An oxygen fired fluidized bed combustor system (Oxy-FBC) is provided. The system provides means of producing a nearly pure stream of carbon dioxide for storage at high efficiency by controlling the oxygen content within certain regions of the combustor to control the rate of heat release allowing efficient transfer of heat from the combustor to the boiler tubes while avoiding excessively high temperatures that will cause ash melting, and simultaneously remove sulphur from the combustor via sorbents such as limestone and dolomite. The present invention utilizes a coarse oxygen carrier bed material to distribute heat and oxygen throughout an Oxy-FBC, while injecting fine sulphur sorbent that will continuously be removed from the bed.

A fluidized bed boiler plant and a method of preheating combustion gas in a fluidized bed boiler plant. The boiler plant includes a furnace and a combustion gas channel, and a water-steam cycle including an evaporator section, a superheater section including a last superheater and a steam turbine, and a superheating path for conveying steam from the evaporator section via the superheater section to the steam turbine, and a first combustion gas preheater. The fluidized bed boiler plant includes a second combustion gas preheater, a steam extraction line attached in flow connection with the second combustion gas preheater and with the superheating path in a location upstream of the last superheater for conveying steam from the superheating path to the second combustion gas preheater.

A chemical looping combustion (CLC) based power generation, particularly using liquid fuel, ensures substantially complete fuel combustion and provides electrical efficiency without exposing metal oxide based oxygen carrier to high temperature redox process. An integrated fuel gasification (reforming)-CLC-followed by power generation model is provided involving (i) a gasification island, (ii) CLC island, (iii) heat recovery unit, and (iv) power generation system. To improve electrical efficiency, a fraction of the gasified fuel may be directly fed, or bypass the CLC, to a combustor upstream of one or more gas turbines. This splitting approach ensures higher temperature (efficiency) in the gas turbine inlet. The inert mass ratio, air flow rate to the oxidation reactor, and pressure of the system may be tailored to affect the performance of the integrated CLC system and process.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500 C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500 C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

In accordance with one embodiment of the present disclosure, an oxygen carrying material may include a primary active mass, a primary support material, and a secondary support material. The oxygen carrying material may include about 20% to about 70% by weight of the primary active mass, the primary active mass including a composition having a metal or metal oxide selected from the group consisting of Fe, Co, Ni, Cu, Mo, Mn, Sn, Ru, Rh, and combinations thereof. The oxygen carrying material may include about 5% to about 70% by weight of a primary support material. The oxygen carrying material may include about 1% to about 35% by mass of a secondary support material.

In accordance with one embodiment of the present disclosure, an oxygen carrying material may include a primary active mass, a primary support material, and a secondary support material. The oxygen carrying material may include about 20% to about 70% by weight of the primary active mass, the primary active mass including a composition having a metal or metal oxide selected from the group consisting of Fe, Co, Ni, Cu, Mo, Mn, Sn, Ru, Rh, and combinations thereof. The oxygen carrying material may include about 5% to about 70% by weight of a primary support material. The oxygen carrying material may include about 1% to about 35% by mass of a secondary support material.

A reactor fluid supply system, a reactor system comprising such a fluid supply system, a method of supplying fluid into a reactor, and a method of operating a reactor system are provided. Preferably, the reactor system comprises a fluidised bed pyrolysis or combustion reactor and a fluid injector. The injector may comprise an internal flow passage extending from an inlet to an outlet, and have a first section including the inlet and a first portion of the passage and a second section including the outlet and a second portion of the passage. There may be a temperature regulator for controlling fluid temperature in the second section of the injector, the regulator comprising a cooling fluid jacket surrounding the second portion of the internal flow passage. The second section of the injector may be located inside the reactor so that the outlet of the injector is positioned in the fluidised bed of the reactor.

A reactor fluid supply system, a reactor system comprising such a fluid supply system, a method of supplying fluid into a reactor, and a method of operating a reactor system are provided. Preferably, the reactor system comprises a fluidised bed pyrolysis or combustion reactor and a fluid injector. The injector may comprise an internal flow passage extending from an inlet to an outlet, and have a first section including the inlet and a first portion of the passage and a second section including the outlet and a second portion of the passage. There may be a temperature regulator for controlling fluid temperature in the second section of the injector, the regulator comprising a cooling fluid jacket surrounding the second portion of the internal flow passage. The second section of the injector may be located inside the reactor so that the outlet of the injector is positioned in the fluidised bed of the reactor.

The invention relates to a plant and to a method for chemical looping oxidation-reduction combustion of a gaseous hydrocarbon feed, for example natural gas essentially containing methane. According to the invention, catalytic pre-reforming of the feed is performed in a pre-reforming zone comprising a fixed reforming catalyst, while benefiting from a heat transfer between the reduction or oxidation zone of the chemical loop and the pre-reforming zone adjoining the reduction or oxidation zone. Pre-reforming zone (130) and oxidation zone (110) or pre-reforming zone (130) and reduction zone (120) are thus thermally integrated within the same reactor (100) while being separated by at least one thermally conductive separation wall (140).