A crude helium stream is recovered from a natural gas feed by distillation. Refrigeration from expanding a portion of the bottoms liquid is used to partially condense the helium-enriched overhead vapor and generate a crude helium vapor and a helium-containing liquid stream that is recycled to the distillation column to maximize helium recovery. The helium-depleted natural gas stream can be returned at pressure for utilization or transportation.

A liquid air energy storage system comprises an air liquefier, a storage facility for storing the liquefied air, and a power recovery unit coupled to the storage facility. The air liquefier comprises an air input, an adsorption air purification unit for purifying the input air, and a cold box for liquefying the purified air. The power recovery unit comprises a pump for pressurising the liquefied air from the liquid air storage facility, an evaporator for transforming the high-pressure liquefied air into high-pressure gaseous air, an expansion turbine capable of being driven by the high-pressure gaseous air, a generator for generating electricity from the expansion turbine, and an exhaust for exhausting low-pressure gaseous air from the expansion turbine. The exhaust is coupled to the adsorption air purification unit such that at least a portion of the exhausted low-pressure gaseous air is usable to regenerate the adsorption air purification unit.

A moderate pressure, argon and nitrogen producing cryogenic air separation unit and air separation cycle having a higher pressure column, a lower pressure column and an argon column arrangement is disclosed. The moderate pressure, argon and nitrogen producing cryogenic air separation unit is configured to take a first portion of an oxygen enriched stream from the lower pressure column, which together with an external source of liquid nitrogen is used as the boiling side refrigerant to condense the argon in the argon condenser. Use of the external source of liquid nitrogen in the argon condenser allows a second portion of the oxygen enriched stream from the lower pressure column to be taken as a liquid oxygen product stream.

A method for producing power and argon is provided by providing a residual gas stream, purifying the residual gas stream in a front-end purification unit to remove carbon dioxide, thereby forming a purified residual gas stream, and introducing the purified residual gas stream to a cold box, wherein the purified residual gas stream is cooled and expanded within the cold box to produce power and then fed to a distillation column system for separation therein, thereby forming an argon-enriched stream and optionally a nitrogen-enriched stream and/or an oxygen-enriched stream, wherein the residual gas stream is sourced from a retentate stream of a cold membrane having oxygen, nitrogen, carbon dioxide, and argon.

A process for removing CO.sub.2 from a methane-containing gas, having the steps of providing a methane-containing gas containing at least CO.sub.2 as an impurity, cooling the gas to remove CO.sub.2 from the methane-containing gas by freezing out same, and additionally reducing the CO.sub.2 concentration of the gas using a pressure temperature swing adsorption apparatus (PTSA), whereby a methane-enriched product gas is obtained. At least a part of the product gas is then used as treatment gas and is passed through the PTSA for treatment of the PTSA, whereby CO.sub.2 is absorbed by the treatment gas and is removed from the PTSA as a CO.sub.2-enriched treatment gas. The treatment gas is then recycled and admixed with the methane containing gas.

In a process for the combined production of a) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or b) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, a still liquor is extracted from a scrubbing column and sent to a stripping column, a still liquor is extracted from the stripping column and sent to a separating column for carbon monoxide and methane and a cooling fluid is used at a pressure greater than that of the head of the separating column for cooling at least one fluid extracted at an intermediate level from the scrubbing column.

The carbon dioxide recovery apparatus has a dryer having a hygroscopic agent for drying a gas, and a separator for separating carbon dioxide from the gas dried by the dryer and discharging a residual gas from which carbon dioxide has been separated. The recovery apparatus further includes an introduction part for introducing a regeneration gas from outside for regenerating the hygroscopic agent, a regeneration system capable of supplying one of the regeneration gas introduced from the introduction part and the residual gas discharged from the separator to the dryer, and a switching mechanism for switching supply by the regeneration system between the regeneration gas and the residual gas in response to regeneration of the hygroscopic agent.

A device for separating a gas mixture containing at least 35 mol % carbon dioxide and also at least one gas lighter than carbon dioxide, comprising a first phase separator configured to receive a first partially condensed flow from an exchange line; a first phase separator configured to separate the gas phase from the liquid phase; a cooling means configured to receive the gas phase from the first phase separator and cool said gas phase to form a second partially condensed flow. The resulting liquid phase is then sent to a first valve and is expanded to a lower pressure that is at most 300 mbar lower in order to form a first expanded liquid, which is then mixed with a second liquid originating from the second phase separator in a mixing means that is located upstream of a third valve.

A method for separating air by cryogenic distillation in a system of columns comprising a first column and a second column operating at a lower pressure than the first column, comprising the steps of compressing all of the feed air in a first compressor to a first output pressure of at least 1 bar greater than the pressure of the first column, sending a first portion of the air under the first output pressure to the second compressor, and compressing the air to a second output pressure, cooling and condensing at least a portion of the air under the second output pressure in a heat exchanger, withdrawal of a liquid from a column of the system of columns, pressurising the liquid and evaporating the liquid by heat exchange in the heat exchanger, and pressure reduction of a portion of the compressed air to a second output pressure, at least partially evaporating said air in the heat exchanger, optionally additional heating of said air in the heat exchanger, and sending at least a portion of this air to the second compressor.

In a purification method, a carbon dioxide-rich gas is cooled in a first brazed aluminum plate-fin heat exchanger, the cooled gas or at least one fluid derived from the cooled gas is sent to a purification step comprising a distillation step, the purification step produces a carbon dioxide-rich liquid which is cooled, then expanded, then sent to a second heat exchanger where it is heated by means of a fluid of the method, the exchanger carrying out an indirect heat exchange only between the carbon dioxide-rich liquid and the fluid of the method, the carbon dioxide-rich liquid at least partially vaporizes in the second exchanger and the vaporized gas formed heats up again in the first exchanger to form a carbon dioxide-rich gas.