A method of co-producing liquid hydrogen and ammonia, including a hydrogen generator, a nitrogen generator, and a HLU is presented. The method includes pressurizing a hydrogen stream from the hydrogen generator in a hydrogen compressor, dividing the pressurized hydrogen into at least a first portion and a second portion, wherein the first portion includes at least part of the flow of a first refrigeration cycle in the HLU, and the second part comprises at least part of the feed to an ammonia plant. The method also includes pressurizing a nitrogen stream from the nitrogen generator in a HP nitrogen compressor, dividing the pressurized nitrogen stream into at least a first part and a second part, wherein the first part comprises at least part of the flow of a second refrigeration cycle in the HLU, and the second part comprises at least part of the feed to the ammonia plant.

Cryogenic refrigeration device comprising a working circuit intended to cool a working fluid circulating in the said circuit, the working circuit comprising, arranged in series in a loop: a compression portion, a cooling portion, a portion with valve(s), an expansion portion and a reheating portion, in order to subject the working fluid to a recuperative working cycle comprising compression, then cooling, then expansion and then reheating to prepare for a new cycle, wherein the compression portion comprises at least one compressor having a linear piston driven by a linear motor, the expansion proportion comprises at least one expander with a linear piston, the portion with valve(s) comprises at least one regulating valve linearly actuated by a linear motor and controlled in order to supply or extract the working fluid from the at least one expansion piston.

The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.

A method for storing and distributing liquefied hydrogen using an installation having a storage facility for liquid hydrogen, a source of gaseous hydrogen, a liquefier having an inlet connected to the source and an outlet connected to the liquid hydrogen storage facility, the storage facility having a liquid withdrawal pipe having an end connected to the liquid hydrogen storage facility and an end configured to be connected to at least one mobile tank, the method having a stage of liquefying gaseous hydrogen and a stage of transferring the liquefied hydrogen to the storage facility, wherein the liquefied hydrogen has a temperature below the bubble point of hydrogen at the storage pressure and further having a stage of transfer of liquid hydrogen directly to the tank at a temperature between the saturation temperature at the pressure of the liquid and a temperature above the solidification temperature of the hydrogen.

Installation and method for storing and dispensing liquefied hydrogen involving a source of gaseous hydrogen, a liquefier, and two storage reservoirs for liquid hydrogen at determined respective storage pressures, wherein the liquefier includes an inlet connected to the source and an outlet connected in parallel, via a set of valves, to a respective inlet of each storage reservoir.

Liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) to chill the gas or gas mixture during the liquefaction process. The gas is compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. A Joule Thomson (JT) adiabatic expansion process results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapour absorber tower (VAT) that permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapour is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may operate at pressures as low as 10 kPa, and the ammonia gas chiller may operate at temperatures as low as −71° C.

In an aspect, a system comprises a water stream in fluid communication with an electrolyzer; the electrolyzer comprising an anode and a cathode side chamber; a deep space oxygen radiator in fluid communication with the anode side chamber of the electrolyzer; a cryogenic heat exchanger comprising an oxygen storage tank in fluid communication with the deep space oxygen radiator; an electrochemical hydrogen compressor in fluid communication with the cathode side chamber; a hydrogen storage tank in fluid communication with the electrochemical hydrogen compressor via a cooled hydrogen stream; wherein at least a portion of the cooled hydrogen stream is in a first fluid communication with an expansion valve and the cryogenic heat exchanger; wherein the hydrogen storage tank is in a second fluid communication with the electrochemical hydrogen compressor via a warmed hydrogen stream; and wherein the cryogenic heat exchanger is in fluid communication with the warmed hydrogen stream.

A process for liquefying hydrogen gas into liquid hydrogen that includes: continuously introducing hydrogen gas into an active magnetic regenerative refrigerator module, wherein the module has one, two, three or four stages, wherein each stage includes a bypass flow heat exchanger that receives a bypass helium heat transfer gas from a cold side of a low magnetic or demagnetized field section that includes a magnetic refrigerant bed at a hydrogen gas first cold inlet temperature and discharges hydrogen gas or fluid at a first cold exit temperature; wherein sensible heat of the hydrogen gas is entirely removed by the bypass flow heat exchanger in the one stage module or a combination of the bypass flow heat exchangers in the two, three or four stage module, the magnetic refrigerant bed operates at or below its Curie temperature throughout an entire active magnetic regeneration cycle, and a temperature difference between the bypass helium heat transfer first cold inlet temperature and the hydrogen gas first cold exit temperature is 1 to 2 K for each bypass flow heat exchanger.

An arrangement comprising at least one liquefaction plant for liquefying a gaseous medium to produce a liquefied medium; and at least one storage tank for storing the liquefied medium. At least one first transfer line is connected between the liquefaction plant and the storage tank, for transferring liquefied medium from the liquefaction plant into the storage tank. At least one second transfer line is connected between the liquefaction plant and the storage tank, for transferring gaseous medium from the storage tank into the liquefaction plant. At least one shut-off valve is provided in each transfer line. The apparatus further includes a bypass line.

A hydrogen liquefaction apparatus according to the present disclosure comprises a compressor located on a hydrogen flow path to perform the first isothermal process; a precooler, a heat exchanger, and a first cryocooler which are connected to the compressor on the hydrogen flow path in this order to perform the first isobaric process; a Joule-Thomson valve connected to the first cryocooler on the hydrogen flow path to perform the isenthalpic process; a storage tank connected to the Joule-Thomson valve on the hydrogen flow path to perform the second isothermal process; and second cryocoolers which are connected to the storage tank on the hydrogen flow path to perform the third isobaric process between the isenthalpic process and the second isothermal process.