A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

A method of liquefying hydrogen, including dividing a hydrogen stream into at least a first fraction and a second fraction, introducing the first fraction into a refrigeration cycle of a hydrogen liquefaction unit, thereby liquefying a product hydrogen stream, withdrawing one or more warm hydrogen stream(s) from the hydrogen liquefaction unit, and returning the one or more warm hydrogen stream to the hydrogen stream, wherein the second fraction is combined with a high-pressure nitrogen stream to form an ammonia synthesis gas stream.

A method for separating air by cryogenic distillation in a system of columns comprising a first column and a second column operating at a lower pressure than the first column, comprising the steps of compressing all of the feed air in a first compressor to a first output pressure of at least 1 bar greater than the pressure of the first column, sending a first portion of the air under the first output pressure to the second compressor, and compressing the air to a second output pressure, cooling and condensing at least a portion of the air under the second output pressure in a heat exchanger, withdrawal of a liquid from a column of the system of columns, pressurising the liquid and evaporating the liquid by heat exchange in the heat exchanger, and pressure reduction of a portion of the compressed air to a second output pressure, at least partially evaporating said air in the heat exchanger, optionally additional heating of said air in the heat exchanger, and sending at least a portion of this air to the second compressor.

The method for producing liquid hydrogen can include the steps of: introducing pressurized natural gas from a high pressure natural gas pipeline to a gas processing unit under conditions effective for producing a purified hydrogen stream; and introducing the purified hydrogen stream to a hydrogen liquefaction unit under conditions effective to produce a liquid hydrogen stream, wherein the hydrogen liquefaction unit provides a warm temperature cooling and a cold temperature cooling to the purified hydrogen stream, wherein the warm temperature cooling is provided by utilizing letdown energy of a pressurized stream selected from the group consisting of a nitrogen stream sourced from a nitrogen pipeline, a natural gas stream sourced from the high pressure natural gas pipeline, an air gas sourced from an air separation unit, and combinations thereof, wherein the cold temperature is provided by utilizing letdown energy of the purified hydrogen stream.

A method for the production of liquefied natural gas (LNG) using a cold fluid provided from a cryogenic unit, such as an air separation unit or nitrogen liquefier, is provided. The method may include the steps of: withdrawing a nitrogen stream from a cryogenic unit, wherein the nitrogen stream is at a temperature between about 155 C. to about 193 C.; and liquefying a natural gas stream in a natural gas liquefaction unit using the nitrogen stream from the cryogenic unit.

Apparatus, systems, and methods store energy by liquefying a gas such as air, for example, and then recover the energy by regasifying the liquid and combusting or otherwise reacting the gas with a fuel to drive a heat engine. The process of liquefying the gas may be powered with electric power from the grid, for example, and the heat engine may be used to generate electricity. Hence, in effect these apparatus, systems, and methods may provide for storing electric power from the grid and then subsequently delivering it back to the grid.

A liquefaction apparatus that automatically adjusts the load on the liquefaction apparatus correspondingly with an upper limit value of contracted power in different time slots, and which is capable of maximizing the amount of liquefied product produced and of achieving optimum operating efficiency is provided. In certain embodiments, the liquefaction apparatus can include: a production amount calculation unit 91 for obtaining an actual production amount of a liquefied product; a predicted power calculation unit 92 for obtaining a predicted power amount after a predetermined time has elapsed, on the basis of an integrated power value obtained by integrating a usage power; and a power demand control unit 93 for comparing the predicted power amount and a moving average of instantaneous power, and controlling a discharge flow rate of a compressor 3 in such a way as to come infinitely close to a target value, without exceeding the target value, and while using the larger value of the predicted power amount and the moving average of instantaneous power as a value being controlled.

A system for storing or producing electricity, which allows stabilization of a power network under conditions of excess availability of electricity or lack thereof and for producing liquefied natural gas is provided.

A liquefaction system comprises: a temperature setting unit for setting an inlet gas temperature on entry to a cold turbine; a control valve for controlling an amount of gas fed to the cold turbine, correspondingly with an inlet gas temperature measured by the temperature measuring unit; and a control unit which compares the inlet gas temperature measured by the temperature measuring unit with a warning temperature set value plus a margin, and sets a first operating state when the inlet gas temperature is equal to or less than the warning temperature set value plus the margin and also sets an emergency stoppage temperature set value at the warning temperature set value plus the margin, and sets a second operating state when the inlet gas temperature is greater than the warning temperature set value plus the margin, the control unit performing control in response to the second operating state to make a degree of opening of the control valve greater than a degree of opening during the first operating state in order to lower an inlet pressure of the cold turbine, and performing control in response to the first operating state to make the degree of opening of the control valve smaller than the degree of opening during the second operating state in order to raise the inlet pressure of the cold turbine.

A novel concept for a high energy and material efficient nitric acid production process and system is provided, wherein the nitric acid production process and system, particularly integrated with an ammonia production process and system, is configured to recover a high amount of energy out of the ammonia that it is consuming, particularly in the form of electricity, while maintaining a high nitric acid recovery in the conversion of ammonia to nitric acid. The energy recovery and electricity generation process comprises pressurizing a liquid gas, such as air, oxygen and/or N.sub.2, subsequently evaporating and heating the pressurized liquid gas, particularly using low grade waste heat generated in the production of nitric acid and/or ammonia, and subsequently expanding the evaporated pressurized liquid gas over a turbine. In particular, the generated electricity is at least partially used to power an electrolyzer to generate the hydrogen needed for the production of ammonia. The novel concepts set out in the present application are particularly useful in the production of nitric acid based on renewable energy sources.