The present disclosure provides devices and methods for cleaning up or burning spills of burnable materials in situ. In some embodiments, a system for burning a burnable material comprises a base having a first side configured for placement on a surface with a burnable material and a second side; and a plurality heat conducting members extending from the second side of the base.

Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200? C. to 400? C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200? C. to 400? C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200 C. to 400 C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

Porous media containing undesired substances, e.g., perfluoroalkylated substances, are treated by mixing the porous media with a solid fuel comprising organic material. The mixture is heated to 200 C. to 400 C. to initiate smoldering combustion and an oxidizer gas is forced through the heated mixture such that the smoldering combustion is self-sustaining until the mixture reaches a PFAS destructive temperature and the perfluoroalkylated substances are thermally destroyed. A system is provided for conducting the treatment. The system includes a source of wax, wood chips, sawdust, tire scraps, waste rubber compounds, coal, granular activated carbon, solid fat, and combinations thereof as solid fuel. A mixer is provided for mixing the porous media with the solid fuel. An ignition system including static heating elements and a gas blower are provided for forcing heated oxidizer gas through the mixture such that self-sustaining smoldering combustion of the mixture is initiated and sustained.

A thermal desorption system for remediating contaminated material in a zero oxygen environment by heating a gas and flowing the heated gas through a core heating conduit traversing the interior of a material compartment of a bin filled with contaminated material, redirecting the flow of heated gas from the core heating conduit to a space between the exterior of the bin and the interior of a bin housing insulator encapsulating the bin to provide dual indirect heating to the contaminated material within the bin, directing off gases of contaminated vapors released by desorption from the material to an exhaust header through a plurality of vapor outlets, and condensing the offgas in the exhaust header.

A thermal desorption system for remediating contaminated material in a zero oxygen environment by heating a gas and flowing the heated gas through a core heating conduit traversing the interior of a material compartment of a bin filled with contaminated material, redirecting the flow of heated gas from the core heating conduit to a space between the exterior of the bin and the interior of a bin housing insulator encapsulating the bin to provide dual indirect heating to the contaminated material within the bin, directing off gases of contaminated vapors released by desorption from the material to an exhaust header through a plurality of vapor outlets, and condensing the offgas in the exhaust header.

A process for the remediation of contaminated particulate materials by the addition of an environmentally benign, carbonaceous fuel source in low concentration to enable or enhance smoldering combustion. The process may be applied to both in situ and ex situ treatments. In an ex situ smoldering process for the remediation of contaminated particulate materials in a continuous manner, contaminated feed is introduced near the top of a treatment unit and treated product emerges near the bottom. A smoldering front is maintained in the unit, fed by the fuel in the contaminated particulate material and a supply of combustion-supporting gas, such as air.

A process for the remediation of contaminated particulate materials by the addition of an environmentally benign, carbonaceous fuel source in low concentration to enable or enhance smoldering combustion. The process may be applied to both in situ and ex situ treatments. In an ex situ smoldering process for the remediation of contaminated particulate materials in a continuous manner, contaminated feed is introduced near the top of a treatment unit and treated product emerges near the bottom. A smoldering front is maintained in the unit, fed by the fuel in the contaminated particulate material and a supply of combustion-supporting gas, such as air.

A process for the remediation of contaminated particulate materials by the addition of an environmentally benign, carbonaceous fuel source in low concentration to enable or enhance smoldering combustion. The process may be applied to both in situ and ex situ treatments. In an ex situ smoldering process for the remediation of contaminated particulate materials in a continuous manner, contaminated feed is introduced near the top of a treatment unit and treated product emerges near the bottom. A smoldering front is maintained in the unit, fed by the fuel in the contaminated particulate material and a supply of combustion-supporting gas, such as air.