Biopesticide compositions, and methods and kits for their preparation from lignin are disclosed. A biopesticide may include a modified lignin chelated with one or more pesticides, the one or more pesticides having at least one acidic pesticide. The modified lignin may have one or more functional groups. Methods of producing a biopesticide may include obtaining a lignin, contacting the lignin with one or more bacteria under conditions suitable for producing a modified lignin, and chelating the modified lignin with one or more pesticides, the one or more pesticides having at least one acidic pesticide.

The present invention includes compositions and methods of for treating plants infected with fungal pathogens by contacting an infected plant or plant at risk of infection with a fungicidal composition comprising an fungicide selected from copper compound such as copper octanoate or copper hydroxide, or a triazole fungicide such as myclobutanil, propiconazole, tebuconazole or epoxiconazole, an enhancer selected from apyrase inhibitors, e.g., N-(m-toly1)-[1, 1′-biphenyl]-4-sulfonamide, S-heptyl 2-oxo-2H-chromene-3-carbothioate, 3-(N-(4-bromophenyl) sulfamoyl)-N-(3-nitrophenyl) benzamide, or (E)-3-methyl-N-(1-(naphthalen-2-yl) ethylidene) benzohydrazide and, optionally, a phytologically-acceptable inert carrier.

The present invention includes compositions and methods of for treating plants infected with fungal pathogens by contacting an infected plant or plant at risk of infection with a fungicidal composition comprising an fungicide selected from copper compound such as copper octanoate or copper hydroxide, or a triazole fungicide such as myclobutanil, propiconazole, tebuconazole or epoxiconazole, an enhancer selected from apyrase inhibitors, e.g., N-(m-toly1)-[1, 1′-biphenyl]-4-sulfonamide, S-heptyl 2-oxo-2H-chromene-3-carbothioate, 3-(N-(4-bromophenyl) sulfamoyl)-N-(3-nitrophenyl) benzamide, or (E)-3-methyl-N-(1-(naphthalen-2-yl) ethylidene) benzohydrazide and, optionally, a phytologically-acceptable inert carrier.

The present invention provides a compound that have excellent harmful arthropod controlling effects, the compounds being represented by formula (I) [wherein Q represents a group represented by formula Q1 or the like, Z represents an oxygen atom or a sulfur atom, A.sup.1 represents a nitrogen atom or CR.sup.6a, A.sup.2 represents a nitrogen atom or CR.sup.6b, A.sup.3 represents a nitrogen atom or CR.sup.6c, A.sup.4 represents CR.sup.1a or the like, A.sup.5 represents a nitrogen atom or CR.sup.6e or the like, A.sup.6 represents a nitrogen atom or CR.sup.6f, R.sup.6a represents a hydrogen atom or the like, R.sup.6b represents a C1-C6 chain hydrocarbon group or the like, R.sup.6c, R.sup.6e, R.sup.6f are identical to or different from each other, and each represents a C1-C6 chain hydrocarbon group or the like, R.sup.1a represents a C1-C6 chain hydrocarbon group or the like, R.sup.2 represents a C1-C6 chain hydrocarbon group or the like, R.sup.3 represents a C1-C6 chain hydrocarbon group or the like, and n is 0, 1 or 2] or its N oxide compound. ##STR00001##

The present invention provides a compound that have excellent harmful arthropod controlling effects, the compounds being represented by formula (I) [wherein Q represents a group represented by formula Q1 or the like, Z represents an oxygen atom or a sulfur atom, A.sup.1 represents a nitrogen atom or CR.sup.6a, A.sup.2 represents a nitrogen atom or CR.sup.6b, A.sup.3 represents a nitrogen atom or CR.sup.6c, A.sup.4 represents CR.sup.1a or the like, A.sup.5 represents a nitrogen atom or CR.sup.6e or the like, A.sup.6 represents a nitrogen atom or CR.sup.6f, R.sup.6a represents a hydrogen atom or the like, R.sup.6b represents a C1-C6 chain hydrocarbon group or the like, R.sup.6c, R.sup.6e, R.sup.6f are identical to or different from each other, and each represents a C1-C6 chain hydrocarbon group or the like, R.sup.1a represents a C1-C6 chain hydrocarbon group or the like, R.sup.2 represents a C1-C6 chain hydrocarbon group or the like, R.sup.3 represents a C1-C6 chain hydrocarbon group or the like, and n is 0, 1 or 2] or its N oxide compound. ##STR00001##

The present invention relates to the compounds of formula (I), and the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof wherein the variables are defined according to the description, formula (I). The compounds of formula (I), as well as the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof, are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds. ##STR00001##

The invention relates to pesticidal compositions comprising trisiloxane surfactants and a matrix-forming agent, which compositions are capable of controlling pests and pathogens using a physical mode of action. Accordingly, in one aspect, the present disclosure provides a pesticidal composition for controlling pests and pathogens with a physical mode of action. The composition comprises trisiloxane surfactants and matrix-forming agents. The composition may form a gel matrix or a film matrix. The trisiloxane surfactants may be selected from the group consisting of Silwet L-77, Silwet 408, Break-Thru S-240, and Silibase 2848. The matrixforming agents of a pesticidal composition are selected from the group consisting of chitosan salts and sol-gel precursors.

The invention relates to pesticidal compositions comprising trisiloxane surfactants and a matrix-forming agent, which compositions are capable of controlling pests and pathogens using a physical mode of action. Accordingly, in one aspect, the present disclosure provides a pesticidal composition for controlling pests and pathogens with a physical mode of action. The composition comprises trisiloxane surfactants and matrix-forming agents. The composition may form a gel matrix or a film matrix. The trisiloxane surfactants may be selected from the group consisting of Silwet L-77, Silwet 408, Break-Thru S-240, and Silibase 2848. The matrixforming agents of a pesticidal composition are selected from the group consisting of chitosan salts and sol-gel precursors.

This disclosure relates to picolinamides of Formula I and their use as fungicides.

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This disclosure relates to picolinamides of Formula I and their use as fungicides.

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