Processes and apparatus are described for removing impurities from solid biomass while preserving hydrogen and carbon content. Examples are provided of processes using acidified aqueous solutions in a countercurrent extraction process that includes the pneumatic transport of slurries between process units, or a mechanical dewatering step, or both, to produce a washed biomass suitable for various upgrading and conversion processes. Compositions related to the processes are also described.

Processes and apparatus are described for removing impurities from solid biomass while preserving hydrogen and carbon content. Examples are provided of processes using acidified aqueous solutions in a countercurrent extraction process that includes the pneumatic transport of slurries between process units, or a mechanical dewatering step, or both, to produce a washed biomass suitable for various upgrading and conversion processes. Compositions related to the processes are also described.

The system for processing waste includes both a fixed bed reactor and a fluidized bed reactor. The fixed bed reactor receives a first waste material and produces a first set of reaction products. The fluidized bed reactor is adapted for receiving a second waste material and producing a second set of reaction products. The first and second sets of reaction products may be selectively and adjustably mixed to produce a mixed set of reaction products. At least one cyclone separator receives the reaction products and separates and collects solids (waxes) from the product stream. At least one condenser receives the product stream and removes a condensable liquids from the product stream. The condensable liquids are collected, and a gas-liquid separator removes any remaining liquid from the gas stream. The remaining gas is then output as gaseous product.

The system for processing waste includes both a fixed bed reactor and a fluidized bed reactor. The fixed bed reactor receives a first waste material and produces a first set of reaction products. The fluidized bed reactor is adapted for receiving a second waste material and producing a second set of reaction products. The first and second sets of reaction products may be selectively and adjustably mixed to produce a mixed set of reaction products. At least one cyclone separator receives the reaction products and separates and collects solids (waxes) from the product stream. At least one condenser receives the product stream and removes a condensable liquids from the product stream. The condensable liquids are collected, and a gas-liquid separator removes any remaining liquid from the gas stream. The remaining gas is then output as gaseous product.

Disclosed is a system and method for the combustion of biomass material employing a swirling fluidized bed combustion (SFBC) chamber, and preferably a second stage combustion carried out in a cyclone separator. In the combustion chamber, primary air is introduced from a bottom air box that fluidizes the bed material and fuel, and staged secondary air is introduced in the tangential direction and at varied vertical positions in the combustion chamber so as to cause the materials in the combustion chamber (i.e., the mixture of air and particles) to swirl. The secondary air injection can have a significant effect on the air-fuel particle flow in the combustion chamber, and more particularly strengthens the swirling flow, promotes axial recirculation, increases particle mass fluxes in the combustion chamber, and retains more fuel particles in the combustion chamber. This process increases the residence time of the particle flow. The turbulent flow of the fuel particles and air is well mixed and mostly burned in the combustion chamber, with any unburned waste and particles being directed to the cyclone separator, where such unburned waste and particles are burned completely, and flying ash is divided and collected in a container connected to the cyclone separator, while dioxin production is significantly minimized if not altogether eliminated. A Stirling engine along with cooling system and engine control box is integrated with the SFBC chamber to produce electricity from the waste combustion process. Residual heat in the flue gas may be captured after the combustion chamber and directed to a fuel feeder to first dry the biomass. System exhaust is directed to a twisted tube-based shell and tube heat exchanger (STHE) and may produce hot water for space heating.

Disclosed is a system and method for the combustion of biomass material employing a swirling fluidized bed combustion (SFBC) chamber, and preferably a second stage combustion carried out in a cyclone separator. In the combustion chamber, primary air is introduced from a bottom air box that fluidizes the bed material and fuel, and staged secondary air is introduced in the tangential direction and at varied vertical positions in the combustion chamber so as to cause the materials in the combustion chamber (i.e., the mixture of air and particles) to swirl. The secondary air injection can have a significant effect on the air-fuel particle flow in the combustion chamber, and more particularly strengthens the swirling flow, promotes axial recirculation, increases particle mass fluxes in the combustion chamber, and retains more fuel particles in the combustion chamber. This process increases the residence time of the particle flow. The turbulent flow of the fuel particles and air is well mixed and mostly burned in the combustion chamber, with any unburned waste and particles being directed to the cyclone separator, where such unburned waste and particles are burned completely, and flying ash is divided and collected in a container connected to the cyclone separator, while dioxin production is significantly minimized if not altogether eliminated. A Stirling engine along with cooling system and engine control box is integrated with the SFBC chamber to produce electricity from the waste combustion process. Residual heat in the flue gas may be captured after the combustion chamber and directed to a fuel feeder to first dry the biomass. System exhaust is directed to a twisted tube-based shell and tube heat exchanger (STHE) and may produce hot water for space heating.

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

A ground supported power boiler is described combining a refractory lined and insulated conical floor; an insulated cylindrical combustion chamber; a cylindrical furnace with water tube wall; a rectangular convective section; a single vertical steam drum; tangential injection of the fuel and combustion air; means for fluidizing the fuel bed; means for selectively stripping particulates from the flue gases; multi-stage particulate stripping and filtering from flue gases, means for using the walls of steam drum as steam/water droplet separator, means for recirculating and capturing heat from the flue gases; means for pressurizing the interior of the boiler above atmospheric pressure; means for heating and drying fuel prior to feeding the fuel to the boiler; means for creating hydrogen shift reaction; means for eliminating any need for sootblowing; and designed to not require the use of an induced draft fan.

A ground supported power boiler is described combining a refractory lined and insulated conical floor; an insulated cylindrical combustion chamber; a cylindrical furnace with water tube wall; a rectangular convective section; a single vertical steam drum; tangential injection of the fuel and combustion air; means for fluidizing the fuel bed; means for selectively stripping particulates from the flue gases; multi-stage particulate stripping and filtering from flue gases, means for using the walls of steam drum as steam/water droplet separator, means for recirculating and capturing heat from the flue gases; means for pressurizing the interior of the boiler above atmospheric pressure; means for heating and drying fuel prior to feeding the fuel to the boiler; means for creating hydrogen shift reaction; means for eliminating any need for sootblowing; and designed to not require the use of an induced draft fan.