A cryogenic technology for the cost-efficient capture of each known component of emissions, such as carbon dioxide, sulfur oxides, nitrogen oxides, carbon monoxide, any other acid vapor, mercury, steam, in a liquefied or frozen/solidified form, and unreacted nitrogen (gas) from industrial plants, such that each of the components is captured separately with minimum use of energy and is industrially useful.

The present disclosure relates to the technical field of natural gas power generation, and particularly discloses a natural gas combined power generation process with zero carbon emission, the process comprising: introducing the pressurized air into an air separation facility to obtain liquid oxygen and liquid nitrogen, wherein the liquid oxygen is used for gasification and power generation, the liquid nitrogen is applied as the coolant of flue gas, and then used for the gasification and power generation; the liquid nitrogen and a part of liquid oxygen stored during the valley period with low electricity load are provided for use during the peak period with high electricity load; the natural gas, oxygen and the recyclable CO.sub.2 jointly enter a combustion gas turbine for burning to drive an air compressor and a generator to rotate at a high speed, the air compressor compresses the air to a pressure of 0.40.8 MPa, the generator generates electricity; the high-temperature combustion flue gas performs the supercritical CO.sub.2 power generation, its coolant is liquid oxygen; the moderate temperature flue gas then exchanges heat with liquid nitrogen, the liquid nitrogen vaporizes for power generation, the cooled flue gas is dehydrated and subjects to distillation and separation to obtain the recovered CO.sub.2, a part of the CO.sub.2 can be returned for circulation and temperature control, another part of the CO.sub.2 may be used for replenishment of work medium for supercritical CO.sub.2 power generation, and the remaining part of CO.sub.2 may be sold outward as liquid CO.sub.2 product. During the peak period with high electricity load, the liquid nitrogen stored during the valley period with low electricity load and separated during the peak period is pumped and pressurized and then subjects to heat exchange and vaporization for power generation. The power generation process provided by the present disclosure not only solves the difficult problems in the existing natural gas combined power generation technology such as high water consumption, low power generation efficiency and small range of peak load adjustment capacity; but also can compress air with high unit volume for energy storage with a high conversion efficiency, and greatly reduce load of the air compressor, thereby perform CO.sub.2 capture and utilization with low cost, zero NO.sub.x emission and discharging fuel gas at a normal temperature, and significantly improve the power generation efficiency.

A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

A method of liquefying hydrogen, including dividing a hydrogen stream into at least a first fraction and a second fraction, introducing the first fraction into a refrigeration cycle of a hydrogen liquefaction unit, thereby liquefying a product hydrogen stream, withdrawing one or more warm hydrogen stream(s) from the hydrogen liquefaction unit, and returning the one or more warm hydrogen stream to the hydrogen stream, wherein the second fraction is combined with a high-pressure nitrogen stream to form an ammonia synthesis gas stream.

The method for producing liquid hydrogen can include the steps of: introducing pressurized natural gas from a high pressure natural gas pipeline to a gas processing unit under conditions effective for producing a purified hydrogen stream; and introducing the purified hydrogen stream to a hydrogen liquefaction unit under conditions effective to produce a liquid hydrogen stream, wherein the hydrogen liquefaction unit provides a warm temperature cooling and a cold temperature cooling to the purified hydrogen stream, wherein the warm temperature cooling is provided by utilizing letdown energy of a pressurized stream selected from the group consisting of a nitrogen stream sourced from a nitrogen pipeline, a natural gas stream sourced from the high pressure natural gas pipeline, an air gas sourced from an air separation unit, and combinations thereof, wherein the cold temperature is provided by utilizing letdown energy of the purified hydrogen stream.

Method and plant for generation of synthesis gas, comprising the steps of air fractionation to give oxygen, nitrogen and tail gas, gasification of a hydrocarbonaceous fuel to give crude synthesis gas and cleaning of the crude synthesis gas by removal of acid gas by means of cryogenic absorption, wherein the absorbent is cooled by means of a compression coolant circuit and the cooling water used is cooled by evaporative cooling by means of the tail gas obtained in the air fractionation.

According to an embodiment of the invention, nitrogen gas of an air separation unit is used to cool the gas formed in a reservoir of liquid from an MEOH unit that is supplied with oxygen by said air separation unit.

Method and plant for generating a synthesis gas which consists mainly of carbon monoxide and hydrogen and has been freed of acid gases, proceeding from a hydrocarbonaceous fuel, and air and steam, wherein low-temperature fractionation separates air into an oxygen stream, a tail gas stream and a nitrogen stream, wherein the tail gas stream and the nitrogen stream are at ambient temperature and the nitrogen stream is at elevated pressure, wherein the hydrocarbonaceous fuel, having been mixed with the oxygen stream and steam at elevated temperature and elevated pressure, is converted to a synthesis gas by a method known to those skilled in the art, and wherein acid gas is subsequently separated therefrom by low-temperature absorption in an absorption column, wherein the nitrogen stream generated in the fractionation of air is passed through and simultaneously cooled in an expansion turbine and then used to cool either the absorbent or the coolant circulating in the coolant circuit of the compression refrigeration plant.

In this patent we disclose, for the first time, detailed methods of our newly invented state-of-the-art cryogenic technology for the cost effective energy efficient capture of each known component of entire emissions (nearly 100%) such as carbon dioxide (CO.sub.2), sulfur oxides (SO.sub.x), nitrogen oxides (NO.sub.x), carbon monoxide(CO), any other acid vapor, mercury, steam and unreacted nitrogen from industrial plants (coal and natural gas fired power plants, cement plants etc.), in a liquefied or frozen/solidified form, such that each of the components is captured separately and is industrially useful. This new technology includes a novel NH.sub.3 power plant to generate auxiliary electrical power from the heat energy of the flue gas to further improve the energy efficiency and cost effectiveness of the capture processes. It is the most cost effective of all existing emission capture technologies. It does not require use of any chemicals/reagents/external cryogens, unlike the current technologies. It uses only a fixed amount of water needed for the cooling process which can be used repeatedly. We present detailed methods of operations, together with scientific and economic analysis of the energy needed and cost involved for the said capture in two specific examples, and advantages of the new technology over the existing ones.

A method for the liquefaction of an industrial gas by integration of a methanol plant and an air separation unit (ASU) is provided. The method can include the steps of: (a) providing a pressurized natural gas stream, a pressurized purge gas stream originating from a methanol plant, and a pressurized air gas stream comprising an air gas originating from the ASU; (b) expanding three different pressurized gases to produce three cooled streams, wherein the three different pressurized gases are the pressurized natural gas stream, the pressurized purge gas stream, and the pressurized air gas stream; and (c) liquefying the industrial gas in a liquefaction unit against the three cooled streams to produce a liquefied industrial gas stream. The industrial gas to be liquefied is selected from the group consisting of a first portion of the pressurized natural gas stream, a nitrogen gas stream, hydrogen and combinations thereof.