The present invention relates to a refrigerant composition. According to the invention it is envisioned that the composition comprises comprising an inert gas selected from nitrogen, argon, neon and a mixture thereof, and a mixture of at least two C.sub.1-C.sub.5 hydrocarbons. The present invention further relates to the use of the refrigerant composition in a method for liquefying a gaseous substance, particularly hydrogen or helium.

The present invention relates to a refrigerant composition comprising neon and hydrogen. The present invention further relates to the use of the refrigerant composition in liquefying gaseous substances such as hydrogen or helium.

A process for liquefying a hydrogen process gas comprising: introducing a hydrogen heat transfer fluid into an active magnetic regenerative refrigerator apparatus that comprises (i) a high magnetic field section in which the hydrogen heat transfer fluid flows from a cold side to a hot side through at least one magnetized bed of at least one magnetic refrigerant, (ii) a first no heat transfer fluid flow section in which the bed is demagnetized, (iii) a low magnetic field or demagnetized section in which the hydrogen heat transfer fluid flows from a hot side to a cold side through the demagnetized bed, and (iv) a second no heat transfer fluid flow section in which the bed is magnetized; continuously introducing the hydrogen heat transfer fluid from the cold side of the low magnetic field or demagnetized section into the cold side of the high magnetic field section; continuously diverting a portion of the hydrogen heat transfer fluid flowing from the cold side of the low magnetic field or demagnetized section into an expander; and isenthalpically expanding the diverted portion of the hydrogen heat transfer fluid to produce liquefied hydrogen.

The present disclosure relates to a hydrogen liquefaction system and hydrogen liquefaction method optionally enabling O-P conversion in a hydrogen liquefaction process, and may include: a hydrogen pipe, where gaseous hydrogen is introduced at a front end, heat exchange occurs in a heat exchange section leading to liquefaction of gaseous hydrogen into liquid hydrogen, and liquefied liquid hydrogen can be discharged at a rear end; a cooling cycle device that is in thermal contact with the heat exchange section of the hydrogen pipe so as to perform heat exchange with the heat exchange section of the hydrogen pipe such that gaseous hydrogen can be liquefied into liquid hydrogen; and an Ortho-Para (O-P) converter formed in the hydrogen pipe, converting a ratio of ortho-hydrogen to para-hydrogen in a process of liquefying gaseous hydrogen into liquid hydrogen.

The invention relates to a method for producing helium from a source gas stream (1) including at least helium, methane, nitrogen and hydrogen, comprising at least the following consecutive steps: step a): injecting said source gas stream (1) into at least one compressor (3); step b): eliminating the hydrogen and the methane by reacting the stream (4) obtained from step a) with oxygen; step c): eliminating at least the impurities from step b) by temperature swing adsorption (TSA); step d): partially condensing the stream (8) obtained from step c) in order to produce a stream (10) of liquid nitrogen and a gas stream (11) comprising mostly helium; step e): purifying the gas stream (11) obtained from step d) in order to increase the helium content by pressure swing adsorption (PSA) by eliminating the nitrogen and the impurities contained in the gas stream (11) obtained from step d).

Systems and methods are provided for recovering helium from a feed comprising helium, carbon dioxide, and at least one of nitrogen and methane. The feed is separated in a first separator to form helium-enriched stream and a CO.sub.2-enriched stream. The helium-enriched stream is separated in a pressure swing adsorption unit to form a helium-rich product stream and a helium-lean stream. At least a portion of the helium-lean stream is recycled to the first separator with the feed. In some embodiments, a membrane separation unit is used to enhance helium recovery.

The present provides a helium gas separation and recovery process involving cryogenic fractionation process, which comprises cooling a dehydrated high-pressure gas stream while maintain velocity and pressure of the stream; reducing pressure of the dehydrated high-pressure gas stream via a Joule-Thompson's process to obtain a partially liquefied gas stream; and iii) subjecting the partially liquefied gas stream to at least one gas-liquid separation process to obtain at least one liquid stream and a gaseous stream comprising helium, and a residual amount of the gaseous components; recycling the liquid stream obtained in step iii) for use as cooling refrigerant to cool the dehydrated high-pressure gas stream; and purifying the unrefined helium gas stream using pressure swing adsorption (PSA) and/or membrane separation process to obtain a helium product stream having a purity of 98.0 mole % or more.

A hydrogen liquefaction system that utilizes two separate compression services, one controlled via pressure and the other via capacitance, to maintain the rotating equipment at its design point. The system also employs an intermediate flash drum to capture boil off gas and a catalyst bed to convert para-hydrogen into ortho-hydrogen. Changing pressure levels within the turbo expander loop are used to transfer hydrogen from the expander loop into the condensate or feed streams, while maintaining the condensate stream at a constant pressure. The system is capable of efficiently producing high-purity liquid hydrogen at a low cost, making it a valuable tool in industries such as fuel cells, energy storage, and aerospace.

A method for recovering a helium product fraction (6) from a nitrogen- and helium-containing feed fraction (3) is described, wherein the nitrogen- and helium-containing feed fraction (3) is partially condensed (E1), separated into a first helium-enriched fraction (5) and a first nitrogen-enriched fraction (8) and the former is cleaned again in an adsorptive manner.

According to the invention, the separation is carried out in a separation column (T), which is supplied with the first nitrogen-enriched fraction (8) as return flow and with a sub-flow of the second nitrogen-enriched fraction as stripping gas (12), wherein the stripping gas quantity (12) is set such that a third nitrogen-enriched fraction (20), which contains at least 30% of the nitrogen contained in the first nitrogen-enriched fraction (8), can be recovered in the separation column (T).

Methods and systems providing a process for cooling and liquefying a purified gaseous hydrogen feed stream to a liquid hydrogen stream that may be stored in a liquid hydrogen storage tank, as well as a system wherein ortho-hydrogen (o-H2) contained in the purified gaseous hydrogen feed stream may be converted to para-hydrogen (p-H2) through serial low-temperature catalytic converters along the cooling process from normal ambient temperature (300K) to the liquefied temperature about (20K) of the hydrogen.