A process comprising the following steps: a) calcination of a metal carbonate by combustion of a fuel in the presence of a mixture of oxygen, water vapour and carbon dioxide, to generate a metal oxide, water vapour, carbon dioxide and heat; b) using the heat generated to drive an oxygen generation reaction; and c) use of the oxygen generated in step b) in calcination step a). The use of the process on carbon dioxide sequestration and/or in oxygen generation.

Systems/methods for continuous operation of fixed bed reactors using gaseous fuels for the purpose of power generation through integration with a combined cycle power plant are provided. The fixed bed reactors are assumed to operate in a semi-batch mode composed of reactor modules that are integrated into module trains that comprise the chemical-looping combustion island of the power plant. The scheduling of each reactor train is cast as an optimization problem that maximizes thermodynamic efficiency subject to constraints imposed to each reactor and the entire island. When the chemical-looping reactors are arranged cyclically, each feeding to or being fed from another reactor, in an operating scheme that mimics simulated moving bed reactors, the thermodynamic efficiency of the reactor island can be improved. Allowing the reversal of module order in the cyclically arranged reactor modules further improves the overall thermodynamic efficiency (to 84.7%), while satisfying constraints imposed for carbon capture, fuel conversion, power plant safety and oxygen carrier stability.

Disclosed herein is a fuel for use in a combustor of a gas turbine, wherein the fuel is a gas mixture that comprises hydrogen and exhaust gas from a total combustor.

An exhaust gas treatment device includes an exhaust gas line where a combustion exhaust gas discharged from a power generation facility flows through, an exhaust gas line where a second combustion exhaust gas discharged from a second power generation facility flows through, exhaust gas exhaust line disposed by branching off from exhaust gas line, discharging a part of combustion exhaust gases as exhaust combustion exhaust gases, a nitrogen oxide removing unit removing nitrogen oxide contained in an integrated combustion exhaust gas that integrates the combustion exhaust gases, an integrated waste heat recovery boiler recovering waste heat from the integrated combustion exhaust gas, and a CO.sub.2 recovery unit recovering CO.sub.2 contained in the integrated combustion exhaust gas by using CO.sub.2 absorbing liquid.

Devices, systems, facilities, and methods for post combustion capture of emissions from a natural gas generator used to power a data center disclosed herein. The facility includes a process for capturing and sequestering CO.sub.2 from a post combustion capture of the natural gas generator utilizing the heat from the flue gas and from the data center. The CO.sub.2 rich streams from the post combustion capture system are sent to sequestration of some form via a sequestration compressor, thereby reducing the overall emissions from the facility.

A method for transferring thermal energy to a separate endothermic process includes: (a) providing a carbon dioxide (CO.sub.2) stream and a carbonaceous fuel to a heater; (b) reacting the carbonaceous fuel in the heater to produce a heated stream; (c) transferring heat from the heated stream to the separate endothermic process; (d) separating the CO.sub.2 stream from the heated stream after (c); and (e) recycling the CO.sub.2 stream to the heater after (d).

A system for offshore electricity generation and direct carbon dioxide sequestration includes an offshore marine platform on which is mounted a plurality of internal combustion engines. The marine platform is deployed above an offshore, subsea storage reservoir. The internal combustion engines drive electric generators to produce electricity. Flue gas from the internal combustion engines is directed to a carbon dioxide capture system adjacent the internal combustion engines and in fluid communication with the flue gas exhausts of the internal combustion engines. The carbon dioxide capture system captures gaseous carbon dioxide from the flue gas, and then injects the captured carbon dioxide directly into the offshore, subsea storage reservoir. Compressors in fluid communication with the carbon dioxide capture system may be utilized to increase the pressure of the captured gaseous carbon dioxide to a desired injection pressure. Electricity produced by the electric generators is conveyed to a land-based power grid.

The plant according to the invention includes a reactor including a combustion chamber in which a fuel is fired with an oxidant to form a carbon dioxide-containing flue gas stream. The plant also includes a waste heat recovery unit in fluid connection with the combustion chamber, configured to capture heat from the flue gas stream. The plant also includes a flue gas compression unit in fluid connection with the waste heat recovery unit, configured to increase the pressure of the flue gas stream. The plant also includes a scrubber in fluid connection with the flue gas compression unit, configured to remove sulphur oxides and/or nitrogen oxides from the flue gas stream and to cool flue gas stream by means of the scrubbing medium. The plant also includes an absorption unit in fluid connection with the scrubber, configured to absorb carbon dioxide from the flue gas stream.

Devices, systems, and methods for carbon capture optimization in industrial facilities are disclosed herein. An example carbon capture process involves cooling a flue gas stream using at least one gas-to-air heat exchanger disposed upstream of a carbon dioxide (CO2) absorber. Another example carbon capture process involves heating a heat medium for solvent regeneration and CO2 stripping using a fired heater and/or using at least one waste heat recovery unit.

A system is provided with a turbine combustor having a first diffusion fuel nozzle, wherein the first diffusion fuel nozzle is configured to produce a diffusion flame. The system includes a turbine driven by combustion products from the diffusion flame in the turbine combustor. The system also includes an exhaust gas compressor, wherein the exhaust gas compressor is configured to compress and route an exhaust gas from the turbine to the turbine combustor along an exhaust recirculation path. In addition, the system includes a control system configured to control flow rates of at least one oxidant and at least one fuel to the turbine combustor in a stoichiometric control mode and a non-stoichiometric control mode, wherein the stoichiometric control mode is configured to change the flow rates and provide a substantially stoichiometric ratio of the at least one fuel with the at least one oxidant, and the non-stoichiometric control mode is configured to change the flow rates and provide a non-stoichiometric ratio of the at least one fuel with the at least one oxidant.