One aspect of the invention provides a composite refrigeration line set including at least one selected from the group consisting of: a suction line and a return line, characterized in that one or more of the suction line and the return line are a composite refrigeration line set tube include: an inner plastic tube; a first adhesive layer positioned about the inner plastic tube; an aluminum layer positioned about the first adhesive layer and coupled to the inner plastic tube via the first adhesive layer; a second adhesive layer positioned about the aluminum layer; and an outer plastic layer positioned about the aluminum layer coupled to the aluminum layer via the second adhesive layer. The inner plastic tube is polyethylene of raised temperature. The outer plastic tube is polyethylene of raised temperature. The aluminum layer comprises AL 3555-O.

One aspect of the invention provides a composite refrigeration line set including at least one selected from the group consisting of: a suction line and a return line, characterized in that one or more of the suction line and the return line are a composite refrigeration line set tube include: an inner plastic tube; a first adhesive layer positioned about the inner plastic tube; an aluminum layer positioned about the first adhesive layer and coupled to the inner plastic tube via the first adhesive layer; a second adhesive layer positioned about the aluminum layer; and an outer plastic layer positioned about the aluminum layer coupled to the aluminum layer via the second adhesive layer. The inner plastic tube is polyethylene of raised temperature. The outer plastic tube is polyethylene of raised temperature. The aluminum layer comprises AL 3004-O.

A monolithic metal thermal insulating sleeve liner for fluid flow devices such as valves and piping used in severe industrial applications is additively manufactured (e.g., by 3D printing) to fit the bore of a protected fluid flow device. Tessellated support structures obliquely extending between inside surfaces of inner and outer shells provide increased resistance to thermal conduction while also providing increased strength against compression forces. Example support structures include an array of four obliquely oriented elongated members mutually intersecting mid-way between the inside surfaces of inner and outer cylindrical shells. If internal interstices are sealed they can be vacuumed or pressurized to enhance thermal insulating properties. A pressure equalizing aperture can be provided on or through the sleeve if needed in some applications.

A composite article has an increased peel strength and includes a first layer including a low surface energy polymer. The composite article also includes a poly(meth)acrylate layer, an epoxide layer, and a polyurethane elastomer layer. The poly(meth)acrylate layer is disposed on and in direct contact with the first layer. Moreover, the poly(meth)acrylate layer includes a poly(meth)acrylate that includes the reaction product of at least one (meth)acrylate that is polymerized in the presence of an organoborane initiator. The epoxide layer is disposed on and in direct contact with the poly(meth)acrylate layer. The polyurethane elastomer layer is disposed on and in direct contact with the epoxide layer. The composite article has a 90 peel strength of at least 50 pli measured using ASTM D6862.

A pipe-in-pipe section comprises an inner pipe spaced within an outer pipe to define an annulus between the inner and outer pipes. The annulus contains a solid insulating material, which may be a microporous aerogel, and an inert gas such as krypton at near-atmospheric pressure.

One aspect of the invention provides a composite tube including: an inner plastic tube; an aluminum layer circumferentially surrounding the inner plastic tube; and an outer plastic layer circumferentially surrounding the aluminum layer. The aluminum layer is an alloy selected from the group consisting of: AL 3004, AL 3005, AL 3105, AL 5052, AL 6061, and AL 8006. The aluminum layer has a thickness within a corresponding range disclosed for the alloy in Table 2. Another aspect of the invention provides: a composite tube including: an inner plastic tube; an aluminum layer circumferentially surrounding the inner plastic tube; and an outer plastic layer circumferentially surrounding the aluminum layer. The aluminum layer can be an alloy having 0.1% or greater magnesium by mass.

A system for packing and assembling a flexible duct that includes a sleeve. The sleeve includes a tubular vapor barrier and an insulating layer within the vapor barrier and includes a central cavity. Further, the sleeve is radially compressed and rolled along an axial direction. The system also includes an air core sized to fit within the central cavity of the insulating layer. The air core includes a sheet that blocks fluid flow therethrough and a structural support coiled within the sheet and the air core is flattenable and not within the rolled sleeve.

A composite article has increased pull-off strength and includes a first layer including a low surface energy polymer, a poly(meth)acrylate layer, and an epoxide layer. The poly(meth)acrylate layer is disposed on and in direct contact with the first layer. Moreover, the poly(meth)acrylate layer includes a poly(meth)acrylate that includes the reaction product of at least one (meth)acrylate that is polymerized in the presence of an organoborane initiator. The epoxide layer is disposed on and in direct contact with the poly(meth)acrylate layer. The epoxide layer includes an epoxide. The composite article has a pull-off strength of greater than zero pli measured using ASTM D4541.

A subsea pipeline has a steel pipe surrounded by a thermally-insulating coating system having at least one thermal insulation layer. The thermal insulation layer has a thermally-insulating matrix in which elongate tensile elements of a thermoplastic polymer, such as monofilament yarns, are embedded. The pipe is preheated to promote bonding between the matrix and the elongate elements and between successive layers of the coating system.

A composite article is formed by disposing a poly(meth)acrylate layer, formed as the reaction product of at least one acrylate that is polymerized in the presence of an organoborane initiator, on and in direct contact with a low surface energy polymer layer, disposing an epoxide layer on and in direct contact with said poly(meth)acrylate layer, and disposing a hydrolytically resistant layer on and in direct contact with said epoxide layer. The hydrolytically resistant layer is a hydrolytically resistant polyurethane elastomer that is the reaction product of an aliphatic isocyanate component and an isocyanate-reactive component that retains at least 90% of its initial tensile strength after submersion in standardized seawater for 24 weeks. The isocyanate-reactive component is a hydroxyl-functional polymer having an average hydroxy functionality ranging from 2 to 3, wherein the hydroxyl-functional polymer is a dimer diol, a trimer triol, or a combination thereof.