One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A process for liquefying hydrogen gas including the following is disclosed: cooling the hydrogen gas to an intermediate temperature by heat exchange with a refrigerant circulating in a refrigeration loop provided with a higher temperature expander and a lower temperature expander, wherein the outlet stream from the lower temperature expander contains some condensed refrigerant; a means is provided of separating the condensate from the circulating refrigerant; and further cooling of the hydrogen gas by heat exchange with evaporation and reheating of the said condensate.

The fluid in the refrigeration loop is typically methane (such as natural gas after removal of carbon dioxide, water vapor and other impurities), or nitrogen, or a mixture thereof.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing an integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen.

An integrated industrial unit is provided, which can include: a nitrogen source configured to provide liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 75 K and 100 K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefaction system.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen. The refrigeration is provided by expansion of a pressurized gaseous nitrogen stream and vaporization of a liquid nitrogen stream that is sourced from a nearby air separation unit.

A SPECTRA process for low-temperature fractionation of air, in which bottoms liquid from an additional second rectification column used to obtain oxygen is evaporated in a second condenser-evaporator. In this second condenser-evaporator, gas that has been evaporated beforehand in a first condenser-evaporator, which is used for condensation of tops gas from a first rectification column, is condensed at the pressure level of the previous evaporation. The invention likewise provides a corresponding plant.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a single heat exchanger, multiple gas-liquid separators, multiple expander/compressor sets, and a rectifier attached to a liquid product drum.

A process and apparatus integrate a deethanizer column with a cryogenic heat exchanger by reboiling the deethanizer column with a refrigerant stream and/or cooling a deethanizer overhead line in the cryogenic heat exchanger. A single stage separator and a single deethanizer column may be used to obtain high purity hydrogen in the net gas stream and an ethane rich off-gas stream, whereas conventionally a dual stage separator and two deethanizer columns were necessary for equivalent purity, respectively.