A reformer assembly includes a vortex tube receiving heated fuel mixed with steam. A catalyst coats the inner wall of the main tube of the vortex tube and a hydrogen-permeable tube is positioned in the middle of the main tube coaxially with the main tube. With this structure the vortex tube outputs primarily Hydrogen from one end and Carbon-based constituents from the other end. In some embodiments a second vortex tube receives the Carbon output of the first vortex tube to establish a water gas shift reactor, producing Hydrogen from the Carbon output of the first vortex tube.

A co-generation process for a regenerator in an FCC system having a reactor and a regenerator includes the steps of introducing flue gas from the regenerator into a heating unit at a first location of the heating unit, and introducing an oxygen/fuel gas mixture into the heating unit at a second location of the heating unit apart from the first location, and combusting the oxygen/fuel gas mixture in the heating unit at the second location to form a hot combustion gas. The process further includes the steps of combining the hot combustion gas and the flue gas at a third location of the heating unit apart from the first location to produce heated flue gas, heating water and/or steam with the heated flue gas to produce a heated steam, and introducing the heated steam into a turbine to extract energy from the heated steam.

A mixture of air and fuel is received into a reaction chamber of a gas turbine system. The fuel is oxidized in the reaction chamber, and a maximum temperature of the mixture in the reaction chamber is controlled to be substantially at or below an inlet temperature of a turbine of the gas turbine system. The oxidation of the fuel is initiated by raising the temperature of the mixture to or above an auto-ignition temperature of the fuel. In some cases, the reaction chamber may be provided without a fuel oxidation catalyst material.