A main heat exchanger receives and partially condenses an effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream including hydrogen and a primary liquid stream including an olefinic hydrocarbon. The main heat exchanger receives and warms at least a portion of the primary vapor stream to provide refrigeration for partially condensing the effluent fluid stream. The main heat exchanger also receives, warms and partially vaporizes the primary liquid stream. A mixed refrigerant compression system also provides refrigeration in the main heat exchanger.

A liquid natural gas (LNG) reforming system of the present invention may include a reformer provided to receive LNG from an LNG tank; a C02 PSA unit connected to the reformer and configured to extract carbon dioxide from off-gas generated from the reformer; a cooler connected to the C02 PSA unit and configured to cool and liquefy the carbon dioxide extracted by the C0.sub.2 PSA unit using the LNG supplied from the LNG tank to the reformer; a storage tank connected to the cooler and provided to store liquid carbon dioxide of the cooler therein; and a circulation pump provided to pump the liquid carbon dioxide from the cooler into the storage tank and circulate a part of the liquid carbon oxide into the cooler.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A system for separating olefinic hydrocarbon and hydrogen in an effluent fluid stream from a dehydrogenation reactor includes a heat exchanger that receives and partially condenses the effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream and a primary liquid product stream. A heat exchanger receives and partially condenses the primary vapor stream so that a mixed phase primary stream is formed. A secondary separation device receives and separates the mixed phase primary stream into a secondary vapor stream and a secondary liquid product stream. A heat exchanger receives and warms the secondary vapor stream to provide refrigeration for partially condensing the effluent fluid stream and a heat exchanger receives and warms the secondary vapor stream to provide refrigeration for partially condensing the primary vapor stream. A mixed refrigerant compression system provides refrigerant to a heat exchanger to provide refrigeration

A carbon dioxide recovery device provided with a separation device that separates carbon dioxide from to-be-separated gas (for example, combustion exhaust gas) containing carbon dioxide, wherein: in order from the upstream side where the to-be-separated gas is supplied, the separation device and carbon dioxide sublimators, which sublimate (solidify) carbon dioxide that was separated in the separation device, are connected in series, refrigerant circuits in which a fluid having cold heat serves as the refrigerant, are connected to the carbon dioxide sublimators, and the refrigerant is used to sublimate (solidify) the carbon dioxide; and when the carbon dioxide is sublimated (solidified), the carbon dioxide sublimators are depressurized and set to negative pressure so as to draw in the carbon dioxide separated at the separation device.

A method for vaporizing liquid propane to be supplied as a raw material to a naphtha cracking ractor. The method comprises: decompressing liquid propane to lower a vaporization point and vaporize at least a portion of the liquid propane; utilizing vaporization heat, generated during vaporization of the portion of liquid propane, as a refrigerant; compressing the vaporized propane gas to increase pressure of the propane gas and produce compressed propane gas; and preheating the compressed propane gas. By using this method, it is possible to reduce pressure of liquid propane to a significantly lower pressure than the related art method so that all the vaporization latent heat or vaporization heat included in liquid propane may be utilized as a refrigerant, while also reducing heat energy consumed in a preheat process before it is supplied to the naphtha cracking reactor.

A process and apparatus reboil a propylene splitter bottoms by heat exchange and/or a deethanizer bottoms stream with a compressed propylene splitter overhead stream. Use of single splitter compressor and operation of the propane-propylene splitter column at lower pressure are enabled, whereas conventionally two splitter compressors and higher splitter pressure were necessary to provide a propylene product stream and a propane recycle stream of equivalent quality.

A system for the removal of nitrogen from a liquid natural gas (LNG) stream. The system. comprises a feed heat changer and a stripper column. The heat receives the LNG stream and cools the LNG stream via heat exchange with a stripper column side-draw stream to yield a cooled LNG stream and a heated side-draw stream. The stripper column receives the cooled LNG stream at a first tray and the heated side-draw stream. The stripper column produces the stripper column side-draw stream, a stripper column overhead stream, and a stripper column bottom stream. The stripper column side-draw stream is taken from the stripper column at a second tray. The second tray is at least about 15 feet higher than the feed heat exchanger.

A method is provided for operating a system for the liquefaction of gas of the type comprising a main heat exchange vessel, a bundle for the gas to be liquefied extending through said MCHE and a refrigerant compression circuit of which a first end leads evaporated refrigerant from the vessel towards a compressor and a second end supplies the compressed and cooled refrigerant from the compressor towards the MCHE. For avoiding problems during heat up or during start up of the heat exchanger the pressure within the liquefaction system is controlled by regulating the amount of evaporated refrigerant in the liquefaction circuit.

A method to condense and recover CO.sub.2 from CO.sub.2 containing streams. A first step involve providing at more than one heat exchanger, with each heat exchanger having a first flow path for passage of a first fluid and a second flow path for passage of a second fluid. A second step involves passing a stream of very cold natural gas sequentially along the second flow path of each heat exchanger until it is heated for distribution and concurrently passing a CO.sub.2 containing stream sequentially along the first flow path of each heat exchanger, allowing the water vapor portion of the CO.sub.2 containing stream to condense and precipitate on the condensing heat exchangers. A third step involves passing a water vapor free CO.sub.2 containing stream to a cryogenic heat exchanger to condense, precipitate and recover CO.sub.2. This processes results in the recovery of CO.sub.2 and water vapor from CO.sub.2 containing streams using condensing heat exchangers, chiller, compressor, expander and power generator to recover the low value thermal heat available in CO.sub.2 containing waste streams.