An arrangement comprising at least one liquefaction plant for liquefying a gaseous medium to produce a liquefied medium; and at least one storage tank for storing the liquefied medium. A first transfer line is provided which is connected between the liquefaction plant and the storage tank, for transferring liquefied medium from the liquefaction plant into the storage tank. A second transfer line is connected between the liquefaction plant and the storage tank, for transferring gaseous medium from the storage tank into the liquefaction plant. The second transfer line, which used for transferring medium from the storage tank into the liquefaction plant, is arranged so that it is routed at least partially through the area of the storage tank in which the liquefied medium is stored in use.

Certain embodiments of the present invention lies in providing a high-purity oxygen production system which is capable of supplying liquid nitrogen in order to supply the cold required by a high-purity oxygen production apparatus, without the use of a costly conventional liquefaction apparatus. A high-purity oxygen production system in accordance with an embodiment can include: an air separation apparatus including a main heat exchanger, a medium-pressure column and a low-pressure column; and a high-purity oxygen production apparatus including a nitrogen compressor, a nitrogen heat exchanger and at least one (high-purity) oxygen rectification column, an oxygen-containing stream serving as a starting material for high-purity oxygen is supplied from the low-pressure column to the high-purity oxygen production apparatus, and liquid nitrogen obtained from the medium-pressure column is supplied to the high-purity oxygen production apparatus in order to replenish cold heat required for operation of the high-purity oxygen production apparatus.

Liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) to chill the gas or gas mixture during the liquefaction process. The gas is compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. A Joule Thomson (JT) adiabatic expansion process results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapour absorber tower (VAT) that permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapour is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may operate at pressures as low as 10 kPa, and the ammonia gas chiller may operate at temperatures as low as 71 C.

In an aspect, a system comprises a water stream in fluid communication with an electrolyzer; the electrolyzer comprising an anode and a cathode side chamber; a deep space oxygen radiator in fluid communication with the anode side chamber of the electrolyzer; a cryogenic heat exchanger comprising an oxygen storage tank in fluid communication with the deep space oxygen radiator; an electrochemical hydrogen compressor in fluid communication with the cathode side chamber; a hydrogen storage tank in fluid communication with the electrochemical hydrogen compressor via a cooled hydrogen stream; wherein at least a portion of the cooled hydrogen stream is in a first fluid communication with an expansion valve and the cryogenic heat exchanger; wherein the hydrogen storage tank is in a second fluid communication with the electrochemical hydrogen compressor via a warmed hydrogen stream; and wherein the cryogenic heat exchanger is in fluid communication with the warmed hydrogen stream.

A method for liquefaction of industrial gases or gas mixtures (hydrocarbon and/or non-hydrocarbon) uses a modified aqua-ammonia absorption refrigeration system (ARP) that is used to chill the gas or gas mixture during the liquefaction process. The gas may be compressed to above its critical point, and the heat of compression energy may be recovered to provide some or all of the thermal energy required to drive the ARP. The method utilizes a Joule Thomson (JT) adiabatic expansion process which results in no requirement for specialty cryogenic rotating equipment. The aqua-ammonia absorption refrigeration system includes a vapor absorber tower (VAT) which permits the recovery of some or all of the heat of solution and heat of condensation energy in the system when anhydrous ammonia vapor is absorbed into a subcooled lean aqua-ammonia solution. The modified ARP with VAT may achieve operating pressures as low as 10 kPa which results in ammonia gas chiller operating temperatures as low as 71 C.

A system and method for cooling an oxygen stream by heat exchange with a warming supply nitrogen stream having of a heat exchanger having at least a Zone A and a Zone B, the system having indirect heat exchange between a gaseous oxygen stream, and a high-pressure liquid nitrogen stream split into at least a first portion which passes through a Zone A, and a second portion which passes through a Zone B during a first phase of operation. And a high-pressure liquid nitrogen stream passing through Zone A, thereby producing a high-pressure nitrogen vapor stream, which passes through an expansion turbine, thereby producing an expansion turbine outlet stream which then passes through Zone B, during a second phase of operation, thereby producing a liquid oxygen stream.

The present invention relates to cryogenic energy storage systems for storing using high-grade heat-of-compression. The system includes a liquefaction sub-system (100) and thermal energy storage device (300). The liquefaction sub-system (100) includes a first compressor (102), a first, second and third heat exchanger (104, 116, 112) and second compressor (114). The first and second heat exchangers (104, 116) are configured to transfer the high-grade heat of compression from the first and second compressors (102, 114) respectively to the thermal energy storage device (300). The third heat exchanger (112) is configured to recuperate the low-grade heat of compression from the second compressor (114) back into the second compressor (114) enabling the second compressor (114) to generate high-grade heat of compression. Further systems use compressors (124) and expanders (122). Further systems include power recovery sub-systems (400). The present disclosure also relates to methods of heat-of-compression storage in cryogenic energy storage systems.

A system and method for the production and supply of a densified, liquid oxidant to a space vehicle launch facility with one or more launch platforms is provided. A low pressure gaseous oxygen stream is piped from a nearby air separation unit and is then liquefied and densified in a two-stage, integrated liquefaction/densification system. The first refrigeration stage is a nitrogen based reverse Brayton cycle refrigeration cycle, that liquefies the gaseous oxygen and subcools the resulting liquid oxygen to a temperature of about 81 Kelvin. The second refrigeration stage is a mixed refrigerant loop containing some combination of helium and/or neon refrigerants that densifies the liquid oxygen to a temperature of about 57 Kelvin. The integrated liquefaction and densification system may also be configured to densify liquid methane or other propellants used in space vehicle launches.

A system and method for the production and supply of a densified, liquid oxidant to a space vehicle launch facility is provided. A stream of liquid oxygen taken from a co-located, liquid producing air separation unit is densified in a two refrigeration stage, integrated densification system. The first refrigeration stage is a nitrogen based reverse Brayton cycle refrigeration cycle that provides refrigeration to the second refrigeration stage. The second refrigeration stage is a helium and/or neon comprising refrigerant loop that densifies the liquid oxygen to a temperature between about 70 Kelvin and 57 Kelvin. The integrated densification system may also be configured to densify liquid methane or other propellants used in space vehicle launches.

A system and method for the co-production of a densified, liquid oxidant and a densified liquid methane fuel to a space vehicle launch facility is provided. In one embodiment, a low pressure gaseous oxygen stream is piped from a nearby air separation unit to the space vehicle launch facility where it is then liquefied and densified in a two-stage, integrated liquefaction/densification system that also densifies a source of liquid methane. In an alternate embodiment, a liquid oxygen stream produced at an air separation unit is densified in a two-stage, integrated densification system configured to densify both the liquid oxygen as well a source of liquid methane at or near the air separation unit with the resulting densified liquid products transported via truck/trailer to a nearby space vehicle launch facility.