The present invention discloses a hydrogen or helium throttling liquefaction system using direct current (DC) flow from the cold and hot ends of the regenerative cryocoolers, which belongs to the technical field of refrigeration and cryogenics. It includes a regenerative cryocooler module, a hot-end DC flow module, a cold-end DC flow module, a throttling liquefaction module, and a gas-phase circulation module. The modules are interconnected to form a closed loop for the flow of hydrogen or helium working fluid. DC flow is introduced from the cold and hot ends of the regenerative cryocooler through the DC flow pipelines and DC flow valves. The hot-end DC flow exchanges heat with the reflowing low-temperature working fluid and is cooled down. After that, it mixes with the cold-end DC flow and enters the throttling liquefaction module to generate liquid phase through throttling and liquefaction. After the liquid phase has output cooling capacity, it flows through the gas-phase circulation module and then enters the back-pressure chamber of the compressor to complete the cycle. Compared with the existing small-scale hydrogen and helium liquefaction technology using regenerative cryocoolers, the present invention has the advantages of simple structure, easy installation, high heat transfer efficiency and liquefaction efficiency of the system.

The present invention relates to a method for liquefying hydrogen, the method comprises the steps of: cooling a feed gas stream comprising hydrogen with a pressure of at least 15 bar(a) to a temperature below the critical temperature of hydrogen in a first cooling step yielding a liquid product stream. According to the invention, the feed gas stream is cooled by a closed first cooling cycle with a high pressure first refrigerant stream comprising hydrogen, wherein the high pressure first refrigerant stream is separated into at least two partial streams, a first partial stream is expanded to low pressure, thereby producing cold to cool the precooled feed gas below the critical pressure of hydrogen, and compressed to a medium pressure, and wherein a second partial stream is expanded at least close to the medium pressure and guided into the medium pressure first partial stream.

The present invention relates to a refrigerant composition. According to the invention it is envisioned that the composition comprises comprising an inert gas selected from nitrogen, argon, neon and a mixture thereof, and a mixture of at least two C.sub.1-C.sub.5 hydrocarbons. The present invention further relates to the use of the refrigerant composition in a method for liquefying a gaseous substance, particularly hydrogen or helium.

The present invention relates to a refrigerant composition comprising neon and hydrogen. The present invention further relates to the use of the refrigerant composition in liquefying gaseous substances such as hydrogen or helium.

A precool heat exchanger system receives a stream of first cryogenic fluid for warming a second cryogenic fluid. A first splitter receives and divides a first cryogenic fluid stream into a motive stream and a secondary cooling stream. An ejector receives the motive stream. An expansion device receives and expands the secondary cooling stream and directs at least a portion of it to the precool heat exchanger system so that a second cryogenic fluid is cooled. First cryogenic fluid from the precool heat exchanger is directed into the ejector suction port and the pressure therein is reduced. A primary separation device divides a first cryogenic fluid mixed phase stream from the ejector into a first cryogenic fluid vapor stream and a liquid recycle stream that exit the primary separation device. A recycle pump directs first cryogenic fluid to the first splitter.

A refrigerator according to the present invention includes: a cooling part for cooling an object to be cooled through heat exchange with a refrigerant; an expander-integrated compressor including a compressor for compressing the refrigerant and an expander for expanding the refrigerant integrated therein; and a refrigerant circulation line configured to circulate the refrigerant through the compressor, the expander, and the cooling part. The compressor includes a low-stage compressor, a middle-stage compressor, and a high-stage compressor disposed in series in the refrigerant circulation line. The expander-integrated compressor includes: the middle-stage compressor; an expander for adiabatically expanding and cooling the refrigerant discharged from the high-stage compressor; a first motor having an output shaft connected to the middle-stage compressor and to the expander; at least one non-contact type bearing, disposed between the middle-stage compressor and the expander, for supporting the output shaft of the first motor without being in contact with the output shaft; and a casing for housing the middle-stage compressor, the expander, and the at least one non-contact type bearing.

The method for producing liquid hydrogen can include the steps of: introducing pressurized natural gas from a high pressure natural gas pipeline to a gas processing unit under conditions effective for producing a purified hydrogen stream; and introducing the purified hydrogen stream to a hydrogen liquefaction unit under conditions effective to produce a liquid hydrogen stream, wherein the hydrogen liquefaction unit provides a warm temperature cooling and a cold temperature cooling to the purified hydrogen stream, wherein the warm temperature cooling is provided by utilizing letdown energy of a pressurized stream selected from the group consisting of a nitrogen stream sourced from a nitrogen pipeline, a natural gas stream sourced from the high pressure natural gas pipeline, an air gas sourced from an air separation unit, and combinations thereof, wherein the cold temperature is provided by utilizing letdown energy of the purified hydrogen stream.

A method for the liquefaction of an industrial gas by integration of a methanol plant and an air separation unit (ASU) is provided. The method can include the steps of: (a) providing a pressurized natural gas stream, a pressurized purge gas stream originating from a methanol plant, and a pressurized air gas stream comprising an air gas originating from the ASU; (b) expanding three different pressurized gases to produce three cooled streams, wherein the three different pressurized gases are the pressurized natural gas stream, the pressurized purge gas stream, and the pressurized air gas stream; and (c) liquefying the industrial gas in a liquefaction unit against the three cooled streams to produce a liquefied industrial gas stream. The industrial gas to be liquefied is selected from the group consisting of a first portion of the pressurized natural gas stream, a nitrogen gas stream, hydrogen and combinations thereof.

A method for the liquefaction of an industrial gas by integration of a methanol plant and an air separation unit (ASU) is provided. The method can include the steps of: (a) providing a pressurized natural gas stream, a pressurized purge gas stream composed predominately of hydrogen and originating from a methanol plant, and a pressurized air gas stream comprising an air gas from the ASU; (b) expanding three different pressurized gases to produce three cooled streams, wherein the three different pressurized gases consist of the pressurized natural gas stream, the pressurized purge gas stream, and the pressurized air gas stream; and (c) liquefying the industrial gas in a liquefaction unit against the three cooled streams to produce a liquefied industrial gas stream, wherein the industrial gas to be liquefied is selected from the group consisting of a first portion of the pressurized natural gas stream, a nitrogen gas stream, hydrogen and combinations thereof

Methods and systems providing a process for cooling and liquefying a purified gaseous hydrogen feed stream to a liquid hydrogen stream that may be stored in a liquid hydrogen storage tank, as well as a system wherein ortho-hydrogen (o-H2) contained in the purified gaseous hydrogen feed stream may be converted to para-hydrogen (p-H2) through serial low-temperature catalytic converters along the cooling process from normal ambient temperature (300K) to the liquefied temperature about (20K) of the hydrogen.