A system and method for cooling and liquefying a gas in a heat exchanger that includes compressing and cooling a mixed refrigerant using first and last compression and cooling cycles so that high pressure liquid and vapor streams are formed. The high pressure liquid and vapor streams are cooled in the heat exchanger and then expanded so that a primary refrigeration stream is provided in the heat exchanger. The mixed refrigerant is cooled and equilibrated between the first and last compression and cooling cycles so that a pre-cool liquid stream is formed and subcooled in the heat exchanger. The stream is then expanded and passed through the heat exchanger as a pre-cool refrigeration stream. A stream of gas is passed through the heat exchanger in countercurrent heat exchange with the primary refrigeration stream and the pre-cool refrigeration stream so that the gas is cooled. A resulting vapor stream from the primary refrigeration stream passage and a two-phase stream from the pre-cool refrigeration stream passage exit the warm end of the exchanger and are combined and undergo a simultaneous heat and mass transfer operation prior to the first compression and cooling cycle so that a reduced temperature vapor stream is provided to the first stage compressor so as to lower power consumption by the system. Additionally, the warm end of the cooling curve is nearly closed further reducing power consumption. Heavy components of the refrigerant are also kept out of the cold end of the process, reducing the possibility of refrigerant freezing, as well as facilitating a refrigerant management scheme.

Liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) to chill the gas or gas mixture during the liquefaction process. The gas is compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. A Joule Thomson (JT) adiabatic expansion process results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapour absorber tower (VAT) that permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapour is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may operate at pressures as low as 10 kPa, and the ammonia gas chiller may operate at temperatures as low as 71 C.

A method for separating nitrogen from an LNG stream with a nitrogen concentration of greater than 1 mol %. A pressurized LNG stream is produced at a liquefaction facility by liquefying natural gas, where the pressurized LNG stream has a nitrogen concentration of greater than 1 mol %. At least one liquid nitrogen (LIN) stream is received from storage tanks, the at least one LIN stream being produced at a different geographic location from the LNG facility. The pressurized LNG stream is separated in a separation vessel into a vapor stream and a liquid stream. The vapor stream has a nitrogen concentration greater than the nitrogen concentration of the pressurized LNG stream. The liquid stream has a nitrogen concentration less than the nitrogen concentration of the pressurized LNG stream. At least one of the one or more LIN streams is directed to the separation vessel.

A method for liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) that is used to chill the gas or gas mixture during the liquefaction process. The gas may be compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. The method utilizes a Joule Thomson (JT) adiabatic expansion process which results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapor absorber tower (VAT) which permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapor is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may achieve operating pressures as low as 10 kPa which results in ammonia gas chiller operating temperatures as low as 71 C.

A system and method for cooling and liquefying a gas in a heat exchanger that includes compressing and cooling a mixed refrigerant using first and last compression and cooling cycles so that high pressure liquid and vapor streams are formed. The high pressure liquid and vapor streams are cooled in the heat exchanger and then expanded so that a primary refrigeration stream is provided in the heat exchanger. The mixed refrigerant is cooled and equilibrated between the first and last compression and cooling cycles so that a pre-cool liquid stream is formed and subcooled in the heat exchanger. The stream is then expanded and passed through the heat exchanger as a pre-cool refrigeration stream. A stream of gas is passed through the heat exchanger in countercurrent heat exchange with the primary refrigeration stream and the pre-cool refrigeration stream so that the gas is cooled. A resulting vapor stream from the primary refrigeration stream passage and a two-phase stream from the pre-cool refrigeration stream passage exit the warm end of the exchanger and are combined and undergo a simultaneous heat and mass transfer operation prior to the first compression and cooling cycle so that a reduced temperature vapor stream is provided to the first stage compressor so as to lower power consumption by the system. Additionally, the warm end of the cooling curve is nearly closed further reducing power consumption. Heavy components of the refrigerant are also kept out of the cold end of the process, reducing the possibility of refrigerant freezing, as well as facilitating a refrigerant management scheme.

