A liquefier device which may be a retrofit to an air separation plant or utilized as part of a new design. The flow needed for the liquefier comes from an air separation plant running in a maxim oxygen state, in a stable mode. The three gas flows are low pressure oxygen, low pressure nitrogen, and higher pressure nitrogen. All of the flows are found on the side of the main heat exchanger with a temperature of about 37 degrees Fahrenheit. All of the gasses put into the liquefier come out as a subcooled liquid, for storage or return to the air separation plant. This new liquefier does not include a front end electrical compressor, and will take a self produced liquid nitrogen, pump it up to a runnable 420 psig pressure, and with the use of turbines, condensers, flash pots, and multi pass heat exchangers. The liquefier will make liquid from a planned amount of any pure gas oxygen or nitrogen an air separation plant can produce.

A process for recovering a noncondensable gas from a gaseous mixture, the method comprising the steps of: supplying a gaseous mixture comprising a noncondensable component; supplying a sweep gas comprising a condensable component; introducing the gaseous mixture and the sweep gas to a swept membrane stage to obtain a retentate stream and a mixed permeate stream, the mixed permeate stream comprising at least a portion of the condensable component and at least a portion of the noncondensable component; introducing the mixed permeate stream to a vapor-liquid separator and subjecting the mixed permeate stream to thermodynamic conditions sufficient to condense most of the condensable component into a liquid, and obtain a raw noncondensable component stream, wherein the raw noncondensable component stream is enriched in the noncondensable component; and introducing the raw noncondensable component to a concentration unit to obtain a noncondensable component product stream enriched in the noncondensable component.

A plant for separating gases from the air comprises, in the direction of circulation of the stream of air: a compression means for compressing the stream of air to a pressure P1 of between 1.15 bar abs and 2 bar abs, a TSA adsorption unit, and a cryogenic distillation unit, with the adsorption unit comprising at least two adsorbers A1 and A2 each having a parallelepipedal casing arranged horizontally and comprising: an air stream inlet and outlet, two fixed bed adsorbent masses each likewise parallelepipedal with faces parallel to the faces of the casing, and a set of volumes allowing the stream of air to traverse the two adsorbent masses horizontally, in parallel, over the whole cross section of each of the adsorbent masses and throughout their thicknesses.

A method of integrating a fuel cell with a steam methane reformer is provided. The system includes at least one fuel cell including an anode and a cathode, and a steam methane reformer including a syngas stream, and a flue gas stream. The method includes introducing at least a portion of the flue gas stream to the cathode, thereby producing a CO2 depleted flue gas stream and introducing a hydrocarbon containing stream to the anode, thereby producing an electrical energy output and a carbon dioxide and hydrogen containing stream from the fuel cell.

A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. Alternatively, the pre-purification systems and methods employ a hopcalite catalyst layer and a noble metal catalyst layer separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layer.

A system and method for flexible production of argon from a cryogenic air separation unit is provided. The cryogenic air separation unit is capable of operating in a ‘no-argon’ or ‘low-argon’ mode when argon demand is low or non-existent and then switching to operating in a ‘high-argon’ mode when argon is needed. The recovery of the argon products from the air separation unit is adjusted by varying the percentages of dirty shelf nitrogen and clean shelf nitrogen in the reflux stream directed to the lower pressure column. The cryogenic air separation unit and associated method also provides an efficient argon production/rejection process that minimizes the power consumption when the cryogenic air separation unit is operating in a ‘no-argon’ or ‘low-argon’ mode yet maintains the capability to produce higher volumes of argon products at full design capacity to meet argon product demands.

A natural gas liquid plant is retrofitted with a bolt-on unit that includes an absorber that is coupled to an existing demethanizer by refrigeration produced at least in part by compression and expansion of the residue gas, wherein ethane recovery can be increased to at least 99% and propane recovery is at least 99%, and where a lower ethane recovery of 96% is required, the bolt-on unit does not require the absorber, which could be optimum solution for revamping an existing facility. Contemplated configurations are especially advantageous to be used as bolt-on upgrades to existing plants.

This specification relates to operating industrial facilities, for example, crude oil refining facilities or other industrial facilities that include operating plants that process natural gas or recover natural gas liquids.

A method for starting up an air separation plant having a higher-pressure column, a lower-pressure column, and a falling film vaporizer disposed within a lower section of the lower-pressure column is provided. The method can include the steps of: introducing a cooled and compressed air stream into the higher pressure column; withdrawing an oxygen-enriched liquid stream from a bottom section of the higher-pressure column and introducing said oxygen-enriched liquid stream to an upper section of the lower-pressure column; and exchanging heat between nitrogen gas coming from a top section of the higher-pressure column and liquid oxygen from the lower-pressure column within the falling film vaporizer. During a start-up period, flow of liquid oxygen is at least reduced to the closed core. This reduces the available heat exchange area during start up, which increases ΔT and ΔP in the condenser/reboiler.

A hydrogen feed stream comprising oxygen and one or more impurities selected from the group consisting of nitrogen, argon, methane, carbon monoxide, carbon dioxide, and water, is purified by first removing oxygen using a copper oxide and/or manganese oxide getter, then using a cryogenic temperature swing adsorption (CTSA) process with high overall recovery of hydrogen. The oxygen getter prevents an explosive mixture of hydrogen and oxygen from occurring in the CTSA during regeneration.