The present invention relates to a cold box cycle which allows for independent control of the heat supplied for reboilers associated with the separation columns. More specifically, the invention relates to the tight control of the hydrogen removal separation, thus avoiding the possibility of excess reboiling in this separation. Optimal reboiling also results in a lower temperature of the hydrogen depleted liquid from this separation. As this stream is used to provide a portion of the cooling at the cold end of the primary heat exchanger, lower temperatures facilitate cooling of the incoming syngas feed, reducing carbon monoxide (CO) losses into the crude hydrogen stream from the high pressure separator. Lower CO in the crude hydrogen allows for smaller hydrogen purification equipment.

The method for producing liquid hydrogen can include the steps of: introducing pressurized natural gas from a high pressure natural gas pipeline to a gas processing unit under conditions effective for producing a purified hydrogen stream; and introducing the purified hydrogen stream to a hydrogen liquefaction unit under conditions effective to produce a liquid hydrogen stream, wherein the hydrogen liquefaction unit provides a warm temperature cooling and a cold temperature cooling to the purified hydrogen stream, wherein the warm temperature cooling is provided by utilizing letdown energy of a pressurized stream selected from the group consisting of a nitrogen stream sourced from a nitrogen pipeline, a natural gas stream sourced from the high pressure natural gas pipeline, an air gas sourced from an air separation unit, and combinations thereof, wherein the cold temperature is provided by utilizing letdown energy of the purified hydrogen stream.

A liquid air energy storage system comprises an air liquefier, a liquid air storage facility for storing the liquefied air, and a power recovery unit coupled to the liquid air storage facility. The air liquefier comprises an air input, an adsorption air purification unit for purifying the input air, and a cold box for liquefying the purified air. The power recovery unit comprise a pump for pressurizing the liquefied air from the liquid air storage facility; an evaporator for transforming the high-pressure liquefied air into high-pressure gaseous air; an expansion turbine capable of being driven by the high-pressure gaseous air; a generator for generating electricity from the expansion turbine; and an exhaust for exhausting low-pressure gaseous air from the expansion turbine. The exhaust is coupled to the adsorption air purification unit such that at least a portion of the low-pressure gaseous air exhausted from the expansion turbine is usable to regenerate the adsorption air purification unit.

The present invention generally relates to a method to enhance heat transfer in the temperature swing adsorption process (TSA) and to an intensified TSA process for gas/liquid purification or bulk separation. Helium is designed as the heat carrier media to directly bring heat/cool to the adsorbent bed during the TSA cycling process. With helium's superior heat conductivity, the time consuming regeneration steps (warming, regeneration and precooling) of TSA process can be significantly reduced and allowing for the TSA process to be intensified.

The present disclosure relates to systems and methods useful for providing one or more chemical compounds in a substantially pure form. In particular, the systems and methods can be configured for separation of carbon dioxide from a process stream, such as a process stream in a hydrogen production system. As such, the present disclosure can provide systems and method for production of hydrogen and/or carbon dioxide.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve passing streams through adsorbent bed units to remove contaminants, such as water, from the stream. As part of the process, the adsorbent bed unit is purged with a purge stream that is provided from the overhead of the demethanizer. The configuration integrates a RCTSA dehydration system with a cryogenic recovery system.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve passing streams through adsorbent bed units to remove contaminants, such as water, from the stream. As part of the process, the adsorbent bed unit is purged with a purge stream that is provided at a temperature less than 450 F. The de-contaminated stream may be used with a liquefied natural gas (LNG) plant or other subsequent process requiring a de-contaminated stream. The swing adsorption process may involve a combined TSA and PSA process, which is utilized to remove contaminants from the feed stream.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve passing streams through adsorbent bed units to remove contaminants, such as water, from the stream. As part of the process, the adsorbent bed unit is purged with a purge stream that is provided from the overhead of the demethanizer. The configuration integrates a PPSA dehydration system with a cryogenic recovery system.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve passing streams through adsorbent bed units to treat the pipeline quality natural gas to form a stream that complies with liquefied natural gas (LNG) specifications. The process may involve a combined TSA and PSA process, which is utilized to remove contaminants from the feed stream.

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve passing streams through adsorbent bed units to treat the feed stream to form a stream that complies with nitrogen rejection specifications. The process may involve using at least a portion of the nitrogen rejection process product streams as a purge for the swing adsorption process.