Method for the liquefaction of nitrogen using the recovery of cold energy deriving from the evaporation of liquefied natural gas comprising the steps of: sending a flow of nitrogen (100) to be liquefied to a precooler (101); sending a flow (107) of nitrogen gas exiting said precooler (101) to a heat exchanger (108) of the high pressure recirculation compressor; sending a flow (114) of nitrogen exiting said heat exchanger (108) to a high pressure recirculation compressor (115, 117); sending a flow (120) of nitrogen exiting said compressor (115, 117) to a liquefaction heat exchanger (121); sending to said liquefaction heat exchanger (121) a flow (123) of natural gas, countercurrent to the flow (120) exiting said compressor (115, 117); sending a flow (126, 150) of nitrogen exiting said liquefaction heat exchanger (121) to said heat exchanger (108) countercurrent to said flow (107) of nitrogen gas and to said flow (114) of nitrogen; sending a flow (151, 152) of nitrogen exiting said heat exchanger (108) to said precooler (101) countercurrent to said flow of nitrogen (100) to be liquefied; sending the flow (126, 130) of nitrogen exiting said liquefaction heat exchanger (121) to an expander (131); sending the flow of nitrogen exiting said expander (131) to a medium pressure separator (112) that delivers an exiting flow (132) of nitrogen.

The device (100) for cooling a flow (101) of a target fluid predominantly comprising dihydrogen, comprises: a first heat exchanger (105) configured to cool an intermediate refrigerant fluid (110) by heat exchange with an expanded dioxygen flow (115), an intermediate closed circuit (120) for transporting the intermediate refrigerant fluid from the first heat exchanger to a second heat exchanger (125), a means (130) for compressing the intermediate refrigerant fluid along the intermediate closed circuit, the intermediate refrigerant fluid, configured to remain in the liquid or supercritical state at least upon passing through the compression means and the second heat exchanger configured to cool the target fluid flow by heat exchange with the intermediate refrigerant fluid cooled in the first heat exchanger.

A method for separating air by cryogenic distillation in a system of columns comprising a first column and a second column operating at a lower pressure than the first column, comprising the steps of compressing all of the feed air in a first compressor to a first output pressure of at least 1 bar greater than the pressure of the first column, sending a first portion of the air under the first output pressure to the second compressor, and compressing the air to a second output pressure, cooling and condensing at least a portion of the air under the second output pressure in a heat exchanger, withdrawal of a liquid from a column of the system of columns, pressurising the liquid and evaporating the liquid by heat exchange in the heat exchanger, and pressure reduction of a portion of the compressed air to a second output pressure, at least partially evaporating said air in the heat exchanger, optionally additional heating of said air in the heat exchanger, and sending at least a portion of this air to the second compressor.

A system and method for cryogenic purification of a hydrogen, nitrogen, methane and argon containing feed stream to produce a methane free, hydrogen and nitrogen containing synthesis gas and a methane rich fuel gas, as well as to recover an argon product stream, excess hydrogen, and excess nitrogen is provided. The disclosed system and method are particularly useful as an integrated cryogenic purifier in an ammonia synthesis process in an ammonia plant. The excess nitrogen is a nitrogen stream substantially free of methane and hydrogen that can be used in other parts of the plant, recovered as a gaseous nitrogen product and/or liquefied to produce a liquid nitrogen product.

Apparatus and processes for liquefying process gases using multi-stage active magnetic regenerative refrigerators are disclosed. The apparatus and processes can be configured to liquefy process streams that liquefy below .sup.200 K, such as ethane, methane, argon, nitrogen, neon, hydrogen and/or helium process gases. Active magnetic regenerative liquefiers use multiple successive active magnetic regenerator stages, with each stage using a compositionally distinct magnetic refrigerant material having a distinct Curie temperature. In some aspects, the refrigerant material in each successive stage has a Curie temperature of about 20 K-40K different from that of neighboring stages. Heat transfer fluid flows are directed to improve system efficiency.