Processes for separating CO.sub.2 from a gas mixture containing one or more of hydrogen, nitrogen, argon, CO, and methane or a combination thereof is described. The processes involve, for example, cooling and partial condensation of the gas mixture, preferably by a single loop refrigeration system with a mixed refrigerant, phase separation of the partially condensed stream, and distillation of the CO.sub.2-rich liquid stream. At least a portion of the liquid CO.sub.2 produced from the processes during the off-peak electricity demand hours can be stored and then heated, vaporized, further heated, and expanded for power generation during the peak electricity demand hours, helping balance the supply and demand of electricity of the electricity grid.

A carbon dioxide capture system includes a first heat exchanger that exchanges heat between an exhaust stream and a lean carbon dioxide effluent stream. The carbon dioxide capture system also includes a second heat exchanger in flow communication with the first heat exchanger. The second heat exchanger is configured to cool the exhaust stream such that a condensate is formed, and the second heat exchanger is configured to channel a condensate stream for injection into the lean carbon dioxide effluent stream. A first turboexpander including a first compressor is driven by a first turbine. The first compressor is coupled in flow communication with the first heat exchanger. The first turbine is coupled in flow communication with the first heat exchanger and configured to expand the lean carbon dioxide effluent stream. The carbon dioxide capture system further includes a carbon dioxide membrane unit coupled in flow communication with the first compressor.

A system and method for capturing and separating carbon dioxide from mixed gas streams. The gas stream is processed in a structure including a compression module comprising a plurality of compressors, intercoolers and inter-stage condensate separators. The flow path from the compression module includes a plurality of flow separators, gas stream splitters, heat exchangers and at least a first mixer and a first expander. The gas stream is sequentially compressed and cooled to form process condensate and separate it from the compressed gas stream. The gas stream is further dried and cooled to liquefy carbon dioxide and separate it from the non-condensable portion. Selective expansion of liquid carbon dioxide streams provides cooling for the system, and further energy efficiency is achieved by selective recycling of portions of gas streams, allowing for compact equipment and economical operation, while providing for high purity product streams of carbon dioxide.

The present disclosure provides a supercritical compressed air energy storage system. The supercritical compressed air energy storage system includes a supercritical liquefaction subsystem, an evaporation and expansion subsystem, a staged cryogenic storage subsystem, a heat storage and heat exchange subsystem, and a cryogenic energy compensation subsystem, the staged cryogenic storage subsystem being used for implementing the staged storage and release of cryogenic energy, improving efficiency of recovering cryogenic energy during energy release and energy storage, and thereby improving cycle efficiency of the system. The present disclosure does not need to provide any inputs of additional cryogenic energy and heat energy input externally, and has the advantages of high cycle efficiency, low cost, independent operation, environmental friendliness, and no limitation on terrain conditions, and it is suitable for large-scale commercial applications.

A method for improving the capacity of an existing air separation unit employing a lost air turbine is provided in which the capacity is increased by operating the existing air separation unit as previously operated, with the exception of collecting the lost air from the lost air turbine, and instead of venting said lost air to the atmosphere, the lost air is compressed in a supplemental air compressor and returned to the air separation unit at a location downstream a front-end purification unit and upstream a booster. This setup advantageously allows for increased production without having to adjust the sizing of the front-end purification unit or main air compressor.

A liquid air energy storage system comprises an air liquefier, a storage facility for storing the liquefied air, and a power recovery unit coupled to the storage facility. The air liquefier comprises an air input, an adsorption air purification unit for purifying the input air, and a cold box for liquefying the purified air. The power recovery unit comprises a pump for pressurising the liquefied air from the liquid air storage facility, an evaporator for transforming the high-pressure liquefied air into high-pressure gaseous air, an expansion turbine capable of being driven by the high-pressure gaseous air, a generator for generating electricity from the expansion turbine, and an exhaust for exhausting low-pressure gaseous air from the expansion turbine. The exhaust is coupled to the adsorption air purification unit such that at least a portion of the exhausted low-pressure gaseous air is usable to regenerate the adsorption air purification unit.

A proposed method for thermally assisted electric energy storage is intended for increase in round-trip efficiency through recovery of waste heat energy streams from the co-located power generation and industrial facilities, combustion of renewable or fossil fuels, or harnessing the renewable energy sources. In the charge operation mode, it is achieved by superheating and expansion of recirculating air stream in the liquid air energy storage with self-producing a part of power required for air liquefaction. In the discharge operation mode, it is attained through the repeated use of a stream of discharged air for production of an additional power in auxiliary discharge cycle.

In a cryogenic combined cycle power plant electric power drives a cryogenic refrigerator to store energy by cooling air to a liquid state for storage within tanks, followed by subsequent release of the stored energy by first pressurizing the liquid air, then regasifying the liquid air and raising the temperature of the regasified air at least in part with heat exhausted from a combustion turbine, and then expanding the heated regasified air through a hot gas expander to generate power. The expanded regasified air exhausted from the expander may be used to cool and make denser the inlet air to the combustion turbine. The combustion turbine exhaust gases may be used to drive an organic Rankine bottoming cycle. An alternative source of heat such as thermal storage, for example, may be used in place of or in addition to the combustion turbine.

A carbon dioxide capture system includes a first heat exchanger configured to exchange heat between an exhaust stream and a lean carbon dioxide effluent stream. The carbon dioxide capture system also includes a first turboexpander including a first compressor driven by a first turbine. The first compressor is coupled in flow communication with the first heat exchanger. The first turbine is coupled in flow communication with the first heat exchanger and configured to expand the lean carbon dioxide effluent stream. The carbon dioxide capture system further includes a carbon dioxide membrane unit coupled in flow communication with the first compressor. The carbon dioxide membrane unit is configured to separate the exhaust stream into the lean carbon dioxide effluent stream and a rich carbon dioxide effluent stream. The carbon dioxide membrane unit is further configured to channel the lean carbon dioxide effluent stream to the first heat exchanger.

A device includes a heat exchanger connected to an air line through which air flows and to a hydrogen line through which liquid-state hydrogen flows. The heat exchanger is configured to produce liquid-state air as the air and the liquid-state hydrogen exchange heat with each other. The device also includes a carbon dioxide separator connected to the heat exchanger via the air line and the hydrogen line. The carbon dioxide separator is configured to separate at least a portion of carbon dioxide from the air. The device also includes an air storage container connected to the heat exchanger via the air line. The air storage container is configured to store the liquid-state air discharged from the heat exchanger. The carbon dioxide separator is configured such that the air and the hydrogen exchange heat with each other inside the carbon dioxide separator.