An acid gas purification system is described herein that includes a primary membrane system with a CO.sub.2- and H.sub.2S-enriched permeate stream effluent and a hydrocarbon stream effluent; a first compression stage arranged to receive the CO.sub.2- and H.sub.2S-enriched permeate stream and produce a compressed stream; and a cryogenic separation system to receive the compressed stream, the cryogenic separation system including a cooler followed by a fractionator, wherein the fractionator produces a CO.sub.2- and H.sub.2S liquid stream and a hydrocarbon gas stream.

In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.

An apparatus for producing product nitrogen gas and product argon, comprising: a first rectification column into which raw air is introduced; a second rectification column from which product nitrogen gas is drawn; a third rectification column from which product argon gas is drawn; and a first condenser configured to perform heat exchange between a gas accumulated in a column top portion of the first rectification column, and a liquid accumulated in a column bottom portion of the second rectification column, wherein an intermediate portion gas containing nitrogen is drawn from an intermediate portion of the second rectification column and merged with a condenser gas drawn from the first condenser. The merged gases are expanded and cooled by means of an expansion turbine whereby the cold thereof is utilized.

A system for melting contaminant-laden solids that have been separated from a hydrocarbon-containing vapor stream in a hydrocarbon distillation tower, comprising at least one plate positioned where the solids form within the hydrocarbon distillation tower, hollow tubing forming an integral part of each of the at least one plate, and a heating medium disposed to flow through the hollow tubing at a higher temperature than a temperature of the solids to at least partially melt the solids.

A process and an apparatus are disclosed for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbon components from a hydrocarbon gas stream. The stream is divided into first and second streams. The first stream is cooled to condense substantially all of it, expanded to lower pressure, and supplied to a fractionation tower at an upper mid-column feed position. The second stream is cooled sufficiently to partially condense it and separated into vapor and liquid streams. The vapor stream is divided into first and second portions. The first portion is cooled to condense substantially all of it, expanded to the tower pressure, and supplied to the tower at the top feed position. The second portion is expanded to the tower pressure and supplied to the fractionation tower at an intermediate mid-column feed position. The liquid stream is expanded to the tower pressure and supplied to the column at a lower mid-column feed position. The quantities and temperatures of the feeds to the fractionation tower are effective to maintain the overhead temperature of the fractionation tower at a temperature whereby the major portion of the desired components is recovered.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as a low-pressure tail gas of an ammonia production plant is provided. The disclosed system and method provides for a rectification system wherein an argon depleted gaseous stream and a methane rich liquid stream are produced and subsequently combined in whole or in part prior to vaporization. Nitrogen and argon containing streams may also be produced from the rectification system. An argon stripping column arrangement is also disclosed where residual argon is removed from the methane-rich fuel gas and recycled back to the feed stream.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as tail gas of an ammonia production plant is provided. The disclosed system and method provides for nitrogen-argon rectification and the methane rejection within a column system comprised of at least one distillation column. Nitrogen and argon are further separated and to produce liquid products. An argon stripping column arrangement is disclosed where residual argon is further removed from the methane-rich fuel gas and recycled back to the feed stream.

A system and method for cryogenic purification of a hydrogen, nitrogen, methane and argon containing feed stream to produce a methane free, hydrogen and nitrogen containing synthesis gas and a methane rich fuel gas, as well as to recover an argon product stream, excess hydrogen, and excess nitrogen is provided. The disclosed system and method are particularly useful as an integrated cryogenic purifier in an ammonia synthesis process in an ammonia plant. The excess nitrogen is a nitrogen stream substantially free of methane and hydrogen that can be used in other parts of the plant, recovered as a gaseous nitrogen product and/or liquefied to produce a liquid nitrogen product.

A system for melting contaminant-laden solids that have been separated from a hydrocarbon-containing vapor stream in a hydrocarbon distillation tower, comprising at least one plate positioned where the solids form within the hydrocarbon distillation tower, hollow tubing forming an integral part of each of the at least one plate, and a heating medium disposed to flow through the hollow tubing at a higher temperature than a temperature of the solids to at least partially melt the solids.

The power required to recover C.sub.3+ hydrocarbons from crude carbon dioxide comprising C.sub.1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C.sub.3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce lighter and heavier hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.