A fluidizing gas nozzle head suitable to be connected to a fluidizing gas feeding device of a fluidized bed reactor. The fluidizing gas nozzle head includes an inlet channel having a longitudinal axis, an inlet end, and a second end, the inlet end of the inlet channel being adapted to connect the inlet channel in vertical gas flow connection with the fluidizing gas feeding device, four outlet channels, each of the four outlet channels extending from a first end to an outlet end, and a gas distribution space having a bottom face and a ceiling opposite to the bottom face. The second end of the inlet channel and the first ends of the four outlet channels are connected to direct gas flow connection with the gas distribution space. Each of the first ends of the four outlet channels has a central point, which central points define a rectangle with two long sides and two short sides having an aspect ratio of at least 2:1.

A fluidizing gas nozzle head suitable to be connected to a fluidizing gas feeding device of a fluidized bed reactor. The fluidizing gas nozzle head includes an inlet channel having a longitudinal axis, an inlet end, and a second end, the inlet end of the inlet channel being adapted to connect the inlet channel in vertical gas flow connection with the fluidizing gas feeding device, four outlet channels, each of the four outlet channels extending from a first end to an outlet end, and a gas distribution space having a bottom face and a ceiling opposite to the bottom face. The second end of the inlet channel and the first ends of the four outlet channels are connected to direct gas flow connection with the gas distribution space. Each of the first ends of the four outlet channels has a central point, which central points define a rectangle with two long sides and two short sides having an aspect ratio of at least 2:1.

A circulating fluidized bed (CFB) boiler has one or more bubbling fluidized bed enclosures containing heating surfaces and located within a lower portion of the CFB boiler to provide an in-bed heat exchanger (IBHX). Solids in the bubbling fluidized bed are maintained in a slow bubbling fluidized bed state by separately controlled fluidization gas supplies. The beds feature open bottom distribution grids with hoppers disposed below to collect solids. The enclosure defining the IBHX is supported from structures below the grids and the enclosure can be supported from the hoppers.

A circulating fluidized bed (CFB) boiler has one or more bubbling fluidized bed enclosures containing heating surfaces and located within a lower portion of the CFB boiler to provide an in-bed heat exchanger (IBHX). Solids in the bubbling fluidized bed are maintained in a slow bubbling fluidized bed state by separately controlled fluidization gas supplies. The beds feature open bottom distribution grids with hoppers disposed below to collect solids. The enclosure defining the IBHX is supported from structures below the grids and the enclosure can be supported from the hoppers.

Contamination of fluidized bed-produced polycrystalline granules by phosphorus is reduced by employing as seals and/or packings, graphite containing <500 ppmw of phosphorus.

The disclosure provides a tri-metallic ferrite oxygen carrier for the chemical looping combustion of carbonaceous fuels. The tri-metallic ferrite oxygen carrier comprises Cu.sub.xFe.sub.yMn.sub.zO.sub.4-δ, where Cu.sub.xFe.sub.yMn.sub.zO.sub.4-δ is a chemical composition. Generally, 0.5≦x≦2.0, 0.2≦y≦2.5, and 0.2≦z≦2.5, and in some embodiments, 0.8≦x≦1.2, y≦1.2, and z≧0.8. The tri-metallic ferrite oxygen carrier may be used in various applications for the combustion of carbonaceous fuels, including as an oxygen carrier for chemical looping combustion.

An apparatus for controlling flow of a material includes an inlet for receiving the material from a source, and a seal mechanism connected to the inlet, the seal mechanism having a fluidizing bed configured to receive the material from the inlet, a first discharge passageway and a second discharge passageway. The fluidizing bed includes a first transport zone associated with the first discharge passageway and a second transport zone associated with the second discharge passageway, wherein the first and second transport zones are configured to receive transport gas from a transport gas source. The transport gas is controllable to selectively divert a flow of the material into the first discharge passageway and the second discharge passageway.

An apparatus for controlling flow of a material includes an inlet for receiving the material from a source, and a seal mechanism connected to the inlet, the seal mechanism having a fluidizing bed configured to receive the material from the inlet, a first discharge passageway and a second discharge passageway. The fluidizing bed includes a first transport zone associated with the first discharge passageway and a second transport zone associated with the second discharge passageway, wherein the first and second transport zones are configured to receive transport gas from a transport gas source. The transport gas is controllable to selectively divert a flow of the material into the first discharge passageway and the second discharge passageway.

The present invention provides a circulating fluidized bed boiler, comprising: furnace side walls; a ceiling; an air distribution plate provided at a bottom of a furnace; and at least one air distribution cone provided on the air distribution plate, wherein each air distribution cone extends upwards from the air distribution plate into an interior of the furnace and has a shape gradually tapered in an extending direction, cone side walls which form the air distribution cone are provided with secondary air ports, the cone side walls are separated from the furnace side walls, and a furnace combustion space is formed and surrounded by the ceiling, the furnace side walls, the air distribution plate, and the cone side walls. The present invention further relates to an air distributor for a circulating fluidized bed boiler, the air distributor being provided on an air distribution plate of the boiler, wherein the air distributor is in a form of an air distribution cone, which extends upwards from the air distribution plate into an interior of a furnace to form a shape gradually tapered in an extending direction, and secondary air ports are formed in air distribution cone side walls forming the air distribution cone. The present invention also relates to an air distributor assembly for a circulating fluidized bed boiler.

The present invention provides a circulating fluidized bed boiler, comprising: furnace side walls; a ceiling; an air distribution plate provided at a bottom of a furnace; and at least one air distribution cone provided on the air distribution plate, wherein each air distribution cone extends upwards from the air distribution plate into an interior of the furnace and has a shape gradually tapered in an extending direction, cone side walls which form the air distribution cone are provided with secondary air ports, the cone side walls are separated from the furnace side walls, and a furnace combustion space is formed and surrounded by the ceiling, the furnace side walls, the air distribution plate, and the cone side walls. The present invention further relates to an air distributor for a circulating fluidized bed boiler, the air distributor being provided on an air distribution plate of the boiler, wherein the air distributor is in a form of an air distribution cone, which extends upwards from the air distribution plate into an interior of a furnace to form a shape gradually tapered in an extending direction, and secondary air ports are formed in air distribution cone side walls forming the air distribution cone. The present invention also relates to an air distributor assembly for a circulating fluidized bed boiler.