relates to a method for pre-oxidizing ilmenite, to pre-oxidized ilmenite and to the use of pre-oxidized ilmenite in a fluidized bed boiler.

The invention relates to a method for operating a fluidized bed boiler, comprising: a) setting the ratio of secondary oxygen containing gas to primary oxygen containing fluidizing gas to a value ranging from 0.0 to 0.8; b) carrying out the combustion of fuel with a fluidized bed comprising ilmenite particle; and to a fluidized bed boiler.

The invention relates to a method for operating a fluidized bed boiler, comprising: a) setting the ratio of secondary oxygen containing gas to primary oxygen containing fluidizing gas to a value ranging from 0.0 to 0.8; b) carrying out the combustion of fuel with a fluidized bed comprising ilmenite particle; and to a fluidized bed boiler.

Systems and methods for coupling a chemical looping arrangement and a supercritical CO.sub.2 cycle are provided. The system includes a fuel reactor, an air reactor, a compressor, first and second heat exchangers, and a turbine. The fuel reactor is configured to heat fuel and oxygen carriers resulting in reformed or combusted fuel and reduced oxygen carriers. The air reactor is configured to re-oxidize the reduced oxygen carriers via an air stream. The air stream, fuel, and oxygen carriers are heated via a series of preheaters prior to their entry into the air and fuel reactors. The compressor is configured to increase the pressure of a CO.sub.2 stream to create a supercritical CO.sub.2 stream. The first and second heat exchangers are configured to heat the supercritical CO.sub.2 stream, and the turbine is configured to expand the heated supercritical CO.sub.2 stream to generate power.

Systems and methods for coupling a chemical looping arrangement and a supercritical CO.sub.2 cycle are provided. The system includes a fuel reactor, an air reactor, a compressor, first and second heat exchangers, and a turbine. The fuel reactor is configured to heat fuel and oxygen carriers resulting in reformed or combusted fuel and reduced oxygen carriers. The air reactor is configured to re-oxidize the reduced oxygen carriers via an air stream. The air stream, fuel, and oxygen carriers are heated via a series of preheaters prior to their entry into the air and fuel reactors. The compressor is configured to increase the pressure of a CO.sub.2 stream to create a supercritical CO.sub.2 stream. The first and second heat exchangers are configured to heat the supercritical CO.sub.2 stream, and the turbine is configured to expand the heated supercritical CO.sub.2 stream to generate power.

The invention relates to a method for starting up a fluidized bed boiler, such as a circulating fluidized bed (CFB) or a bubbling fluidized bed (BFB) boiler, for operation with a predetermined concentration of ilmenite particles in the bed material. The invention also relates to a method for pre-oxidizing ilmenite, to pre-oxidized ilmenite and to the use of pre-oxidized ilmenite in a fluidized bed boiler.

The invention relates to a method for starting up a fluidized bed boiler, such as a circulating fluidized bed (CFB) or a bubbling fluidized bed (BFB) boiler, for operation with a predetermined concentration of ilmenite particles in the bed material. The invention also relates to a method for pre-oxidizing ilmenite, to pre-oxidized ilmenite and to the use of pre-oxidized ilmenite in a fluidized bed boiler.