A rubber composition for golf balls includes (a) a base rubber, relative amounts of (b) a co-crosslinking agent which is an ?,?-unsaturated carboxylic acid and/or a metal salt thereof and of (c) an organic peroxide that together satisfy a specific condition, and (d) a specific amount of a moisture-providing agent, the latter being a substance which includes on the structure thereof a water constituent other than free water and eliminates moisture under heating or a substance which thermally decomposes under heating, releasing a water constituent. When the hardness difference in the internal hardness profile of a golf ball core made of the composition is large, the ball exhibits a low spin rate on shots, improving the flight performance of the ball, and the durability of the ball to cracking is enhanced.

An object of the present invention is to provide a rubber composition from which a crosslinked rubber molded product excellent in the resilience performance can be obtained. The present invention provides a rubber composition containing (a) a base rubber, (b) a co-crosslinking agent and (c) a crosslinking initiator, wherein (b) the co-crosslinking agent contains a complex represented by a general formula (1). ##STR00001## [In the formula (1), M is a metal atom, and L is a carboxylate represented by the general formula (2). In the formula (2), R is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, and the dotted line shows a resonance structure. In the formula (1), a plurality of R may be identical to or different from each other, and at least one of R is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.]

The invention provides a golf ball having a core and a cover of one or more layer encasing the core, wherein the core has a center core and a foamed outer layer that directly, or indirectly through another layer, envelops the center core. The foamed outer layer is made of a rubber composition that includes a base rubber, a co-crosslinking agent and an organic peroxide. The foamed outer layer has an inside portion facing the ball center and an outside portion facing the outside of the ball that are unfoamed regions, and contains a foamed region in an intermediate portion therebetween. A method of manufacturing such a golf ball is also provided.

The invention provides a golf ball having a core and a cover of one or more layer encasing the core, wherein the core is formed of a rubber composition that includes a base rubber, a co-crosslinking agent and an organic peroxide. The core has a center portion and a surface portion that are unfoamed regions, and has an intermediate portion that contains a foamed region. A method of manufacturing such a golf ball is also provided.

In a golf ball having a core, a cover of at least one layer and a paint film layer formed on a surface of the cover, the paint film layer has an elastic work recovery of at least 60%, the cover layer in contact with the paint film layer has a material hardness on the Shore D scale of at least 55 and, letting M be the elastic work recovery (%) of the paint film layer and N be the material hardness (Shore D hardness) of the cover layer, MN>0. The ball surface is scratch-resistant and has an excellent durability, and the ball has a reduced spin rate on shots with a driver or a long iron, resulting in an increased carry.

A golf ball 2 has a large number of dimples 10 on a surface thereof. A dimple pattern of each hemisphere of the golf ball 2 includes three units (T1, T2, and T3) that are rotationally symmetrical to each other. A dimple pattern of each unit includes two small units (T1a, T1b) that are mirror-symmetrical to each other. A standard deviation Su of areas of all the dimples 10 is not greater than 1.7 mm.sup.2. A standard deviation Pd of distances L between dimples 10 of all neighboring dimple pairs is less than 0.500 mm. A ratio So of a sum of areas of the dimples 10 relative to a surface area of a phantom sphere of the golf ball 2 is not less than 78.0%.

Casing compositions including carboxyl groups, cover compositions including hydroxyl groups and an adhesion promoter capable of crosslinking carboxyl and hydroxyl groups, and golf balls made from such compositions that have crosslinks between carboxyl groups in the casing composition and hydroxyl groups in the cover composition. The type and concentration of the components in the casing and cover compositions, including the adhesion promoter, affect the adhesion between golf balls having components made from such compositions and, thus, can be used to produce a golf ball having increased durability.

Casing compositions including carboxylic acid groups, cover compositions including an adhesion promoter with functional groups that crosslink with carboxylic acid groups, and golf balls made from such compositions that have crosslinks between functional groups of the cover compositions and the carboxylic acid groups. The type and concentration of the components in the casing and cover compositions, including the adhesion promoter, affect the adhesion between golf balls having components made from such compositions and, thus, can be used to produce a golf ball having increased durability. Additionally, methods of crosslinking casing and cover layers made from such casing and cover compositions to increase interlayer adhesion are disclosed.

A method and system for determining concentricity of a multiple layer golf ball are disclosed herein. One or more images of a golf ball are generated using an X-ray source, a camera or a digital detector, and an image intensifier. An edge detection algorithm is preferably utilized. The method also includes calculating Y,Z center coordinates of the a best fit diameter or ellipse of the inner edge layer and outer edge layer of the multiple layer golf ball.

Golf balls and golf ball components made using three-dimensional (3D) additive manufacturing systems are provided. The golf ball includes at least one three-dimensional piece. Preferably, a continuous liquid interface printing method is used to make the three-dimensional structure. Ultraviolet (UV)-light polymerizable materials are used in the method. The method may be used to make single-piece or multi-piece balls. For example, the ball may include an inner core produced by the liquid interface printing method. An outer core layer may be disposed about the inner core, and a cover comprising inner and outer cover layers may encapsulate the core assembly to form the finished golf ball. The outer core and cover layers may be made using conventional molding technologies or the methods of this invention.