A carbon sequestration system includes a furnace having an oxy-combustion burner, a mill configured to receive a fuel and to provide the fuel to the oxy-combustion burner, a waste heat recovery exchanger configured to receive a flue gas from the furnace, the flue gas ultimately supplied to one or more of an overfire air port of the furnace, the oxy-combustion burner, the mill, and a CO.sub.2 purification unit, the CO.sub.2 purification unit configured to produce a purified CO.sub.2 stream.