A natural gas liquid recovery system includes a cold box and a refrigeration system. The refrigeration system includes a primary refrigerant loop in fluid communication with the cold box. The primary refrigerant loop includes a primary refrigerant including a first mixture of hydrocarbons. The refrigeration system includes a secondary refrigerant loop. The secondary refrigerant loop includes a secondary refrigerant including i-butane. The refrigeration system includes a first subcooler configured to transfer heat between the primary refrigerant of the primary refrigerant loop and the secondary refrigerant of the secondary refrigerant loop. The refrigeration system includes a second subcooler downstream of the first subcooler. The second subcooler is configured to transfer heat between the primary refrigerant and a vapor phase of the primary refrigerant. The cold box is configured to receive the primary refrigerant from the second subcooler.

A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

A moderate pressure, argon and nitrogen producing cryogenic air separation unit and air separation cycle having a higher pressure column, a lower pressure column and an argon column arrangement is disclosed. The moderate pressure, argon and nitrogen producing cryogenic air separation unit is configured to take a first portion of an oxygen enriched stream from the lower pressure column, which together with an external source of liquid nitrogen is used as the boiling side refrigerant to condense the argon in the argon condenser. Use of the external source of liquid nitrogen in the argon condenser allows a second portion of the oxygen enriched stream from the lower pressure column to be taken as a liquid oxygen product stream.

A process for producing biomethane by scrubbing a biogas feed stream includes introducing the feed gas stream into a pretreatment unit wherein a CO.sub.2-depleted gas stream is partially separated from a CO.sub.2 stream and an oxygen stream and is compressed to a pressure P1 above 25 bar abs. Subjecting the CO.sub.2-depleted gas stream to cryogenic separation in a distillation column to separate a nitrogen stream and produce a CH.sub.4-enriched stream, the distillation column comprising n plates, n being an integer between 8 and 100. Recovering a pressurized CH.sub.4-enriched stream by pumping the CO.sub.2-depleted gas stream to a pressure P2 above 25 bar absolute.

A process for producing biomethane by scrubbing a biogas feed stream, including introducing a feed gas stream into a pretreatment unit thereby partially separating a CO.sub.2 stream and an oxygen stream and producing a CO.sub.2-depleted gas stream which is then compressed to a pressure P1 above 25 bar abs; introducing the CO.sub.2-depleted gas stream to cryogenic separation in a distillation column to separate a nitrogen stream, the distillation column having n plates, n being an integer between 8 and 100; recovering a pressurized CH.sub.4-enriched stream by pumping the CO.sub.2-depleted gas stream) at a pressure P2 above 25 bar, wherein, when the molar concentration of nitrogen of the CO.sub.2-depleted gas stream is less than a predetermined threshold, nitrogen is injected prior to introduction into the distillation column, in order that the stream introduced into said column has a molar concentration of nitrogen at least equal to said predetermined threshold.

A helium-containing stream is recovered from a natural gas feed using a membrane followed by multiple distillation steps. Refrigeration is provided by expanding a bottoms liquid with a higher nitrogen content than the feed, achieving a lower temperature in the process. The helium-enriched vapor is then purified and the helium-containing waste stream is recycled to maximize recovery and reduce the number of compressors needed. The helium-depleted natural gas stream can be returned at pressure for utilization or transportation.

A process and facility for producing gaseous methane by purifying biogas from landfill, can include a VOC purification unit, at least one membrane, a booster, a CO.sub.2 purification unit, a cryodistillation unit comprising a heat exchanger, a distillation column, and a subcooler, a deoxo, and a dryer.

A method for producing biomethane by purifying biogas from non-hazardous waste storage facilities involves compressing the initial gas flow, introducing the gas flow to be purified into at least one adsorber loaded with adsorbents capable of reversibly adsorbing the VOCs, and subjecting the VOC-depleted gas flow to at least one membrane separation step in order to partially separate the CO.sub.2 and O.sub.2 from the gas flow. The method also involves introducing the retentate from the membrane separation step into at least one adsorber loaded with adsorbents capable of reversibly adsorbing the major portion of the remaining CO.sub.2, subjecting the CO.sub.2-depleted gas flow exiting the adsorber loaded with adsorbents capable of reversibly adsorbing the major portion of the remaining CO.sub.2 to a cryogenic separation step in a distillation column in order to separate the O.sub.2 and N.sub.2 from the gas flow, and recovering the CH.sub.4-rich flow from the cryogenic separation step.

In a method for separating a synthesis gas containing carbon monoxide and hydrogen, a synthesis gas flow from a synthesis gas source is compressed in a compressor and separated into at least three gaseous products. If there is insufficient synthesis gas, at least three separation products are recycled in the compressor in order to separate said products.

In a helium purification process, a stream containing at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane is separated to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane and a second stream enriched in nitrogen and in methane, the helium-enriched stream is treated to produce a helium-rich product and a residual gas containing water, the residual gas is treated by adsorption (TSA) to remove the water and the regeneration gas from the adsorption is sent to a combustion unit (O).