The present invention relates to an adsorption process for xenon recovery from a cryogenic liquid or gas stream wherein a bed of adsorbent is contacted with a xenon-containing liquid or gas stream selectively adsorbing the xenon from said stream. The adsorption bed is operated to at least near full breakthrough with xenon to enable a deep rejection of other stream components, prior to regeneration using the temperature swing method. After the stripping step, the xenon adsorbent bed is drained to clear out the liquid residue left in the nonselective void space and the xenon molecules in those void spaces is recycled upstream to the ASU distillation column for increasing xenon recovery. The xenon adsorbent bed is optionally purged with oxygen, followed by purging with gaseous argon at cryogenic temperature (≤160 K) to displace the oxygen co-adsorbed on the AgX adsorbent due to higher selectivity of argon over oxygen on the AgX adsorbent. By the end of this step, the xenon adsorbent bed is filled with argon and xenon. Then the entire adsorbent bed is heated indirectly without utilizing any of the purge gas for direct heating. Operating the adsorption bed to near full breakthrough with xenon and displacing the adsorbed oxygen and other residues with argon, prior to regeneration, along with indirect heating of the bed, enables production of a high purity product ≥40 vol % xenon from the adsorption bed and further enables safely heating without any purge gas and ease for downstream product collection, even in cases where hydrocarbons are co-present in the feed stream.

This specification relates to operating industrial facilities, for example, crude oil refining facilities or other industrial facilities that include operating plants that process natural gas or recover natural gas liquids.

An oxygen liquefier system may be configured to defrost an oxygen line included therein. The system may include one or more sieve beds, a liquid oxygen reservoir, an oxygen line, a controller, a heating apparatus, and/or other components. The one or more sieve beds are configured to extract oxygen from air obtained from an ambient environment. The liquid oxygen reservoir is configured to store oxygen extracted at the one or more sieve beds that has been liquefied. The oxygen line is configured to provide fluid communication between the one or more sieve beds and the liquid oxygen reservoir. The controller is configured to detect a blockage caused by frozen liquid within the oxygen line based on a liquid oxygen production rate. The heating apparatus is configured to defrost the oxygen line to melt frozen liquid within the oxygen line responsive to the detection of the blockage.

A process for producing liquefied natural gas (14) and liquid carbon dioxide (CO.sub.2) (15) comprising at least the following steps: Step a): separating a natural gas feed gas (1), containing hydrocarbons and carbon dioxide in a treatment unit (2), into a CO.sub.2-enriched gas stream (4) and a CO.sub.2-depleted natural gas stream (3); step b): liquefying the CO.sub.2-depleted natural gas stream (3) resulting from step a) in a natural gas liquefaction unit (5) comprising at least a main heat exchanger (8) and a system (9) for producing frigories; step c): simultaneous liquefying of the CO.sub.2-enriched gas stream (4) resulting from step a) in a CO.sub.2 liquefaction unit (6); characterized in that all of the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream (4) and for the liquefaction of the natural gas is supplied by said frigorie-producing system (9) of the natural gas liquefaction unit (5).

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing a startup mode process prior to beginning a normal operation mode process to remove contaminants from a gaseous feed stream. The startup mode process may be utilized for swing adsorption processes, such as TSA and/or PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

Hydrogen is liquefied through a process utilizing refrigeration from hydrogen at one, two, or three different pressures as well as a nitrogen refrigeration cycle. One or more stages of catalyst are used to convert ortho-hydrogen to para-hydrogen as the hydrogen is cooled and liquefied. Subcooled liquid hydrogen feeds the final stage of ortho-hydrogen to para-hydrogen conversion to reduce or eliminate vaporization of the hydrogen during the exothermic ortho-hydrogen to para-hydrogen conversion.

Systems, devices, and methods for recovering mixed refrigerant and/or nitrogen within liquefaction systems are provided. The systems, devices, and methods facilitate recovering mixed refrigerant (MR) and/or nitrogen vapor that can leak from a compressor, separating the MR from the nitrogen, and reusing the MR and/or the nitrogen within the liquefaction system. Recovering and reusing MR and/or nitrogen can minimize loss of MR and nitrogen which can lower the total operating cost of a liquefaction system. Additionally, recovering the MR, rather than burning it, can reduce environmental emissions by reducing the amount of MR that is burned.

A system and method for flexible production of argon from a cryogenic air separation unit is provided. The cryogenic air separation unit is capable of operating in a ‘no-argon’ or ‘low-argon’ mode when argon demand is low or non-existent and then switching to operating in a ‘high-argon’ mode when argon is needed. The recovery of the argon products from the air separation unit is adjusted by varying the percentages of dirty shelf nitrogen and clean shelf nitrogen in the reflux stream directed to the lower pressure column. The cryogenic air separation unit and associated method also provides an efficient argon production/rejection process that minimizes the power consumption when the cryogenic air separation unit is operating in a ‘no-argon’ or ‘low-argon’ mode yet maintains the capability to produce higher volumes of argon products at full design capacity to meet argon product demands.

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. Alternatively, the pre-purification systems and methods employ a hopcalite catalyst layer and a noble metal catalyst layer separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layer.

A pretreatment system and method for a floating liquid natural gas (“FLNG”) facility are presented. The inlet natural gas stream flows through a membrane system to remove carbon dioxide and a heat exchanger, producing first and second cooled CO.sub.2-depleted non-permeate streams. The first cooled CO.sub.2-depleted non-permeate stream is routed to additional pretreatment equipment, while the second cooled CO.sub.2-depleted non-permeate stream is routed directly to a LNG train. Alternatively, the inlet natural gas stream may flow through a membrane system to produce a single cooled CO.sub.2-depleted non-permeate stream that is routed to the LNG train after sweetening and dehydration. Because the pretreatment system delivers the incoming gas stream to the LNG train at a lower temperature than conventional systems, less energy is needed to convert the gas stream to LNG. In addition, the pretreatment system has a smaller footprint than conventional pretreatment systems.