A small-scale thermoelectric power generator and combustion apparatus, components thereof, methods for making the same, and applications thereof. The thermoelectric power generator can include a burner including a matrix stabilized combustion chamber comprising a catalytically enhanced, porous flame containment portion. The combustion apparatus can include components connected in a loop configuration including a vaporization chamber; a mixing chamber connected to the vaporization chamber; a combustion chamber connected to the vaporization chamber; and a heat exchanger connected to the combustion chamber. The combustion chamber can include a porous combustion material which can include a unique catalytic material.

A small-scale thermoelectric power generator and combustion apparatus, components thereof, methods for making the same, and applications thereof. The thermoelectric power generator can include a burner including a matrix stabilized combustion chamber comprising a catalytically enhanced, porous flame containment portion. The combustion apparatus can include components connected in a loop configuration including a vaporization chamber; a mixing chamber connected to the vaporization chamber; a combustion chamber connected to the vaporization chamber; and a heat exchanger connected to the combustion chamber. The combustion chamber can include a porous combustion material which can include a unique catalytic material.

Disclosed is an apparatus for conversion of ammonia into oxides of nitrogen which may comprise an adiabatic burner (108), a set of platinum/rhodium alloy catalytic gauzes (102A), (102B), and (102C), a waste heat recovery boiler (WHRB) (110), an absorption tower (302A), (302B), (302C), (302D) and (302E), a NaOH tank (306) and a surge tank (304). Further, the adiabatic burner may be configured to carry out catalytic oxidation of air and ammonia, using catalytic gauzes (102A), (102B), and (102C) of platinum/rhodium alloy. Further, the mixture of air and ammonia may be selectively oxidized to oxides of nitrogen, which may be absorbed in an alkali medium in the absorption tower (302A), (302B), (302C), (302D) and (302E), to yield sodium nitrites and nitrates.

Disclosed is an apparatus for conversion of ammonia into oxides of nitrogen which may comprise an adiabatic burner (108), a set of platinum/rhodium alloy catalytic gauzes (102A), (102B), and (102C), a waste heat recovery boiler (WHRB) (110), an absorption tower (302A), (302B), (302C), (302D) and (302E), a NaOH tank (306) and a surge tank (304). Further, the adiabatic burner may be configured to carry out catalytic oxidation of air and ammonia, using catalytic gauzes (102A), (102B), and (102C) of platinum/rhodium alloy. Further, the mixture of air and ammonia may be selectively oxidized to oxides of nitrogen, which may be absorbed in an alkali medium in the absorption tower (302A), (302B), (302C), (302D) and (302E), to yield sodium nitrites and nitrates.

A scroll heating device includes a base, a reaction region, and a first and a second channel. The reaction region is at the center of the base. The two channels are located on the base and extend spirally from the reaction region toward the periphery of the base. The width of each channel is gradually reduced as the channel extends from adjacent to the center of the base toward the periphery of the base. The first channel allows a gas that flows into the first channel through the periphery of the base toward the center of the base to flow toward the reaction region at a progressively slower rate, enter the reaction region slowly through the gradually widening first channel, and therefore stay in the reaction region for longer. The combusted exhaust enters the second channel from adjacent to the center of the base and exits through the periphery of the base.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500° C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500° C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

The present disclosure provides a cerium-zirconium-based composite oxide with a core-shell structure and a preparation method thereof, a catalyst system using the cerium-zirconium-based composite oxide, a catalytic converter for purifying tail gas by using the catalyst system, and application of the catalyst system or the catalytic converter in motor vehicle exhaust purification, industrial waste gas treatment or catalytic combustion. In the present invention, the cerium-zirconium-based composite oxide with a core-shell structure oxygen storage material is prepared by a step-by-step precipitation method. On the one hand, yttrium and a part of zirconium and cerium are precipitated on a cerium-zirconium surface, where the post-precipitation of yttrium is to segregate yttrium ions (Y.sup.3+) on a grain boundary surface, thus reducing lattice surface energy, pinning the grain boundary surface, making the migration of the grain boundary surface difficult, controlling the growth of grains.

A scroll heating device includes a base, a reaction region, and a first and a second channel. The reaction region is at the center of the base. The two channels are located on the base and extend spirally from the reaction region toward the periphery of the base. The width of each channel is gradually reduced as the channel extends from adjacent to the center of the base toward the periphery of the base. The first channel allows a gas that flows into the first channel through the periphery of the base toward the center of the base to flow toward the reaction region at a progressively slower rate, enter the reaction region slowly through the gradually widening first channel, and therefore stay in the reaction region for longer. The combusted exhaust enters the second channel from adjacent to the center of the base and exits through the periphery of the base.

A micro-combustion device generating electrical power raises global performance of the system, is compact, and reduces losses by utilizing an induced helical path. The device includes: injection ducts inserting a combustion agent, a fuel and/or a mixture thereof wherein the injection of the combustion agent takes place tangentially to the internal cylindrical wall, inducing a helical combustion path, the internal cylindrical walls of the chamber having a deposition of catalytic material to accelerate the combustion reaction; a turbo compressor group, including a compressor, feeding under pressure the combustion chamber through the injection ducts, and a turbine, receiving the flue gases from the discharge duct, compressor and turbine being keyed on the same axis, whereon a generator of electrical power, in turn, is keyed; and a fuel cell, fed by the flue gases through the turbine and by an oxidizing agent, implementing an electrochemical process generating additional electrical power.