A process for producing liquefied natural gas and liquid carbon dioxide from a natural gas feed gas comprising at least the following steps: Separation of a natural gas feed gas into a CO.sub.2-enriched gas stream and a natural gas stream; Cooling of said natural gas in a heat exchanger; Purification of the in step 1 from compounds containing at least six carbon atoms; At least partial condensation of said gas stream resulting from step 3 to form a two-phase stream; Separation of said two-phase stream resulting from step 4 to form a gas stream and a liquid stream; Condensation of the gas stream resulting from step 5 to form a liquefied gas containing less than 5 ppm by volume of compounds containing at least six carbon atoms; Liquefaction of the CO.sub.2-enriched gas stream resulting from step 1 with a portion of the liquid stream resulting from step 5.

A method for liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) that is used to chill the gas or gas mixture during the liquefaction process. The gas may be compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. The method utilizes a Joule Thomson (JT) adiabatic expansion process which results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapor absorber tower (VAT) which permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapor is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may achieve operating pressures as low as 10 kPa which results in ammonia gas chiller operating temperatures as low as 71 C.

A molten carbonate fuel cell-powered system for capturing carbon dioxide produced by a steam methane reformer system. Tail gas from a pressure swing adsorption system is mixed with exhaust gas from the fuel cell anode, then pressurized and cooled to extract liquefied carbon dioxide. The residual low-CO.sub.2 gas is directed to an anode gas oxidizer, to the anode, to the reformer to be burned for fuel, and/or to the pressure swing adsorption system. Low-CO.sub.2 flue gas from the reformer can be vented to the atmosphere or directed to the anode gas oxidizer. Reduction in the amount of CO.sub.2 reaching the fuel cell allows the fuel cell to be sized according to the power demands of the system and eliminates the need to export additional power output.

A marine vessel and method for carbon capture and sequestration are described. The marine vessel includes a buoyant hull, a cryogenic storage tank within the hull, and a gaseous carbon dioxide loading manifold. The marine vessel also includes a carbon dioxide liquefaction system in fluid communication with the cryogenic storage tank downstream of the carbon dioxide liquefaction system and with the gaseous carbon dioxide loading manifold upstream of the carbon dioxide liquefaction system. Finally, the marine vessel includes a carbon dioxide supercritical system in fluid communication with the cryogenic storage tank. In operation, the marine vessel moves between multiple locations, where gaseous carbon dioxide is onboarded, liquified and stored. Thereafter, the marine vessel transports the liquified carbon dioxide to a location adjacent an offshore geological reservoir. The liquefied carbon dioxide is then pressurized to produce supercritical carbon dioxide, which is then injected directly into the reservoir from the marine vessel.

A method for automatically dispensing and vending carbon dioxide (CO2) snow block is disclosed. The automatic dispensing system contains multiple containers of different volumes. A user can input the volume of CO2 snow block into a controller, such as a programmable logic controller (PLC). The controller uses the inputted volume and process information to determine which container to utilize for the automated filling process. The controller can configure the selected container into a filling orientation into which liquid CO2 can flow to generate CO2 snow block. Upon detection of the completion of the fill, the container is configured into a dispensing orientation from which the CO2 snow block is released into an access region from which the user can retrieve the CO2 snow block. The control methodology may also be used to auto charge a single container located within a charging station as disclosed herein.

Embodiments described herein provide methods and systems for separating a mixed ethane and CO.sub.2. A method described includes generating a liquid stream including ethane and CO.sub.2. The liquid stream is flashed to form an ethane vapor stream and solid CO.sub.2. The solid CO.sub.2 is accumulated in an accumulation vessel and the gas is removed from the top of the accumulation vessel.

A combined plant for cryogenic separation and liquefaction of methane and carbon dioxide in a biogas stream, including a mixing means, a compressor, a first exchanger, a distillation column, a second exchanger, a separating means, an expanding means, and a separator vessel. Wherein, the mixing means is configured such that the recycle gas is the overhead vapour stream, and the first exchanger and the expanding means are combined.

The device (100) for cooling a flow (101) of a target fluid predominantly comprising dihydrogen, comprises: a first heat exchanger (105) configured to cool an intermediate refrigerant fluid (110) by heat exchange with an expanded dioxygen flow (115), an intermediate closed circuit (120) for transporting the intermediate refrigerant fluid from the first heat exchanger to a second heat exchanger (125), a means (130) for compressing the intermediate refrigerant fluid along the intermediate closed circuit, the intermediate refrigerant fluid, configured to remain in the liquid or supercritical state at least upon passing through the compression means and the second heat exchanger configured to cool the target fluid flow by heat exchange with the intermediate refrigerant fluid cooled in the first heat exchanger.

The present invention relates to a method for removing carbon dioxide (CO.sub.2) from a CO.sub.2-containing stream, the method at least comprising the steps of: a) providing a CO.sub.2-containing stream (10), preferably air wherein the CO.sub.2-containing stream (10) has a CO.sub.2 content in the range of from 10 to 1000 ppmv, preferably from 100 to 1000 ppmv; b) removing CO.sub.2 from the CO.sub.2-containing stream (10) provided in step a) in a first CO.sub.2 removal unit (2), thereby obtaining a first CO.sub.2-enriched stream (30) and a first CO.sub.2-depleted stream (20); c) liquefying the first CO.sub.2-enriched stream (30) obtained in step b) in a liquefaction unit (3); d) removing from the liquefaction unit (3) at least a liquefied CO.sub.2 stream (40) and a gaseous stream (15) containing at least nitrogen [N.sub.2 (g)], oxygen [O.sub.2 (g)] and CO.sub.2 (g).

A method of capturing carbon dioxide from a steam methane reformer system includes mixing tail gas from the steam methane reformer system with anode exhaust gas from an anode of a molten carbonate fuel cell to form a gas mixture, compressing the gas mixture, cooling the gas mixture, and separating the gas mixture into liquid carbon dioxide and a residual gas mixture.