A system for the regeneration of nitrogen energy within a closed loop cryogenic system is described. A liquid nitrogen storage is provided in fluid communication with a first flow line. A pump pumps liquid nitrogen from the liquid nitrogen storage to the first flow line. At least one cryogenic cooling loop is provided in fluid communication with the first flow line. The cryogenic cooling loop has an nitrogen intake and a nitrogen outlet with the nitrogen outlet being positioned downstream of the nitrogen intake. The cryogenic cooling loop has a heat exchanger between the nitrogen intake and the nitrogen outlet. A turbo expander used for re-cooling the nitrogen flowing through the first flow line and the at least one cryogenic cooling loop has an inlet and an outlet. The inlet is provided in fluid communication with the first flow line. The turbo expander is connected to a power source. A second flow line connects the outlet of the turbo expander to the liquid nitrogen storage.

A refrigeration system for use in petrochemical plants, such as an ethylene production plant includes a refrigerant vent rectifier. The rectifier purifies the refrigerant by removing low molecular weight inerts. The refrigeration system is more efficient, consumes less energy and increases plant capacity.

The invention relates to an integrated process and apparatus for liquefaction of natural gas and recovery of natural gas liquids. In particular, the improved process and apparatus reduces the energy consumption of a Liquefied Natural Gas (LNG) unit by using a portion of the already cooled overhead vapor from a fractionation column from an NGL (natural gas liquefaction) unit to, depending upon composition, provide, for example, reflux for fractionation in the NGL unit and/or a cold feed for the LNG unit, or by cooling, within the NGL unit, a residue gas originating from a fractionation column of the NGL unit and using the resultant cooled residue gas to, depending upon composition, provide, for example, reflux/feed for fractionation in the NGL and/or a cold feed for the LNG unit, thereby reducing the energy consumption of the LNG unit and rendering the process more energy-efficient.

Method and Apparatus for separating at least one CO isotope compound, especially isotope compound 13C16O, from natural CO, comprising: a rectification column system (110) comprising a plurality of rectification sections (112,114,116,118,120) arranged adjacent to one another in a chain-like manner, including an upper rectification section (112) and a plurality of lower rectification sections (114,116,118,120), each rectification section comprising a heating means (112a,114a,116a,118a,120a) to maintain evaporation of liquid present therein, provided that the heating means (112a) of the at least one of the plurality of rectification sections (112) is provided to comprise a heat pump cycle (112b).

An apparatus for using nitrogen within a closed loop cryogenic system is described. A cryochamber is provided that has a first nitrogen flow line with an inlet for connection to a nitrogen source and an outlet. At least one cryogenic cooling loop is provided that has a nitrogen inlet and a nitrogen outlet. The nitrogen inlet and outlet are in fluid communication with the first nitrogen flow line. The nitrogen inlet is positioned upstream of the nitrogen outlet. A heat exchanger is provided on the at least one cryogenic cooling loops through which the nitrogen passes. The heat exchanger has a fluid inlet and a fluid outlet. A turbo expander is in fluid communication with the outlet of the first nitrogen flow line and the nitrogen source. The turbo expander re-cools the nitrogen that passes through the first flow line and the at least one cryogenic cooling loop.

A process for co-producing a liquid oxygen and a liquefied hydrocarbon stream, including introducing a gaseous hydrocarbon stream and a gaseous nitrogen stream into a liquefier, thereby producing a liquefied hydrocarbon stream and a liquid nitrogen stream, liquefying a gaseous oxygen stream, wherein at least a portion of the required refrigeration is obtained from the liquid nitrogen stream. Wherein the liquefied hydrocarbon stream and the liquefied gaseous oxygen stream have mass flow rates. The liquid oxygen stream may be produced in an aft separation unit, wherein at least a portion of the required refrigeration is obtained from the liquid nitrogen stream.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as a low-pressure tail gas of an ammonia production plant is provided. The disclosed system and method provides for a rectification system wherein an argon depleted gaseous stream and a methane rich liquid stream are produced and subsequently combined in whole or in part prior to vaporization. Nitrogen and argon containing streams may also be produced from the rectification system. An argon stripping column arrangement is also disclosed where residual argon is removed from the methane-rich fuel gas and recycled back to the feed stream.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as tail gas of an ammonia production plant is provided. The disclosed system and method provides for nitrogen-argon rectification and the methane rejection within a column system comprised of at least one distillation column. Nitrogen and argon are further separated and to produce liquid products. An argon stripping column arrangement is disclosed where residual argon is further removed from the methane-rich fuel gas and recycled back to the feed stream.

Certain embodiments of the invention relate to a facility for refrigerating a fluid to a cryogenic temperature, comprising a circuit for the fluid to be refrigerated, comprising an upstream end connected to a source and a downstream end connected to a refrigerated and/or liquefied fluid collection member, the facility comprising at least one exchanger for precooling the fluid leaving the upstream end, the precooling exchanger exchanging heat with a precooling circuit composed of a flow of vaporization gas from a user, the facility further comprising a heat exchanger assembly for cooling by heat exchange with the circuit of fluid to be cooled downstream of the precooling exchanger, the facility comprising a device for cooling by heat exchange with at least a part of the cooling heat exchanger assembly, said cooling device comprising a first refrigerator with a refrigeration cycle of a cycle gas in a working circuit, the cycle gas preferably comprising hydrogen and/or helium, the working circuit of the first refrigerator comprising a member for compressing the cycle gas, a member for cooling the cycle gas, a member for expanding the cycle gas and a member for heating the cycle gas, the precooling exchanger being composed of at least one of the following materials: stainless steel or grades of stainless steel, Inconel, nickel, titanium or plastic material compatible with use at cryogenic temperatures.

A technology liquefies natural gas. The natural gas liquefaction method pre-cools treated natural gas by ethane evaporation, sub-cools liquefied gas using cooled nitrogen as a refrigerant, reduces liquefied gas pressure, separates non-liquefied gas and diverts liquefied natural gas. Before pre-cooling the natural gas is compressed, ethane is evaporated during the multi-stage pre-cooling of liquefied gas with simultaneous evaporation of ethane using cooled ethane as a refrigerant. Ethane generated by evaporation is compressed, condensed and used as a refrigerant during the cooling of liquefied gas and nitrogen, with nitrogen being compressed, cooled, expanded and fed to the natural gas sub-cooling stage. The natural gas liquefaction unit contains a natural gas liquefaction circuit, an ethane circuit and a nitrogen circuit. The natural gas liquefaction circuit includes a natural gas compressor, a cooler unit, ethane vaporizers, a closed-end subcooling heat exchanger, and a separator, connected in series.