The present disclosure provides a cerium-zirconium-based composite oxide with a core-shell structure and a preparation method thereof, a catalyst system using the cerium-zirconium-based composite oxide, a catalytic converter for purifying tail gas by using the catalyst system, and application of the catalyst system or the catalytic converter in motor vehicle exhaust purification, industrial waste gas treatment or catalytic combustion. In the present invention, the cerium-zirconium-based composite oxide with a core-shell structure oxygen storage material is prepared by a step-by-step precipitation method. On the one hand, yttrium and a part of zirconium and cerium are precipitated on a cerium-zirconium surface, where the post-precipitation of yttrium is to segregate yttrium ions (Y.sup.3+) on a grain boundary surface, thus reducing lattice surface energy, pinning the grain boundary surface, making the migration of the grain boundary surface difficult, controlling the growth of grains.

The present disclosure relates to a cerium-zirconium-based composite oxide having gradient element distribution and a preparation method therefor. According to the present disclosure, the cerium-zirconium-based composite oxide having gradient element distribution is prepared by a step-by-step precipitation method. First, a zirconium-rich component is precipitated to form a crystal structure and a crystal grain stack structure which have high thermal stability, slow down the segregation of zirconium on a surface after high-temperature treatment, and reduce element migration among crystal grains; second, a cerium-rich component is precipitated to improve the cerium content of the surface layers of the crystal grains, improve the utilization rate of the cerium element, and improve the oxygen storage amount and the oxygen storage rate.

The integrated device for adsorptive purification and catalytic regeneration of VOCs is provided and includes a filtration adsorption coupling filter, a catalytic combustion regeneration box and a housing, where the housing includes a filter inner cavity and a combustion inner cavity that are communicated in sequence. The VOC exhaust gas is adsorbed and filtered by the filtration adsorption coupling filter. Moreover, under an operating condition of desorption regeneration, the catalytic combustion regeneration box is utilized to perform thermal desorption and regeneration on the filtration adsorption coupling filter, and catalytically combust and purify the VOC exhaust gas obtained by thermal desorption.

The integrated device for adsorptive purification and catalytic regeneration of VOCs is provided and includes a filtration adsorption coupling filter, a catalytic combustion regeneration box and a housing, where the housing includes a filter inner cavity and a combustion inner cavity that are communicated in sequence. The VOC exhaust gas is adsorbed and filtered by the filtration adsorption coupling filter. Moreover, under an operating condition of desorption regeneration, the catalytic combustion regeneration box is utilized to perform thermal desorption and regeneration on the filtration adsorption coupling filter, and catalytically combust and purify the VOC exhaust gas obtained by thermal desorption.

A composite material is used for desulfurization. The composite material contains activated carbon, alkali metal oxides, silicon oxides, iron oxides, and rare earth element oxides. The weight ratio among the activated carbon, iron oxides and rare earth element oxides is 100:(0.5-5):(1-10). The composite material, used as a sulfur adsorbent, has a higher sulfur breakthrough capacity and desulfurization rate.

A molecular sieve complex contains an oxide of aluminum, an oxide of an alkaline earth metal and a rare earth-modified molecular sieve. The rare earth-modified molecular sieve is a molecular sieve doped by a rare earth element. The percentage of the pore volume occupied by pores of 3 nm or less to the total pore volume in the molecular sieve complex is greater than or equal to 63.5%. The content of the rare earth element and the contents of the oxide of aluminum, the oxide of the alkaline earth metal and the molecular sieve satisfy a certain relationship. The composite material contains a molecular sieve complex and an auxiliary agent loaded on the molecular sieve complex, and the composite material may be applied to flue gas adsorption and desulfurization.

Disclosed are a VOC treatment rotor system and a VOC treatment method. The system comprises: a rotor having a first adsorption zone and a second adsorption zone; a gas intake pipeline communicated with an inlet of the first adsorption zone; a gas outlet pipeline comprising a gas outlet main pipe, a gas outlet branch pipe and a first clean gas outlet pipe; a second clean gas outlet pipe, communicated with an outlet of the second adsorption zone. The treatment method comprises: making VOC-containing waste gas enter the first adsorption zone through the gas intake pipeline for adsorption treatment by the first adsorption zone, then enter the gas outlet main pipe, and then enter the second adsorption zone through the gas outlet branch pipe or be discharged from the first clean gas outlet pipe.

Disclosed are a VOC treatment rotor system and a VOC treatment method. The system comprises: a rotor having a first adsorption zone and a second adsorption zone; a gas intake pipeline communicated with an inlet of the first adsorption zone; a gas outlet pipeline comprising a gas outlet main pipe, a gas outlet branch pipe and a first clean gas outlet pipe; a second clean gas outlet pipe, communicated with an outlet of the second adsorption zone. The treatment method comprises: making VOC-containing waste gas enter the first adsorption zone through the gas intake pipeline for adsorption treatment by the first adsorption zone, then enter the gas outlet main pipe, and then enter the second adsorption zone through the gas outlet branch pipe or be discharged from the first clean gas outlet pipe.

A combustion ash handling method of handling combustion ash discharged from a combustion furnace that combusts a petroleum-based fuel includes: separating the combustion ash into a heavy component and a light component by a dry-type separation technique; feeding the light component to the combustion furnace as a fuel; and recovering the heavy component. A metal such as vanadium is separated and extracted from the heavy component of the combustion ash.

A non-bypassable catalyst assisted appliance includes, for example, a housing having a combustion chamber, a loading door, an air inlet opening, and an exit opening connectable to a flue. A platform defines a non-movable separation in the housing between the combustion chamber and the exit opening. An insulated catalyst combustor is disposed between a top wall of the housing and the platform. When the door of the appliance is closed, gas from the combustion chamber is exhausted and directed along a single flow path horizontally through the insulated catalytic combustor and into the flue. When the door of the appliance is open, gas from the combustion chamber is inhibited from passing through the loading door opening, and ambient air entering the loading door opening and combustion gas from the combustion chamber are exhausted and directed along a single flow path horizontally through the insulated catalytic combustor and into the flue.