Thermally-sensitive hardware is at least partially enclosed within a container in which reactants for a solid-solid endothermic chemical reaction are disposed, surrounding at least a portion of the thermally-sensitive hardware. The reactants or a structure including the reactants are positioned between the thermally-sensitive hardware and a heat source, such as an external surface of a missile traveling through atmospheric gases at extremely high speed and experiencing extreme frictional heating. The reactants absorb heat during the solid-solid endothermic reaction to thermally protect the thermally-sensitive hardware. The reactants are preferably selected to absorb heat of at least 5 kilo-Joules per gram (kJ/g) during the solid-solid endothermic chemical reaction.

A heavy inert gas insulation layer is wrapped around the length of a warhead to thermally insulate the warhead from fire or aerodynamic heating. The insulation layer may be integrally formed into the warhead casing or provided as a sleeve that may be permanently or removably positioned about the warhead casing. The insulation layer contains an inert gas such as Argon, Krypton, Xenon or a synthetic gas having a density of at least 1.5 kg/m.sup.3 and a thermal conductivity Tcond_gas no greater than two-thirds of the thermal conductivity of air Tcond_air.

A heavy inert gas insulation layer is wrapped around the length of a warhead to thermally insulate the warhead from fire or aerodynamic heating. The insulation layer may be integrally formed into the warhead casing or provided as a sleeve that may be permanently or removably positioned about the warhead casing. The insulation layer contains an inert gas such as Argon, Krypton, Xenon or a synthetic gas having a density of at least 1.5 kg/m.sup.3 and a thermal conductivity Tcond_gas no greater than two-thirds of the thermal conductivity of air Tcond_air.

A vacuum insulation layer is wrapped around the length of a warhead to thermally insulate the warhead from fire or aerodynamic heating. The vacuum insulation layer may be integrally formed into the warhead casing or provided as a sleeve that may be permanently or removably positioned about the warhead casing. The vacuum insulation layer is held under vacuum with a pressure of less than 25 Torr and a thermal conductivity Tcond_vac of less than one-third of the thermal conductivity of air Tcond_air.

A vacuum insulation layer is wrapped around the length of a warhead to thermally insulate the warhead from fire or aerodynamic heating. The vacuum insulation layer may be integrally formed into the warhead casing or provided as a sleeve that may be permanently or removably positioned about the warhead casing. The vacuum insulation layer is held under vacuum with a pressure of less than 25 Torr and a thermal conductivity Tcond_vac of less than one-third of the thermal conductivity of air Tcond_air.

A vacuum insulation layer is wrapped around the length of a warhead to thermally insulate the warhead from fire or aerodynamic heating. The vacuum insulation layer may be integrally formed into the warhead casing or provided as a sleeve that may be permanently or removably positioned about the warhead casing. The vacuum insulation layer is held under vacuum with a pressure of less than 25 Torr and a thermal conductivity Tcond_vac of less than one-third of the thermal conductivity of air Tcond_air.

A vacuum insulation layer is wrapped around the length of a warhead to thermally insulate the warhead from fire or aerodynamic heating. The vacuum insulation layer may be integrally formed into the warhead casing or provided as a sleeve that may be permanently or removably positioned about the warhead casing. The vacuum insulation layer is held under vacuum with a pressure of less than 25 Torr and a thermal conductivity Tcond_vac of less than one-third of the thermal conductivity of air Tcond_air.

Heavy inert gas insulation layer(s) are provided for containers configured to contain components that include an energetic material. The heavy inert gas insulation layer delays desensitization or inhibits premature reaction of the energetic material due to high external temperatures. The layers may be formed in hollow walls of the container itself or as inserts that are attached to the container. An inert gas fills a sealed void space in the walls or the insert. The inert gas has a density of at least 1.5 Kg/m.sup.3 and a thermal conductivity (Tcond_gas) of no greater than two-thirds of a thermal conductivity of air (Tcond_air) to form the heavy inert gas insulation layer. The inert gas may be Argon, Krypton, Xenon or a synthetic gas and is suitably held at a pressure of 760 Torr (1 atmosphere) or greater at sea level.