An exhaust gas treatment system includes in order: an intake for receiving an exhaust gas from a lean burn combustion engine; an injector for the provision of a nitrogenous reductant; a close-coupled vanadium-containing SCR catalyst composition; one or more downstream PGM-containing oxidation catalyst compositions, wherein the close-coupled vanadium-containing SCR catalyst composition includes cerium in a Ce:V molar ratio of greater than 0.3.

A honeycomb filter includes: a honeycomb structure having porous partition walls disposed so as to surround cells, and plugging portions disposed at any one of ends on the inflow end face and the ends on the outflow end face, of cells. In a cross section perpendicular to an extending direction of the cells, a thickness T1 of the partition walls in a central portion including a center of gravity O of the cross section is 0.17 to 0.32 mm, a thickness T2 of the partition walls in an outer peripheral portion is 70 to 90% of the thickness T1, and the outer peripheral portion extends from an outer peripheral edge of the cross section of honeycomb structure by 6 to 12% of a radius r which is from the center of gravity O of the cross section to the outer peripheral edge.

A thin-walled honeycomb body (100) having a plurality of repeating cell structures (110) formed of intersecting porous thick walls (112V, 112H) and thin walls (114V, 114H). Each repeating cell structure (110) is bounded on its periphery by the thick walls (112V, 122H) of a first transverse thickness (Tk) and the thin walls (114V, 114H) have a second transverse thickness (Tt) that subdivides each repeating cell structure (110) into between 7 and 36 individual cells (108). In the thin-walled honeycomb body (100), the first transverse thickness (Tk) of the thick walls (112V, 112H) is less than or equal to 0.127 mm (0.005 inch) and the second transverse thickness (Tt) of the thin walls (114V, 114H) is less than or equal to 0.0635 mm (0.0025 inch), and Tk>Tt. Honeycomb extrusion dies and methods of manufacturing the thin-walled honeycomb body (100) having thick walls (112V, 112H) and thin walls (114V, 114H) are provided.

A compression ignition internal combustion engine (30) for a heavy-duty diesel vehicle comprising an exhaust system (32) comprising a composite oxidation catalyst (12, 42) and a soot filter substrate (44, 50) disposed downstream from the composite oxidation catalyst comprising: a substrate (5), preferably a honeycomb flow-through substrate monolith, having a total length L and a longitudinal axis and having a substrate surface extending axially between a first substrate end (I) and a second substrate end (O); two catalyst washcoat zones (1, 2) arranged axially in series on and along the substrate surface, wherein a first catalyst washcoat zone (1) having a length L.sub.1 and comprising a first catalyst washcoat layer (9), wherein L.sub.1<L, is defined at one end by the first substrate end (I) and at a second end by a first end (15) of a second catalyst washcoat zone (2) having a length L.sub.2 and comprising a second catalyst washcoat layer (11), wherein L.sub.2<L, wherein the second catalyst washcoat zone (2) is defined at a second end thereof by the second substrate end (O), and wherein the first substrate end (I) of the composite oxidation catalyst (12, 42) is oriented to an upstream side and wherein the first catalyst washcoat zone (1) comprises a first refractory metal oxide support material and two or more platinum group metal components supported thereon comprising both platinum and palladium at a weight ratio of platinum to palladium of <1; and the second catalyst washcoat zone (2) comprises a second refractory metal oxide support material and one or more platinum group metal components supported thereon; and a washcoat overlayer (G) extending axially from the first substrate end (I) comprising a particulate metal oxide having a loading of >48.8 g/l (>0.8 g/in.sup.3), wherein a total platinum group metal loading in the first catalyst washcoat zone (1) defined in grams of platinum group metal per litre of substrate volume (g/l) is greater than a total platinum group metal loading in the second catalyst washcoat zone (2) and wherein the first catalyst washcoat zone (1) comprises one or more first alkaline earth metal components, preferably barium, supported on the first refractory metal oxide support material.

A method of manufacturing a ceramic honeycomb structure by mixing a ceramic precursor batch composition having a median particle diameter less than or equal to about 10 μm and at least one starch-based pore former having a median particle diameter greater than or equal to about 10 μm. The method also includes forming a mixture of ceramic precursor batch composition and a starch-based pore former into a green ceramic structure having a web structure, and firing the green ceramic structure to yield a ceramic honeycomb structure.

A honeycomb body (300) including a plurality of radially-extending walls (322) intersecting with a plurality of circumferentially-extending walls (324), the plurality of radially-extending walls (322) and the plurality of circumferentially-extending walls (324) form a plurality of circumferential zones (334A, 334B, 334C) of cells (308). The plurality of circumferential zones (334A, 334B, 334C) of cells (308) includes a first zone of cells (334A) including two or more first rings of cells (330) and having a first cell density, and a second zone of cells (334B) including two or more rings of cells (330) having varying cell densities across the two or more rings of cells. Other structures and extrusion dies are disclosed.

A diesel engine emissions catalyst which may be used to fill a niche between standard oxidation catalyst and diesel particulate filters for control of diesel particulate matter. The catalyst includes a structure (substrate) comprising one or more coated, corrugated micro-expanded metal foil layers. The coated surface may be a high surface area, stabilized, and promoted washcoat layer. The corrugated pattern may include a herringbone-style pattern that, when in use, is oriented in a longitudinal direction of the diesel engine exhaust flow. The micro-expanded metal foil provides small openings or eyes that, as the exhaust flow passes through the catalyst (transverse to the eye opening), particulates in the flow impinge on the surface and becomes trapped in the eyes. The catalyst may be used to treat a locomotive engine exhaust stream and may be used with a selective catalyst reduction system.

An exhaust gas purification catalyst device having a substrate and one or more catalytic noble metals supported on the substrate. The substrate has a plurality of cells partitioned by a porous wall 1 and includes ceria-zirconia compound oxide particles. A specific noble metal that is one of the one or more catalytic noble metals satisfies both the following requirements (1) and (2): (1) the noble metal 50% support depth for the specific noble metal is 30% or less of the distance from the surface of the porous wall 1 to the center of the interior of the porous wall 1, and (2) the noble metal 90% support depth for the specific noble metal is 35% or more of the distance from the surface of the porous wall 1 to the center of the interior of the porous wall 1.

A catalytic converter includes a catalyst substrate including a body having a length and defining a plurality of zones along the length, with each zone having at least one cross-sectional structure defining a plurality of cells forming an exhaust gas flow path through the length via cells of adjacent zones, and the cells being more densely arranged within the at least one cross-sectional structure of an upstream zone than an adjacent downstream zone. The catalytic converter also includes a wash-coat layer deposited on surfaces of the cells forming active surface area configured to react with exhaust gas traveling along the length. The exhaust gas flows along the exhaust gas flow path through the cells such that more active surface area is available for reaction in each upstream zone than an adjacent downstream zone.

An exhaust purification system may include at least one catalyst in an exhaust flow path of an internal combustion engine to decrease gaseous pollutants from an exhaust gas, a first particulate filter downstream of the catalyst, and a second particulate filter with a porosity lower and a lower mean pore size than the first particulate filter and in a bypass flow line downstream of the first particulate filter, the bypass flow line being configured to open and close based on at least one condition of the exhaust purification system or conditions of the exhaust gas. The second particulate filter may be configured to be removed and replaced when full. A method of purifying an exhaust gas through the exhaust purification system is also described.