The present disclosure relates to systems and methods that provide power generation using predominantly CO.sub.2 as a working fluid. In particular, the present disclosure provides for the use of a portion of the heat of compression from a CO.sub.2 compressor as the additive heating necessary to increase the overall efficiency of a power production system and method.

A process for producing liquefied natural gas and liquid carbon dioxide comprising: Step a): separating a natural gas feed gas into a CO.sub.2-enriched gas stream and a CO.sub.2-depleted natural gas stream; Step b): liquefying the CO.sub.2-depleted natural gas stream in a liquefaction unit comprising at least a main heat exchanger and a system for producing frigories, said liquefaction unit comprising at least one refrigeration cycle fed by a refrigerant stream; Step c): simultaneous liquefying of the CO.sub.2-enriched gas stream resulting from step a) in a CO.sub.2 liquefaction unit; wherein the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream and for the liquefaction of the natural gas is supplied by said frigorie-producing system of the liquefaction unit and in that the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream originates from a portion of said refrigerant stream supplying the refrigeration cycle of said liquefaction unit.

A process for producing liquefied natural gas (14) and liquid carbon dioxide (CO.sub.2) (15) comprising at least the following steps: Step a): separating a natural gas feed gas (1), containing hydrocarbons and carbon dioxide in a treatment unit (2), into a CO.sub.2-enriched gas stream (4) and a CO.sub.2-depleted natural gas stream (3); step b): liquefying the CO.sub.2-depleted natural gas stream (3) resulting from step a) in a natural gas liquefaction unit (5) comprising at least a main heat exchanger (8) and a system (9) for producing frigories; step c): simultaneous liquefying of the CO.sub.2-enriched gas stream (4) resulting from step a) in a CO.sub.2 liquefaction unit (6); characterized in that all of the refrigeration necessary for the liquefaction of the CO.sub.2-enriched gas stream (4) and for the liquefaction of the natural gas is supplied by said frigorie-producing system (9) of the natural gas liquefaction unit (5).

The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO.sub.2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO.sub.2 circulating fluid. Fuel derived CO.sub.2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

Lake Kivu contains ˜50 million tonnes (MT) dissolved biomethane. Efficient use is problematic from massive associated CO.sub.2: ˜600 MT. Conventional extraction scrubs CO.sub.2 with ˜50% overall CH.sub.4 loss, and returns ˜80% CO.sub.2 into the deep lake, preserving a catastrophe hazard threatening >2 M people. Methods and systems are disclosed coupling: (1) efficient CH.sub.4+CO.sub.2 degassing; (2) optional oxyfuel power generation and CO.sub.2 power cycle technologies; and (3) CO.sub.2 capture, processing, storage and use in a utilization hub. The invention optimally allows power production with >2× improved efficiency plus cryo-energy storage and large-scale greentech industrialization. CO.sub.2-utilizing products can include: Mg-cements/building materials, algal products/biofuels, urea, bioplastics and recycled materials, plus CO.sub.2 for greenhouse agriculture, CO.sub.2-EOR/CCS, off-grid cooling, fumigants, solvents, carbonation, packaging, ores-, biomass-, and agro-processing, cold pasteurization, frack and geothermal fluids, and inputs to produce methanol, DME, CO, syngas, formic acid, bicarbonate and other greentech chemicals, fuels, fertilizers and carbon products.

A system for removing acid gases from a raw gas stream is provided. The system includes a cryogenic distillation column. The cryogenic distillation column receives a dehydrated and chilled sour gas stream, and separates the sour gas stream into an overhead gas stream comprised primarily of methane, and a bottom acid gas stream comprised primarily of carbon dioxide. The system also includes a series of co-current contactors. The co-current contactors may be placed in series to receive the bottom acid gas stream and recapture any entrained methane gas. Alternatively or in addition, the co-current contactors may be placed in series to receive the overhead gas stream, and sweeten it using a reflux liquid such as methane. In this instance, the sweetened gas is optionally liquefied and delivered for commercial sale, or is used as fuel gas on-site.

The invention relates to a method and apparatus for removing CO.sub.2 gas emissions from a coal combustion power plant, comprising a means for physically removing the CO.sub.2 gas from the coal, and then using a turbo compressor and turbo expander device to produce super chilled air, which can then be mixed with the CO.sub.2 gas to form frozen CO.sub.2 crystals which can agglomerate together to form dry ice blocks, wherein the ice blocks can be easily transported and stored, and/or used for commercial purposes (such as for the beverage industry). The heating (compression) and cooling (expansion) processes preferably generate additional energy which can then be used to offset the substantial costs associated with separating the CO.sub.2 gas from the coal.

A method and a plant for producing liquid CO.sub.2 from flue gas as described with reduced energy consumption and a stable behavior.

A cryogenic method for capturing carbon dioxide in the gaseous emissions produced from the fossil-energy combustion of solid, liquid, or gaseous fossil fuels in a power generation installation employing an OxyFuel mode of combustion. The method includes: producing essentially pure carbon dioxide under elevated pressure and at near ambient temperatures in a Carbon-Dioxide Capture Component from the carbon-dioxide content of at least a part of the gaseous emissions produced from fossil-energy fueled combustion in the Oxyfuel mode of combustion; separating atmospheric air in an Air Separation Component into a stream of liquid nitrogen and a stream of high-purity oxygen; supplying low temperature, compressed purified air to a cryogenic air separation unit (cold box) within the Air Separation Component; collecting low temperature thermal energy from coolers employed within the Carbon-Dioxide Capture Component and the Air Separation Component; and converting the collected thermal energy to electricity within a Thermal-Energy Conversion Component.

A set of process equipment for use in an enhanced oil recovery (EOR) process comprises first piping, a dehydrator, second piping, and a natural gas liquids recovery column. The first piping is configured to receive a wet carbon dioxide recycle stream from a recovery well. The dehydrator is configured to receive the wet carbon dioxide stream from the first piping and configured to dehydrate the wet carbon dioxide recycle stream using ethylene glycol to produce a dry carbon dioxide recycle stream. The second piping is configured to receive the dry carbon dioxide recycle stream from the dehydrator. The natural gas liquids recovery column is configured to receive the dry carbon dioxide recycle stream from the second piping and configured to separate the dry carbon dioxide recycle stream into a carbon dioxide reinjection stream and a natural gas liquids stream.