A chemical looping combustion (CLC) process for sour gas combustion is integrated with a gas turbine combined cycle and a steam generation unit, and is configured to provide in-situ removal of H.sub.2S from the sour gas fuel by reacting the H.sub.2S with a oxygen carrier at a location within the fuel reactor of the CLC unit. The process is also configured such that oxygen-rich exhaust gases from the gas turbine combined cycle is used to feed the air reactor of the CLC unit and re-oxidize oxygen carriers for recirculation in the CLC unit.

A dual-bed system for preventing a boiler heating surface from being contaminated comprises a fluidized bed, a cyclone separator, a coal ash distributor, an ash-coal mixer, a lower pyrolysis bed, a return feeder and a cleaner, wherein the cyclone separator is connected with the upper lateral side of the fluidized bed; the inlet end of the coal ash distributor; the two outlets of the coal ash distributor are respectively connected with the inlet of the return feeder and the inlet of the ash-coal mixer; the outlet of the ash-coal mixer is connected with the inlet of the lower pyrolysis bed; the return feeder close to the lower lateral side of the fluidized bed is connected with the inlet on the lower lateral side of the fluidized bed; and the outlet of the cleaner is connected with the inlet on the lower lateral side of the fluidized bed.

A dual-bed system for preventing a boiler heating surface from being contaminated comprises a fluidized bed, a cyclone separator, a coal ash distributor, an ash-coal mixer, a lower pyrolysis bed, a return feeder and a cleaner, wherein the cyclone separator is connected with the upper lateral side of the fluidized bed; the inlet end of the coal ash distributor; the two outlets of the coal ash distributor are respectively connected with the inlet of the return feeder and the inlet of the ash-coal mixer; the outlet of the ash-coal mixer is connected with the inlet of the lower pyrolysis bed; the return feeder close to the lower lateral side of the fluidized bed is connected with the inlet on the lower lateral side of the fluidized bed; and the outlet of the cleaner is connected with the inlet on the lower lateral side of the fluidized bed.

Methods and devices for combusting a carbonaceous fuel in an oxy-combustion fluidized bed reactor involving controlling the local oxygen content within the oxy-combustion reactor to specified levels. The carbonaceous fuel and an oxygen-containing gas are introduced into a fluidized bed reactor and eluted through a fluidized bed of an inert material, dolomite or a combination thereof to combust the fuel and oxygen to produce at least CO.sub.2 and steam. The oxygen-containing gas is a mixture of oxygen, recycled CO.sub.2 and steam and has sufficient oxygen added to the recycled CO.sub.2 and steam that the mixture contains 7-20 mole % oxygen. The carbonaceous fuel and the oxygen-containing gas are introduced into the fluidized bed at a location in sufficiently close proximity to each other to avoid producing a reducing atmosphere at the location. At least a portion of the produced CO.sub.2 and steam are recycled to the reactor.

Methods and devices for combusting a carbonaceous fuel in an oxy-combustion fluidized bed reactor involving controlling the local oxygen content within the oxy-combustion reactor to specified levels. The carbonaceous fuel and an oxygen-containing gas are introduced into a fluidized bed reactor and eluted through a fluidized bed of an inert material, dolomite or a combination thereof to combust the fuel and oxygen to produce at least CO.sub.2 and steam. The oxygen-containing gas is a mixture of oxygen, recycled CO.sub.2 and steam and has sufficient oxygen added to the recycled CO.sub.2 and steam that the mixture contains 7-20 mole % oxygen. The carbonaceous fuel and the oxygen-containing gas are introduced into the fluidized bed at a location in sufficiently close proximity to each other to avoid producing a reducing atmosphere at the location. At least a portion of the produced CO.sub.2 and steam are recycled to the reactor.

A fluidized fuel gas combustor system for a catalytic dehydrogenation process comprising a vessel having a lower portion and an upper portion; a plurality of air injection diffusers located in the lower portion of the vessel; a plurality of fuel gas injection diffusers located on fuel gas distributors disposed in the vessel and spaced apart from and above a plurality of air injection diffusers, wherein the fuel gas diffusers are placed in a manner to maximize even mass distribution of a fuel gas injected through the fuel gas diffusers in the vessel, wherein each fuel distributor comprises a tube having a plurality of fuel gas injection diffusers; and one or more grid assemblies disposed in the vessel spaced above the fuel gas distributors is provided.

A fluidized fuel gas combustor system for a catalytic dehydrogenation process comprising a vessel having a lower portion and an upper portion; a plurality of air injection diffusers located in the lower portion of the vessel; a plurality of fuel gas injection diffusers located on fuel gas distributors disposed in the vessel and spaced apart from and above a plurality of air injection diffusers, wherein the fuel gas diffusers are placed in a manner to maximize even mass distribution of a fuel gas injected through the fuel gas diffusers in the vessel, wherein each fuel distributor comprises a tube having a plurality of fuel gas injection diffusers; and one or more grid assemblies disposed in the vessel spaced above the fuel gas distributors is provided.

A feed injector for a circulating fluid bed reactor is fitted with a discharge nozzle with a circular, radially notched discharge orifice to improve the surface-to-volume ratio of the spray pattern formed by the nozzle. The feed injector is useful for injecting fluids into various types of circulating fluid bed reactors in which good contact between the components of the fluidized bed and the injected fluid is required. It is particularly useful in fluid coking reactors.

A feed injector for a circulating fluid bed reactor is fitted with a discharge nozzle with a circular, radially notched discharge orifice to improve the surface-to-volume ratio of the spray pattern formed by the nozzle. The feed injector is useful for injecting fluids into various types of circulating fluid bed reactors in which good contact between the components of the fluidized bed and the injected fluid is required. It is particularly useful in fluid coking reactors.

A reactor system includes plural batch-cyclic reduction/oxidation (redox) reactors. One reactor is operated in fuel mode while another is operated in air mode, and vice-versa. For each reactor in air mode, air is introduced via air-only tuyeres and via fuel-air tuyeres to oxidize oxidation particles. For each reactor in fuel mode, fuel is introduced via the reactor's fuel-air tuyeres and not via its air-only tuyeres. As a result, air is introduced at a higher rate than fuel is introduced so that the oxidation rate can match the reduction rate. Thus, for example, as few as two reactors can be used for continuous power generation without having to shuttle oxidation particles between reactors.