Systems and methods for the enhanced recovery of ethane and heavier hydrocarbons using an absorbing agent. Typical absorbing agents include one or more C3+ alkanes. The systems and methods separate components of a feed gas containing methane and heavier hydrocarbons, which maximizes ethane recovery, without requiring appreciable increases in capital and operating costs, and improves the safety margin with respect to the risk of CO.sub.2 freeze-out.

In a process for the separation of a gas rich in carbon dioxide and containing at least one component lighter than carbon dioxide, the feed gas rich in carbon dioxide is cooled in a first heat exchanger, partially condensed and separated to form a gaseous portion and a liquid, sending the liquid portion to the top of a distillation column, removing a liquid stream richer in carbon dioxide than the feed gas from the bottom of the distillation column, removing a gaseous stream less rich in carbon dioxide than the feed gas from the top of the distillation column and warming the gaseous stream in the first heat exchanger, sending the gaseous portion to a shell and tube heat exchanger having tubes in a bath of triple point carbon dioxide, in which it condenses at least partially to form a liquid fraction, sending the liquid fraction to the top of the distillation column, vaporizing a liquid stream from the bottom of the distillation column outside or within the distillation column to form a gas which is subsequently separated in the distillation column, expanding a liquid stream from the bottom of the distillation column, vaporizing at least part of the expanded liquid stream in the shell and tube heat exchanger to form a vapor and warming the vapor formed in the first heat exchanger.

A cryogenic method for capturing carbon dioxide in the gaseous emissions produced from the fossil-energy combustion of solid, liquid, or gaseous fossil fuels in a power generation installation employing an OxyFuel mode of combustion. The method includes: producing essentially pure carbon dioxide under elevated pressure and at near ambient temperatures in a Carbon-Dioxide Capture Component from the carbon-dioxide content of at least a part of the gaseous emissions produced from fossil-energy fueled combustion in the Oxyfuel mode of combustion; separating atmospheric air in an Air Separation Component into a stream of liquid nitrogen and a stream of high-purity oxygen; supplying low temperature, compressed purified air to a cryogenic air separation unit (cold box) within the Air Separation Component; collecting low temperature thermal energy from coolers employed within the Carbon-Dioxide Capture Component and the Air Separation Component; and converting the collected thermal energy to electricity within a Thermal-Energy Conversion Component.

Helium can be recovered from nitrogen-rich natural gas at high pressure with low helium loss by cryogenic distillation of the natural gas after pre-treatment of the gas to remove incompatible impurities and then recovery of natural gas liquid (NGL) from the pre-treated gas by distillation. Overall power consumption may be reduced, particularly if the feed to the helium recovery column system is at least substantially condensed by indirect heat exchange against a first portion of nitrogen-enriched bottoms liquid at first pressure, and a second portion of nitrogen-enriched bottoms liquid at a second pressure that is different from the first pressure.

Overall power consumption in a cryogenic distillation process for recovering helium from nitrogen-rich gases comprising helium may be reduced if the feed to the distillation column system is at least substantially condensed by indirect heat exchange against a first bottoms liquid at first pressure, and a second bottoms liquid at a second pressure that is different from the first pressure.

A process for separating carbon dioxide from a fluid containing carbon dioxide, NO.sub.2, and at least one of oxygen, argon, and nitrogen comprises the steps of separating at least part of the fluid into a carbon dioxide enriched stream, a carbon dioxide depleted stream comprising CO.sub.2 and at least one of oxygen, argon, and nitrogen and a NO.sub.2 enriched stream and recycling said NO.sub.2 enriched stream upstream of the separation step.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as a low-pressure tail gas of an ammonia production plant is provided. The disclosed system and method provides for a rectification system wherein an argon depleted gaseous stream and a methane rich liquid stream are produced and subsequently combined in whole or in part prior to vaporization. Nitrogen and argon containing streams may also be produced from the rectification system. An argon stripping column arrangement is also disclosed where residual argon is removed from the methane-rich fuel gas and recycled back to the feed stream.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as tail gas of an ammonia production plant is provided. The disclosed system and method provides for nitrogen-argon rectification and the methane rejection within a column system comprised of at least one distillation column. Nitrogen and argon are further separated and to produce liquid products. An argon stripping column arrangement is disclosed where residual argon is further removed from the methane-rich fuel gas and recycled back to the feed stream.

Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

This method comprises cooling the feed natural gas in a first heat exchanger and introducing the cooled, feed natural gas into a first separation flask. It comprises the dynamic expansion of a turbine supply flow in a first expansion turbine and introducing the expanded flow into a separation column. This method comprises removing, at the head of the separation column, a head flow rich in methane and removing a first recirculation flow from the compressed head flow rich in methane. The method comprises forming at least a second recirculation flow obtained from the head flow rich in methane downstream of the separation column and forming a dynamic expansion flow from the second recirculation flow.