A vertical support rigidly mounted to a planar base positions and supports a cryocooler expander unit off axis and away from a sample to be examined. The sample support is likewise rigidly mounted to the planar base with a rigidly mounted sample housing therein. The cryocooler expander unit is suspended in the vertical support by spring dampening bearings. A pair of opposing flexible vacuum bellows connects the cryocooler expander unit to the sample housing and vertical support. This configuration isolates the sample from vibration. Flexible thermal links associated with a predictive electronic closed loop control sequence maintains sample temperature.

Included are an ammonia synthesis column that synthesizes ammonia from a raw material gas, a discharge line that discharges a synthetic gas, a water-cooled cooler that cools the synthetic gas with a coolant, disposed in the discharge line, an ammonia separator into which a synthetic gas after cooling is introduced and which separates the ammonia gas and a liquid ammonia from each other, a raw material return line that returns a raw material gas containing the separated ammonia gas to the ammonia synthesis column side as a return raw material gas, and a compressor that compresses the return raw material gas, disposed in the raw material return line. An ammonia concentration in the return raw material gas is 5 mol % or more, and an ammonia synthesis catalyst that synthesizes the ammonia gas in the ammonia synthesis column is a ruthenium catalyst.

Provided is a supercritical fluid chromatography system, and components comprising such a system, including one or more of a supercritical fluid chiller, a supercritical fluid pressure-equalizing vessel, and a supercritical fluid cyclonic separator. The supercritical fluid chiller and the use of the chiller allow efficient and consistent pumping of liquid-phase gases employing off-the-shelf HPLC pumps in the supercritical chromatography system using liquid-phase gas mobile phase. The pressure equalizing vessel allows the use of off the shelf HPLC column cartridges in the supercritical chromatography system. The cyclonic separator efficiently and effectively allows for separation of sample molecules from a liquid phase or gas phase stream of a supercritical fluid.

A vapor compression system (200; 400; 600; 700; 800; 900; 1000) comprises a plurality of valves (260, 262, 264; 260) controllable to define a first mode flowpath and a second mode flowpath. The first mode flowpath is sequentially through: a compressor (22); a first heat exchanger (30); a first nozzle (228; 624); and a separator (48), and then branching into: a first branch returning to the compressor; and a second branch passing through an expansion device (70) and a second heat exchanger (64) to the rejoin the flowpath between the first heat exchanger and the separator. The second mode flowpath is sequentially through: the compressor; the second heat exchanger; a second nozzle (248; 625); and the separator, and then branching into: a first branch returning to the compressor; and a second branch passing through the expansion device and first heat exchanger to the rejoin the flowpath between the first heat exchanger and the separator.

Embodiments as disclosed herein are directed to a heat pump that employs at least two different refrigerants, each of which is optimized for either a cooling operation mode or a heating operation mode. The embodiments as disclosed herein can help increase the capacity and/or efficiency of a heat pump in both the cooling operation mode and the heating operation mode. In addition, the embodiments as disclosed herein may also eliminate the need for a ground source in a relatively low ambient temperature environment.

A cryocooler includes a displacer, a cylinder that forms an expansion space, a Scotch yoke mechanism configured to drive the displacer in a reciprocating manner, a first rod that extends from the Scotch yoke mechanism, a housing that includes an assist chamber, a rotary valve configured to switch between a state in which the expansion space and a discharge side of a compressor are connected and the assist chamber and a suction side of the compressor are connected and a state in which the expansion space and the suction side of the compressor are connected and the assist chamber and the discharge side of the compressor are connected, a motor configured to drive the Scotch yoke mechanism and the rotary valve, and an on-off valve configured to open and close a gas flow path through which the rotary valve and the assist chamber are connected.

An apparatus for using nitrogen within a closed loop cryogenic system is described. A cryochamber is provided that has a first nitrogen flow line with an inlet for connection to a nitrogen source and an outlet. At least one cryogenic cooling loop is provided that has a nitrogen inlet and a nitrogen outlet. The nitrogen inlet and outlet are in fluid communication with the first nitrogen flow line. The nitrogen inlet is positioned upstream of the nitrogen outlet. A heat exchanger is provided on the at least one cryogenic cooling loops through which the nitrogen passes. The heat exchanger has a fluid inlet and a fluid outlet. A turbo expander is in fluid communication with the outlet of the first nitrogen flow line and the nitrogen source. The turbo expander re-cools the nitrogen that passes through the first flow line and the at least one cryogenic cooling loop.

An electrochemical compressor utilizes an anion conducting layer disposed between an anode and a cathode for transporting a working fluid. The working fluid may include carbon dioxide that is dissolved in water and is partially converted to carbonic acid that is equilibrium with bicarbonate anion. An electrical potential across the anode and cathode creates a pH gradient that drives the bicarbonate anion across the anion conducting layer to the cathode, wherein it is reformed into carbon dioxide. Therefore, carbon dioxide is pumped across the anion conducting layer. The compressor may be part of a refrigeration system that pumps the working fluid in a closed loop through a condenser and an evaporator.

A cryocooler includes a second-stage cooling stage, a second cylinder which includes the second-stage cooling stage on a terminal of the second-stage cylinder, a second-stage displacer which includes a magnetic regenerator material and is accommodated in the second-stage cylinder so as to be able to reciprocate in the second-stage cylinder, and a tubular magnetic shield which is installed on the second-stage cooling stage and extends along the second-stage cylinder outside the second-stage cylinder. The magnetic shield is formed of a normal conductor and a product of an electrical conductivity in a temperature range of 10 K (Kelvin) or less and a thickness of the tubular magnetic shield is 60 MS (Mega-Siemens) to 1980 MS.

Provided is a chiller and system that may be utilized in a supercritical fluid chromatography method, wherein a non-polar solvent may replace a portion or all of a polar solvent for the purpose of separating or extracting desired sample molecules from a combined sample/solvent stream. The system may reduce the amount of polar solvent necessary for chromatographic separation and/or extraction of desired samples. The system may incorporate a supercritical fluid chiller, a supercritical fluid pressure-equalizing vessel and a supercritical fluid cyclonic separator. The supercritical fluid chiller allows for efficient and consistent pumping of liquid-phase gases employing off-the-shelf HPLC pumps. The pressure equalizing vessel allows the use of off-the-shelf HPLC column cartridges. The system may further incorporate the use of one or more disposable cartridges containing silica gel or other suitable medium. The system may also utilize an open loop cooling circuit using fluids with a positive Joule-Thomson coefficient.