F25J1/0012

High energy recovery nitric acid process using liquid oxygen containing fluid
11905172 · 2024-02-20 · ·

A novel concept for a high energy and material efficient nitric acid production process and system is provided, wherein the nitric acid production process and system, particularly integrated with an ammonia production process and system, is configured to recover a high amount of energy out of the ammonia that it is consuming, particularly in the form of electricity, while maintaining a high nitric acid recovery in the conversion of ammonia to nitric acid. The energy recovery and electricity generation process comprises pressurizing a liquid gas, such as air, oxygen and/or N.sub.2, subsequently evaporating and heating the pressurized liquid gas, particularly using low grade waste heat generated in the production of nitric acid and/or ammonia, and subsequently expanding the evaporated pressurized liquid gas over a turbine. In particular, the generated electricity is at least partially used to power an electrolyzer to generate the hydrogen needed for the production of ammonia. The novel concepts set out in the present application are particularly useful in the production of nitric acid based on renewable energy sources.

Staged cryogenic storage type supercritical compressed air energy storage system and method

The present disclosure provides a supercritical compressed air energy storage system. The supercritical compressed air energy storage system includes a supercritical liquefaction subsystem, an evaporation and expansion subsystem, a staged cryogenic storage subsystem, a heat storage and heat exchange subsystem, and a cryogenic energy compensation subsystem, the staged cryogenic storage subsystem being used for implementing the staged storage and release of cryogenic energy, improving efficiency of recovering cryogenic energy during energy release and energy storage, and thereby improving cycle efficiency of the system. The present disclosure does not need to provide any inputs of additional cryogenic energy and heat energy input externally, and has the advantages of high cycle efficiency, low cost, independent operation, environmental friendliness, and no limitation on terrain conditions, and it is suitable for large-scale commercial applications.

Integrated pre-cooled mixed refrigerant system and method

A system and method for cooling and liquefying a gas in a heat exchanger that includes compressing and cooling a mixed refrigerant using first and last compression and cooling cycles so that high pressure liquid and vapor streams are formed. The high pressure liquid and vapor streams are cooled in the heat exchanger and then expanded so that a primary refrigeration stream is provided in the heat exchanger. The mixed refrigerant is cooled and equilibrated between the first and last compression and cooling cycles so that a pre-cool liquid stream is formed and subcooled in the heat exchanger. The stream is then expanded and passed through the heat exchanger as a pre-cool refrigeration stream. A stream of gas is passed through the heat exchanger in countercurrent heat exchange with the primary refrigeration stream and the pre-cool refrigeration stream so that the gas is cooled. A resulting vapor stream from the primary refrigeration stream passage and a two-phase stream from the pre-cool refrigeration stream passage exit the warm end of the exchanger and are combined and undergo a simultaneous heat and mass transfer operation prior to the first compression and cooling cycle so that a reduced temperature vapor stream is provided to the first stage compressor so as to lower power consumption by the system. Additionally, the warm end of the cooling curve is nearly closed further reducing power consumption. Heavy components of the refrigerant are also kept out of the cold end of the process, reducing the possibility of refrigerant freezing, as well as facilitating a refrigerant management scheme.

INDUSTRIAL AND HYDROCARBON GAS LIQUEFACTION
20190360747 · 2019-11-28 ·

Liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) to chill the gas or gas mixture during the liquefaction process. The gas is compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. A Joule Thomson (JT) adiabatic expansion process results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapour absorber tower (VAT) that permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapour is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may operate at pressures as low as 10 kPa, and the ammonia gas chiller may operate at temperatures as low as 71 C.

Liquid air power and storage
10473029 · 2019-11-12 ·

Apparatus, systems, and methods store energy by liquefying a gas such as air, for example, and then recover the energy by regasifying the liquid and combusting or otherwise reacting the gas with a fuel to drive a heat engine. The process of liquefying the gas may be powered with electric power from the grid, for example, and the heat engine may be used to generate electricity. Hence, in effect these apparatus, systems, and methods may provide for storing electric power from the grid and then subsequently delivering it back to the grid.

NITROGEN PRODUCTION METHOD AND NITROGEN PRODUCTION APPARATUS

A portion of feed air is expanded and cooled in front of a main heat exchanger, and is used as cold for precooling the remaining unexpanded feed air inside the main heat exchanger. A portion of the feed air precooled inside the main heat exchanger is removed to outside the main heat exchanger, expanded and cooled, and used as cold to cool the remaining unexpanded precooled feed air inside the main heat exchanger.

CRYOGENIC COOLING SYSTEM FOR AN AIRCRAFT

A cryogenic cooling system for an aircraft includes a first air cycle machine, a second air cycle machine, and a means for collecting liquid air. The first air cycle machine is operable to output a cooling air stream based on a first air source. The second air cycle machine is operable to output a chilled air stream at a cryogenic temperature based on a second air source cooled by the cooling air stream of the first air cycle machine. An output of the second air cycle machine is provided to the means for collecting liquid air.

CHILLED WORKING FLUID GENERATION AND SEPARATION FOR AN AIRCRAFT
20190292982 · 2019-09-26 ·

A system for an aircraft includes an engine bleed source of a gas turbine engine. The system also includes a means for chilling an engine bleed air flow from the engine bleed source to produce a chilled working fluid. The system further includes a means for providing the chilled working fluid for an aircraft use.

PROPULSION SYSTEM COOLING CONTROL
20190293346 · 2019-09-26 ·

A propulsion system includes an electric fan propulsion motor with a plurality of propulsion motor windings. The propulsion system also includes a means for controlling a flow rate of a working fluid through a cryogenic working fluid flow control assembly to the propulsion motor windings.

Industrial and hydrocarbon gas liquefaction
10415878 · 2019-09-17 ·

A method for liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) that is used to chill the gas or gas mixture during the liquefaction process. The gas may be compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. The method utilizes a Joule Thomson (JT) adiabatic expansion process which results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapor absorber tower (VAT) which permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapor is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may achieve operating pressures as low as 10 kPa which results in ammonia gas chiller operating temperatures as low as 71 C.