A system for natural gas cooling using nitrogen. The system can include a nitrogen liquefier and a natural gas cooler. The nitrogen liquefier can provide liquid nitrogen to the natural gas cooler. One or more heat exchangers of the natural gas cooler can include a gaseous nitrogen output that is in fluid communication with the nitrogen liquefier. In response to receiving gaseous nitrogen at the nitrogen liquefier, from the one or more heat exchangers, a production rate of the the nitrogen liquefier is adjusted.

Liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) to chill the gas or gas mixture during the liquefaction process. The gas is compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. A Joule Thomson (JT) adiabatic expansion process results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapour absorber tower (VAT) that permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapour is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may operate at pressures as low as 10 kPa, and the ammonia gas chiller may operate at temperatures as low as −71° C.

A method and system for liquefying a natural gas feed stream and removing nitrogen therefrom.

Liquefier arrangements configured for flexible co-production of both liquid natural gas (LNG) and liquid nitrogen (LIN) are provided. Each liquefier arrangement comprises separate and independent nitrogen recycle circuits or loops, including a warm recycle circuit and a cold recycle circuit with a means for diverting nitrogen refrigerant between the two recycle circuits or loops. The warm recycle circuit includes a booster loaded warm turbine, a warm booster compressor and warm recycle compression whereas the cold recycle circuit includes a booster loaded cold turbine, a cold booster compressor and a separate cold recycle compression.

A method for separating nitrogen from an inlet gas having less than 25 mole % nitrogen includes supplying the inlet gas having less than 25 mole % nitrogen to a nitrogen separation system configured with cryogenic refrigeration.

A liquefier device which may be a retrofit to an air separation plant or utilized as part of a new design. The flow needed for the liquefier comes from an air separation plant running in a maxim oxygen state, in a stable mode. The three gas flows are low pressure oxygen, low pressure nitrogen, and higher pressure nitrogen. All of the flows are found on the side of the main heat exchanger with a temperature of about 37 degrees Fahrenheit. All of the gasses put into the liquefier come out as a subcooled liquid, for storage or return to the air separation plant. This new liquefier does not include a front end electrical compressor, and will take a self produced liquid nitrogen, pump it up to a runnable 420 psig pressure, and with the use of turbines, condensers, flash pots, and multi pass heat exchangers. The liquefier will make liquid from a planned amount of any pure gas oxygen or nitrogen an air separation plant can produce.

A method for producing liquid nitrogen using a residual gas stream derived from a flue gas of a power plant is provided. The residual gas stream is purified in a front-end purification unit to remove freezable components and then the purified stream is compressed. Following compression, the stream can be divided into a first portion and a second portion, wherein the first portion is cooled and sent to a distillation column, wherein oxygen and argon are separated, thereby leaving an essentially pure gaseous nitrogen stream. The gaseous nitrogen stream can then be liquefied using refrigeration provided by expanding the second portion of the purified stream. In a preferred embodiment, the second portion is expanded in two turbines, and the gaseous nitrogen is compressed in a cold nitrogen booster, which is powered by one of the two turbines. In an additional embodiment, after warming, the expanded second portion of the purified stream can be used to regenerate the front-end purification unit.

A method for loading liquefied nitrogen (LIN) into a cryogenic storage tank initially containing liquid natural gas (LNG) and a vapor space above the LNG. First and second nitrogen gas streams are provided. The first nitrogen stream has a lower temperature than the second nitrogen gas stream. While the LNG is offloaded from the storage tank, the first nitrogen gas stream is injected into the vapor space. The storage tank is then purged by injecting the second nitrogen gas stream into the storage tank to thereby reduce a natural gas content of the vapor space to less than 5 mol %. After purging the storage tank, the storage tank is loaded with LIN.

An arrangement comprising at least one liquefaction plant for liquefying a gaseous medium to produce a liquefied medium; and at least one storage tank for storing the liquefied medium. At least one first transfer line is connected between the liquefaction plant and the storage tank, for transferring liquefied medium from the liquefaction plant into the storage tank. At least one second transfer line is connected between the liquefaction plant and the storage tank, for transferring gaseous medium from the storage tank into the liquefaction plant. At least one shut-off valve is provided in each transfer line. The apparatus further includes a bypass line.

A liquid nitrogen energy storage (LNES) system that includes a liquid charging mode and a power generating mode is provided. The disclosed liquid nitrogen energy storage system comprises a nitrogen liquefier designed to cool or liquefy a first portion of the gaseous nitrogen and a cold recovery heat exchanger designed to cool or liquefy a second portion of the gaseous nitrogen during a liquid charging mode and to warm a liquid nitrogen energy stream during a power generating mode. The liquid nitrogen energy storage system also includes a cold store configured to provide refrigeration for liquefaction of the second portion of the gaseous nitrogen in the cold recovery heat exchanger during the liquid charging mode and to warm a portion of the liquid nitrogen taken as a liquid nitrogen energy stream in the cold recovery heat exchanger during the power generating mode.