A hollow turbine airfoil or a hollow turbine casting including a cooling passage partition. The cooling passage partition is formed from a single crystal grain structure nickel based super alloy, a cobalt based super alloy, a nickel-aluminum based alloy, or a coated refractory metal.

A system comprises a gas turbine engine including a compressor, combustor, gas turbine, the combustor including a plurality of late lean fuel injectors; and wash system configured to be attached to and in fluid communication with the a plurality of late lean fuel injectors of the combustor. The wash system includes a water source supplying water; a first fluid source supplying a first fluid; a mixing chamber in communication with the water source and first fluid source; a water pump to pump water to the mixing chamber; a first fluid pump to pump the first fluid to the mixing chamber; a fluid line in fluid communication with the mixing chamber and at least one of the plurality of late lean fuel injectors so fluid from the mixing chamber is injected into the combustor at late lean fuel injectors. The wash system is operated with the gas turbine engine off-line.

A gas turbine engine system includes a compressor, gas turbine, and combustor including a plurality of late lean fuel injectors supplied with secondary fuel to its interior. The gas turbine engine system includes a wash system in communication with the late lean fuel injectors. The wash system includes a water source; water pump; anti-corrosion agent fluid source with an anti-corrosion agent including a polyamine corrosion inhibitor; anti-corrosion agent supply piping in fluid communication with the anti-corrosion agent fluid source; mixing chamber receiving water and anti-corrosion agent to produce an anti-corrosion mixture in fluid communication with the mixing chamber and the plurality of late lean fuel injectors. Fluid from the mixing chamber including the water, the anti-corrosion agent fluid source, or a mixture thereof is injected, while the gas turbine engine is off-line, into the combustor at at least one of the plurality of late lean fuel injectors.

A hollow turbine airfoil or a hollow turbine casting including a cooling passage partition. The cooling passage partition is formed from a single crystal grain structure nickel based super alloy, a cobalt based super alloy, a nickel-aluminum based alloy, or a coated refractory metal.

A coated substrate is provided that includes an environmental barrier coating on (e.g., directly on) a surface of a substrate (e.g., a ceramic matrix composite). The environmental barrier coating can include a barrier layer having a refractory material phase and a silicon-containing glass phase. The silicon-containing glass phase may be a continuous phase within the barrier layer (e.g., a breathable grain boundary of the barrier layer), or may be a plurality of discontinuous layers dispersed throughout the refractory material phase. The refractory material phase can include a rare earth silicate material having a rare earth component at a first atomic percent, while the silicon-containing glass phase comprises the rare earth component at a second atomic percent that is less than the first atomic percent. Methods are also provided for forming a barrier layer on a substrate.

There is provided a cobalt-based alloy product comprising: Co, C, N, B, Cr, Fe, Ni, W, Mo, Al, Si, and/or Mn with predetermined contents, and 0.5-4 mass % of an M component. The M component is a transition metal other than W and Mo and having an atomic radius of more than 130 pm. The product is a polycrystalline body of matrix phase crystal grains in which segregation cells are formed. There are at least two kinds of regions of the segregation cells wherein: a first region has an average size of 0.13-1.3 μm; a second region has an average size of 0.25-2 μm; and the average size of the second region is 1.3 times or more larger than that of the first region.

A structure which is resistant to corrosion at high temperatures comprises a layer of ruthenium and/or ruthenium alloy and a layer of a refractory metal having a high strength at high temperatures, such as rhenium. Further, the structure may include a layer of ceramic such as zirconia or hafnia on the exposed face of the ruthenium layer. Alternative embodiments of the present invention include a catalyst formed from a low strength support structure with a first metal layer and a second ruthenium catalytic layer on top of the first metal layer. Another alternative embodiment of the present invention includes the formation of high purity ruthenium electrodes that are resistant to corrosion at high temperatures.

A nickel-based superalloy includes, in weight percent, 4 to 6% aluminum, 5 to 8% cobalt, 6 to 9% chromium, 0.1 to 0.9% hafnium, 2 to 4% molybdenum, 5 to 7% rhenium, 5 to 7% tantalum, 2 to 5% tungsten, 0 to 0.1% silicon, the balance being of nickel and unavoidable impurities.

A gas turbine component includes a substrate and a corrosion resistant layer coupled to the substrate. The corrosion resistant layer includes zirconium silicate and is configured to protect the substrate from exposure to a vanadium corrodent.

A component for a gas turbine engine according to an exemplary embodiment of the present disclosure can include a substrate, a thermal barrier coating deposited on at least a portion of the substrate, and an outer layer deposited on at least a portion of the thermal barrier coating. The outer layer can include a material that is reactive with an environmental contaminant that comes into contact with the outer layer to alter a microstructure of the outer layer.