A heat transfer system is disclosed that includes a plurality of supported electrocaloric film segments (46) arranged in a stack and connected to a frame (10). A working fluid flow path (44) extends through the stack, disposed between adjacent electrocaloric film segments. The working fluid flow path is in operative thermal communication with a heat sink and a heat source at opposite ends of the working fluid flow path. A plurality of electrodes are arranged to generate an electric field in the electrocaloric film segments, and are connected to a power source configured to selectively apply voltage to activate the electrodes in coordination with fluid flow along the working fluid flow path to transfer heat from the heat source to the heat sink. The heat transfer system further includes a film stress management mechanism.

A cooling system includes an electrocaloric element having a nanoparticulate ion scavenger and a co-continuous polymer network of a first polymer phase and a second polymer phase wherein the first polymer includes a liquid crystal polymer. A pair of electrodes is disposed on opposite surfaces of the electrocaloric element. A first thermal flow path is disposed between the electrocaloric element and a heat sink. A second thermal flow path is disposed between the electrocaloric element and a heat source. The system also includes a controller configured to control electrical current to the electrodes and to selectively direct transfer of heat energy from the electrocaloric element to the heat sink along the first thermal flow path or from the heat source to the electrocaloric element along the second thermal flow path.

A method of making an electrocaloric element includes providing an electrocaloric material, forming a first electrode at a first surface of the electrocaloric material, and forming a second electrode at a second surface of the electrocaloric material. The forming of the first electrode includes, or the forming of the second electrode includes, or the forming of each of the first and second electrodes independently includes modifying the respective first and/or second surface of the electrocaloric material with an electrically conductive surface modification.

An electrocaloric element for a heat transfer system includes an electrocaloric material of a copolymer of (i) vinylidene fluoride, and (ii) an addition polymerization monomer that is larger than vinylidene fluoride and includes a substituent more electronegative than chlorine. Electrodes are disposed on opposite surfaces of the electrocaloric material, and an electric power source is configured to provide voltage to the electrodes. The system also includes a first thermal flow path between the electrocaloric material and a heat sink, and a second thermal flow path between the electrocaloric material and a heat source.

A method of making an electrocaloric article is disclosed. The method includes mounting a supported electrocaloric film to a frame. The supported electrocaloric film includes an electrocaloric film and a first support film disposed on a first side of the electrocaloric film. An active area of the electrocaloric film is provided, which is not covered by the first support film on the first side of the electrocaloric film. Electrical connections are provided to electrodes disposed on opposing sides of the electrocaloric film in the active area.

An electric power source in which an electron collector and an electron emitter, having a higher work function than the electron collector, are connected peripherally by a wire and placed very close together. An electric potential difference develops between the electron collector and the electron emitter as electrons spontaneously flow through the wire from the electron collector to the electron emitter due to the difference in work functions. With the electron collector and electron emitter positioned extremely close together, the small electric potential difference creates a strong electric field. The strong electric field allows field emission of electrons from the electron emitter. The emitted electrons then cross the small gap to the electron collector, completing the electric circuit, allowing a continuous electric current to flow, making this device an electric power source.

An electrocaloric module includes a housing and an electrocaloric element in the housing. The electrocaloric element includes an electrocaloric film, a first electrode on a first surface of the electrocaloric film, and a second electrode on a second surface of the electrocaloric film. The electrocaloric module also includes a first thermal connection configured to connect to a first thermal flow path between the electrocaloric elements and a heat sink, a second thermal connection configured to connect to a second thermal flow path between the electrocaloric elements and a heat source, and a power connection connected to the first and second electrodes and configured to connect to a power source.

A method for operating an electrocaloric system includes determining an internal temperature lift of an electrocaloric device. A current temperature of a space to be cooled is determined. A heat rejection temperature is determined. A difference between the current temperature and the heat rejection temperature is determined. A target temperature lift is determined based on the difference and a target temperature for the space. A voltage applied to the electrocaloric device is modulated based on the internal temperature lift and the target temperature lift.

A solid-state heat transporting device including a heat transporting element whose uniformity of contact with one or multiple surfaces is controllable so that various amounts of heat may be transported to and from the one or multiple surfaces. The heat transporting element uses the electrocaloric effect to absorb and release the heat and the uniformity of contact is controlled using an electrostatic effect which may change the shape of the heat transporting element. In one embodiment, the heat transporting element is an electrostatically actuated P(VDF-TrFE-CFE) polymer stack achieving a high specific cooling power of 2.8 W/g and a COP of 13 (the highest reported coefficient of performance to date) when used as a cooling device.

The present invention refers to a hybrid thermal apparatus comprising at least one heat exchanger and at least one heat source and/or heat sink. The thermal apparatus according to the invention is formed as a combination of a first thermal apparatus (1, 15) based on a vapour-compression principle and comprising a first medium for heat transfer, and of a second thermal apparatus (2, 16) based on an elastocaloric principle and comprising a second medium for heat transfer. Said thermal apparatuses (1, 15; 2, 16) have at least one deformable heat exchanger (3, 21) of elastocaloric material in common.