An air separation apparatus comprises: a first rectification column, a first condensing portion, a second rectification column, a third rectification column, a second condensing portion, a fourth rectification column, a third condensing portion, and a recycling pipe for recycling a gas drawn from the third condensing portion to the second rectification column. The air separation apparatus furthermore comprises: a branch pipe branching from the recycling pipe; and a control unit for controlling opening/closing of a valve so that a gas drawn from the third condensing portion is fed to the branch pipe for a predetermined period from the start of driving of the third condensing portion, and for controlling opening/closing of the valve so that the gas drawn from the third condensing portion is fed to the recycling pipe after the predetermined period has elapsed.

In this process and apparatus for cryogenic separation of air, the separation column system comprises a high-pressure column, a low-pressure column and a crude argon column. A mixed gas stream produced by mixing gaseous oxygen and a gas stream from the evaporation space of the argon top condenser, is work expanded in a mixed gas turbine.

A moderate pressure nitrogen and argon producing cryogenic air separation unit is provided that includes a three distillation column system and turbine air stream bypass arrangement or circuit. The turbine air stream bypass arrangement or circuit is configured to improve argon and nitrogen recoveries in select operating modes by optionally diverting a portion of the turbine air stream to a nitrogen waste stream circuit drawn from the lower pressure column of the cryogenic air separation unit such that the diverted portion of the turbine air stream bypasses the distillation column system.

A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

Certain embodiments of the present invention lies in providing a high-purity oxygen production system which is capable of supplying liquid nitrogen in order to supply the cold required by a high-purity oxygen production apparatus, without the use of a costly conventional liquefaction apparatus.

A high-purity oxygen production system in accordance with an embodiment can include: an air separation apparatus including a main heat exchanger, a medium-pressure column and a low-pressure column; and a high-purity oxygen production apparatus including a nitrogen compressor, a nitrogen heat exchanger and at least one (high-purity) oxygen rectification column, an oxygen-containing stream serving as a starting material for high-purity oxygen is supplied from the low-pressure column to the high-purity oxygen production apparatus, and liquid nitrogen obtained from the medium-pressure column is supplied to the high-purity oxygen production apparatus in order to replenish cold heat required for operation of the high-purity oxygen production apparatus.

A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon and an overall nitrogen recovery of 98% or greater. The air separation is configured to produce a high purity oxygen enriched stream which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption prepurifier unit. Argon recovery is facilitated with the use of an argon superstaged column.

A cryogenic air separation apparatus comprises: a heat exchanger, a first rectification column, a first condenser, a second rectification column, a third rectification column, a second condenser, a high-purity oxygen rectification column, a third condenser, a nitrogen compressor, and a compressed recycled gas line L52 for introducing product nitrogen gas compressed by the first nitrogen compressor into a warm end (heat source) of an ultra-high-purity oxygen vaporizer as a compressed recycled gas.

A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98% or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.