F25J1/004

Liquid natural gas liquefier utilizing mechanical and liquid nitrogen refrigeration

The present invention relates to a method and system for producing liquefied natural gas (LNG) from a stream of pressurized natural gas which involves a combination of mechanical refrigeration.

METHOD AND SYSTEM FOR DECARBONIZED LNG PRODUCTION

Integration of a natural gas liquefaction system, a hydrogen production system, and power generation system to increase CO2 capture and improve overall plant efficiency. The predominantly methane endflash is sent to the hydrogen production system which produces hydrogen and CO2. The CO2 may be captured or beneficially used. At least a portion of the hydrogen produced is used to fuel gas turbines in the power generation which, in turn, provides power for the refrigeration compressor of the natural gas liquefaction system—either in the form of mechanical work or electricity.

METHODS AND SYSTEMS FOR HYDROGEN LIQUEFACTION

Systems and methods for liquefying a gaseous hydrogen that include a first refrigeration stage and a second refrigeration stage. The first refrigeration stage includes a first heat exchanger configured to flow a first refrigerant to pre-cool the gaseous hydrogen. The second refrigeration stage includes a second heat exchanger configured to flow a second refrigerant to liquefy and sub-cool the hydrogen. The second refrigerant is split into two streams that flow through two compressor-expanders and multiple passes through the second heat exchanger before being recombined to repeat the second refrigeration stage circuit.

Methods and systems for hydrogen liquefaction

Systems and methods for liquefying a gaseous hydrogen that include a first refrigeration stage and a second refrigeration stage. The first refrigeration stage includes a first heat exchanger configured to flow a first refrigerant to pre-cool the gaseous hydrogen. The second refrigeration stage includes a second heat exchanger configured to flow a second refrigerant to liquefy and sub-cool the hydrogen. The second refrigerant is split into two streams that flow through two compressor-expanders and multiple passes through the second heat exchanger before being recombined to repeat the second refrigeration stage circuit.

SYSTEMS AND PROCESSES FOR STATIONARY AND MOBILE NATURAL GAS LIQUEFACTION

The disclosure describes processes which include cooling a natural gas product stream to a cryogenic liquid storage temperature by way of refrigeration streams which include a primary refrigeration stream, a secondary refrigeration stream, and a tertiary refrigeration stream in a refrigeration system. After leaving the refrigeration system, the pressure of each refrigeration stream is increased, and upon reaching a sufficient pressure, the refrigeration streams are recycled to flow back into the refrigeration system as a recycle stream. The disclosure further describes systems capable of performing the processes. The processes and systems can include one or more sensors and one or more controls capable of adjusting a flow rate, flow volume, and/or flow ratio among one or more gas streams to maximize cooling efficiency based on monitoring from the one or more sensors. Mobile natural gas liquefaction systems are also described.

METHOD TO CONVERT EXCESS LIQUID OXYGEN INTO LIQUID NITROGEN
20220112083 · 2022-04-14 ·

A method for converting excess liquid oxygen into liquid nitrogen, including introducing a gaseous nitrogen stream into a main heat exchanger, therein exchanging heat with a vaporized oxygen stream, a vapor phase nitrogen steam, and a waste liquid nitrogen stream; thereby producing a cold gaseous nitrogen stream, an oxygen vent stream, a nitrogen vent steam, and a gaseous nitrogen waste stream, introducing the cold gaseous nitrogen stream into a secondary heat exchanger, therein exchanging heat with a liquid oxygen stream; thereby producing the vaporized oxygen stream and a cold liquid nitrogen stream, introducing the cold liquid nitrogen stream into a nitrogen pressure reduction valve thereby producing a two-phase nitrogen stream, introducing the two-phase nitrogen stream into a nitrogen flash vessel thereby producing a liquid phase nitrogen stream and the vapor phase nitrogen stream, wherein the method is performed in the absence of refrigerant turbo-expanders, refrigerant expansion turbines, or refrigerant compressors.

APPARATUS TO CONVERT EXCESS LIQUID OXYGEN INTO LIQUID NITROGEN
20220113085 · 2022-04-14 ·

An apparatus for converting excess liquid oxygen into liquid nitrogen, including a main heat exchanger to exchange heat between a gaseous nitrogen stream, a vaporized oxygen stream, a vapor phase nitrogen steam, and a waste liquid nitrogen stream; thereby producing a cold gaseous nitrogen stream, an oxygen vent stream, a nitrogen vent steam, and a gaseous nitrogen waste stream, a secondary heat exchanger to exchange heat between a liquid oxygen stream and the cold gaseous nitrogen stream; thereby producing the vaporized oxygen stream and a cold liquid nitrogen stream, a nitrogen pressure reduction valve to reduce the pressure of the cold liquid nitrogen stream; thereby producing a two-phase nitrogen stream, a nitrogen flash vessel to receive the two-phase nitrogen stream, and to generate a liquid phase nitrogen stream and a vapor phase nitrogen stream, wherein the apparatus does not include any refrigerant turbo-expanders, refrigerant expansion turbines, or refrigerant compressors.

Method for Operating a Liquid Air Energy Storage
20220082092 · 2022-03-17 · ·

A method for operating the liquid air energy storage (LAES) includes production of the storable liquid air through consumption of a low-demand power and recovery the liquid air for co-production of an on-demand power and a high-grade saleable cold thermal energy which may be used, say, for liquefaction of the delivered natural gas; in so doing zero carbon footprint is provided both for fueled augmentation of the LAES power output and for LNG co-production at the LAES facility.

SYSTEM FOR COOLING AND CONDENSING GAS

The present invention corresponds to a gas cooling and condensing system using fluid energy and comprising a gas feed line, a first vortex tube connected to the gas feed line, a second vortex tube connected to the first vortex tube and a first heat exchanger connected to the second vortex tube and to the gas feed line. Said gas cooling and condensing system is a modular system, which may be replicated and connected in series or in parallel to another modular system to obtain a cooler or higher mass flow gas than that obtained with a single modular system.

Moreover, the system of the present invention is optionally connected to thermal recovery, pressure recovery, recirculation or venting elements for the utilization of the waste gas streams. Furthermore, the system of the present invention does not require additional energy to that obtained from the pressure of the feed line for obtaining liquefied gas. On the other hand, the system of the present invention taps the pressure drop required between the compressed gas transport and distribution activities.

NITROGEN PROCESS FOR PRODUCTION OF AMMONIA AND LIQUID HYDROGEN

A method of co-producing liquid hydrogen and ammonia, including a hydrogen generator, a nitrogen generator, and a HLU is presented. The method includes pressurizing a hydrogen stream from the hydrogen generator in a hydrogen compressor, dividing the pressurized hydrogen into at least a first portion and a second portion, wherein the first portion includes at least part of the flow of a first refrigeration cycle in the HLU, and the second part comprises at least part of the feed to an ammonia plant. The method also includes pressurizing a nitrogen stream from the nitrogen generator in a HP nitrogen compressor, dividing the pressurized nitrogen stream into at least a first part and a second part, wherein the first part comprises at least part of the flow of a second refrigeration cycle in the HLU, and the second part comprises at least part of the feed to the ammonia plant.