An inflatable non-imaging solar concentrator powered high temperature thermo-chemical reaction system, which is designed to reduce CO2 into CO and H2O into H2 for liquid fuels such as methanol and kerosene, comprises: 1) an inflatable non-imaging solar concentrator with a transparent cover and a Compound Parabolic Concentrator (CPC); 2) the first stage of the multi-stage non-imaging non-tracking solar concentrator with a domed divergent Fresnel Lens transparent cover and a CPC; 3) the second stage of the multi-stage non-imaging non-tracking solar concentrator with a domed divergent Fresnel Lens transparent cover and a CPC; 4) a high temperature thermo-chemical reactor with a steel high pressure vessel, an insulation layer, a first CeO2 catalyst layer, and a second CeO2 catalyst layer.

A heat receiver, a reactor, and a heater utilize the heat of concentrated solar light for thermal decomposition and/or chemical reaction of coals, etc. The heat receiver includes: a side portion forming a substantially cylindrical side surface; a substantially circular bottom portion connected to the lower edge of the side portion; and a ceiling connected to the upper edge of the side portion. A substantially circular aperture is formed in the center of the ceiling. The heat receiver has a substantially cylindrical cavity and the opening portion is open. When the cavity has a diameter of D and a length of L, and the aperture has a diameter of d, d=D/2 or less and L=2D or more. Concentrated solar light entering the heat receiver is to be contained in the heat receiver to effectively utilize the solar light.

Provided is an azobenzene-based photothermal energy storage molecule represented by Formula I which contains two types of azobenzene unit: two biscarboxyl azobenzene units and one monoamino azobenzene unit. By utilizing the energy difference between the two configurations of the azobenzene units, energy is stored during the transition from trans to cis, and in reverse, energy is released. The carboxyl and amino groups on different azobenzene units can form strong intermolecular and intramolecular hydrogen bonds, which leads to a great improvement in energy density and reversion half-life compared with the traditional azobenzene materials in which a single type of an azobenzene unit is grafted. Moreover, the release of thermal energy can be controlled by light and heating, which is beneficial to fully utilize the solar energy for photothermal energy conversion and storage, and used as a solar thermal fuel to the field of heating technology and new generation of light-driven spacecrafts. ##STR00001##

Provided is an azobenzene-based photothermal energy storage molecule represented by Formula I which contains two types of azobenzene unit: two biscarboxyl azobenzene units and one monoamino azobenzene unit. By utilizing the energy difference between the two configurations of the azobenzene units, energy is stored during the transition from trans to cis, and in reverse, energy is released. The carboxyl and amino groups on different azobenzene units can form strong intermolecular and intramolecular hydrogen bonds, which leads to a great improvement in energy density and reversion half-life compared with the traditional azobenzene materials in which a single type of an azobenzene unit is grafted. Moreover, the release of thermal energy can be controlled by light and heating, which is beneficial to fully utilize the solar energy for photothermal energy conversion and storage, and used as a solar thermal fuel to the field of heating technology and new generation of light-driven spacecrafts. ##STR00001##

A method for full spectrum solar thermal energy harvesting and collection includes storing a first heat in a phase change material in the presence of solar radiation based on absorbing full spectrum solar radiation, harvesting a second heat from the phase change material in the presence of solar radiation, storing molecular energy in a molecular storage material in the presence of solar radiation based on absorbing full spectrum solar radiation, transferring the second heat from the phase change material to the molecular storage material in the absence of solar radiation, and harvesting the molecular energy released by the molecular storage material.

A method for full spectrum solar thermal energy harvesting and collection includes storing a first heat in a phase change material in the presence of solar radiation based on absorbing full spectrum solar radiation, harvesting a second heat from the phase change material in the presence of solar radiation, storing molecular energy in a molecular storage material in the presence of solar radiation based on absorbing full spectrum solar radiation, transferring the second heat from the phase change material to the molecular storage material in the absence of solar radiation, and harvesting the molecular energy released by the molecular storage material.

A device and a method for thermal-electrochemical energy storage and energy provision, and methods of using the device in the fields of electrical energy and thermal energy generation, distribution, and storage. The device facilitates short-term storage and long-term storage of electrical energy and is particularly useful in solar power plants.

A device and a method for thermal-electrochemical energy storage and energy provision, and methods of using the device in the fields of electrical energy and thermal energy generation, distribution, and storage. The device facilitates short-term storage and long-term storage of electrical energy and is particularly useful in solar power plants.

The integrated solar absorption heat pump system includes an absorption heat pump assembly (AHPA) having a generator, a condenser in fluid communication with the generator, an evaporator/absorber in fluid communication with the condenser and the generator, and a heat exchanger in communicating relation with the evaporator/absorber; a solar collector in fluid communication with the generator of the AHPA; a photovoltaic thermal collector in communicating relation with the evaporator/absorber of the AHPA; a plurality of pumps configured for pumping a fluid throughout the system to provide the desired heating or cooling; a power storage source, e.g., a solar battery, in communicating relation with the photovoltaic thermal collector; and a coil unit in communicating relation to the evaporator/absorber for receiving an air-stream. The absorption heat pump assembly can include an absorber and a solution heat exchanger.

A polymer consisting of small functional molecules can be integrated into solar thermal fuels in the solid-state for solar energy harvesting and storage. In certain embodiments, a solar energy storage device can include one or more layers of photoswitchable moieties associated with a polymer. Such solar thermal fuel polymers can be used to enable deposition from low concentration solutions, resulting in uniform and large-area thin-films. This approach enables conformal deposition on a variety of conducting substrates that can be either flat or structured and control over film growth via electrodeposition conditions and results in highly uniform and large-area thin films.