A method to condense and recover CO.sub.2 from CO.sub.2 containing streams. A first step involve providing at more than one heat exchanger, with each heat exchanger having a first flow path for passage of a first fluid and a second flow path for passage of a second fluid. A second step involves passing a stream of very cold natural gas sequentially along the second flow path of each heat exchanger until it is heated for distribution and concurrently passing a CO.sub.2 containing stream sequentially along the first flow path of each heat exchanger, allowing the water vapor portion of the CO.sub.2 containing stream to condense and precipitate on the condensing heat exchangers. A third step involves passing a water vapor free CO.sub.2 containing stream to a cryogenic heat exchanger to condense, precipitate and recover CO.sub.2. This processes results in the recovery of CO.sub.2 and water vapor from CO.sub.2 containing streams using condensing heat exchangers, chiller, compressor, expander and power generator to recover the low value thermal heat available in CO.sub.2 containing waste streams.

A process for producing liquefied natural gas and liquid carbon dioxide comprising: Step a): separating a natural gas feed gas into a CO.sub.2-enriched gas stream and a CO.sub.2-depleted natural gas stream; Step b): liquefying the CO.sub.2-depleted natural gas stream in a liquefaction unit comprising at least a main heat exchanger and a system for producing frigories, said liquefaction unit comprising at least one refrigeration cycle fed by a refrigerant stream; Step c): simultaneous liquefying of the CO.sub.2-enriched gas stream resulting from step a) in a CO.sub.2 liquefaction unit; wherein the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream and for the liquefaction of the natural gas is supplied by said frigorie-producing system of the liquefaction unit and in that the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream originates from a portion of said refrigerant stream supplying the refrigeration cycle of said liquefaction unit.

A process for producing liquefied natural gas (14) and liquid carbon dioxide (CO.sub.2) (15) comprising at least the following steps: Step a): separating a natural gas feed gas (1), containing hydrocarbons and carbon dioxide in a treatment unit (2), into a CO.sub.2-enriched gas stream (4) and a CO.sub.2-depleted natural gas stream (3); step b): liquefying the CO.sub.2-depleted natural gas stream (3) resulting from step a) in a natural gas liquefaction unit (5) comprising at least a main heat exchanger (8) and a system (9) for producing frigories; step c): simultaneous liquefying of the CO.sub.2-enriched gas stream (4) resulting from step a) in a CO.sub.2 liquefaction unit (6); characterized in that all of the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream (4) and for the liquefaction of the natural gas is supplied by said frigorie-producing system (9) of the natural gas liquefaction unit (5).

A process for producing liquefied natural gas and liquid carbon dioxide from a natural gas feed gas comprising at least the following steps: Separation of a natural gas feed gas into a CO.sub.2-enriched gas stream and a natural gas stream; Cooling of said natural gas in a heat exchanger; Purification of the in step 1 from compounds containing at least six carbon atoms; At least partial condensation of said gas stream resulting from step 3 to form a two-phase stream; Separation of said two-phase stream resulting from step 4 to form a gas stream and a liquid stream; Condensation of the gas stream resulting from step 5 to form a liquefied gas containing less than 5 ppm by volume of compounds containing at least six carbon atoms; Liquefaction of the CO.sub.2-enriched gas stream resulting from step 1 with a portion of the liquid stream resulting from step 5.

A carbon dioxide capture system includes a first heat exchanger configured to exchange heat between an exhaust stream and a lean carbon dioxide effluent stream. The carbon dioxide capture system also includes a first turboexpander including a first compressor driven by a first turbine. The first compressor is coupled in flow communication with the first heat exchanger. The first turbine is coupled in flow communication with the first heat exchanger and configured to expand the lean carbon dioxide effluent stream. The carbon dioxide capture system further includes a carbon dioxide membrane unit coupled in flow communication with the first compressor. The carbon dioxide membrane unit is configured to separate the exhaust stream into the lean carbon dioxide effluent stream and a rich carbon dioxide effluent stream. The carbon dioxide membrane unit is further configured to channel the lean carbon dioxide effluent stream to the first heat exchanger.

Method and system for removing high freeze point components from natural gas. Feed gas is cooled in a heat exchanger and separated into a first vapor portion and a first liquid portion. The first liquid portion is reheated using the heat exchanger and separated into a high freeze point components stream and a non-freezing components stream. A portion of the non-freezing components stream may be at least partially liquefied and received by an absorber tower. The first vapor portion may be cooled and received by the absorber tower. An overhead vapor product which is substantially free of high freeze point freeze components and a bottoms product liquid stream including freeze components and non-freeze components are produced using the absorber tower.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing a startup mode process prior to beginning a normal operation mode process to remove contaminants from a gaseous feed stream. The startup mode process may be utilized for swing adsorption processes, such as TSA and/or PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

A method and system for liquefying a natural gas feed stream and removing nitrogen therefrom.

Lake Kivu contains ˜50 million tonnes (MT) dissolved biomethane. Efficient use is problematic from massive associated CO.sub.2: ˜600 MT. Conventional extraction scrubs CO.sub.2 with ˜50% overall CH.sub.4 loss, and returns ˜80% CO.sub.2 into the deep lake, preserving a catastrophe hazard threatening >2 M people. Methods and systems are disclosed coupling: (1) efficient CH.sub.4+CO.sub.2 degassing; (2) optional oxyfuel power generation and CO.sub.2 power cycle technologies; and (3) CO.sub.2 capture, processing, storage and use in a utilization hub. The invention optimally allows power production with >2× improved efficiency plus cryo-energy storage and large-scale greentech industrialization. CO.sub.2-utilizing products can include: Mg-cements/building materials, algal products/biofuels, urea, bioplastics and recycled materials, plus CO.sub.2 for greenhouse agriculture, CO.sub.2-EOR/CCS, off-grid cooling, fumigants, solvents, carbonation, packaging, ores-, biomass-, and agro-processing, cold pasteurization, frack and geothermal fluids, and inputs to produce methanol, DME, CO, syngas, formic acid, bicarbonate and other greentech chemicals, fuels, fertilizers and carbon products.

A system for removing acid gases from a raw gas stream is provided. The system includes a cryogenic distillation column. The cryogenic distillation column receives a dehydrated and chilled sour gas stream, and separates the sour gas stream into an overhead gas stream comprised primarily of methane, and a bottom acid gas stream comprised primarily of carbon dioxide. The system also includes a series of co-current contactors. The co-current contactors may be placed in series to receive the bottom acid gas stream and recapture any entrained methane gas. Alternatively or in addition, the co-current contactors may be placed in series to receive the overhead gas stream, and sweeten it using a reflux liquid such as methane. In this instance, the sweetened gas is optionally liquefied and delivered for commercial sale, or is used as fuel gas on-site.