A system and method for argon and nitrogen extraction and liquefaction from a low-pressure tail gas of an ammonia production plant is provided. The preferred tail gas of the ammonia production plant comprises methane, nitrogen, argon, and hydrogen. The disclosed system and method provides for the methane rejection via rectification and hydrogen rejection by way of a side stripper column or phase separator. The resulting nitrogen and argon containing stream is separated and liquefied in a double column distillation system.

A system used to recycle exhaust gas during olefin polymer production, comprising: a compression cooling mechanism (101); a hydrocarbon membrane separation mechanism (102) and a hydrogen membrane separation mechanism (103), both connected to a first outlet (202) of the compression cooling mechanism; and a deep cooling mechanism (104) connected to a first outlet (208) of the hydrogen membrane separation mechanism. A method used to recycle exhaust gas during olefin polymer production, comprising a compression cooling step, a hydrocarbon membrane separation step, a hydrogen membrane separation step and a deep cooling step.

A method for vaporizing liquid propane to be supplied as a raw material to a naphtha cracking ractor. The method comprises: decompressing liquid propane to lower a vaporization point and vaporize at least a portion of the liquid propane; utilizing vaporization heat, generated during vaporization of the portion of liquid propane, as a refrigerant; compressing the vaporized propane gas to increase pressure of the propane gas and produce compressed propane gas; and preheating the compressed propane gas. By using this method, it is possible to reduce pressure of liquid propane to a significantly lower pressure than the related art method so that all the vaporization latent heat or vaporization heat included in liquid propane may be utilized as a refrigerant, while also reducing heat energy consumed in a preheat process before it is supplied to the naphtha cracking reactor.

In an aspect, the present disclosure provides a method for the oxidative coupling of methane to generate hydrocarbon compounds containing at least two carbon atoms (C.sub.2+ compounds). The method can include mixing a first gas stream comprising methane with a second gas stream comprising oxygen to form a third gas stream comprising methane and oxygen and performing an oxidative coupling of methane (OCM) reaction using the third gas stream to produce a product stream comprising one or more C.sub.2+ compounds.

A process for removing a foulant from a gas stream is disclosed. The gas stream, containing a foulant, is cooled across a first heat exchanger and a second heat exchanger, producing a solid foulant entrained in cryogenic liquid as a foulant slurry, and a foulant-depleted gas stream. The foulant-depleted gas stream is passed through a cryogenic turbine and a first separation vessel, producing a light gas stream and further solid foulant. The solid foulants are recovered by a combination of pressurization, melting, and distillation to produce a liquid foulant product. Heat is recovered from the various streams in the various heat exchangers and the melter.

A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream containing significant quantities of components more volatile than methane (hydrogen, nitrogen, etc.). The gas stream is partially condensed, then the remaining vapor is expanded to lower pressure and supplied to a fractionation tower at a mid-column feed position. The condensed liquid is cooled and divided into two portions. The first portion is expanded to tower pressure, heated by cooling the liquid, and supplied to the tower at a lower column feed position. The second portion is expanded to tower pressure and supplied to the tower at an upper mid-column feed position. A distillation vapor stream is withdrawn from the fractionation tower below the mid-column feed position and is heated, compressed to higher pressure, and cooled to substantial condensation before it is expanded and supplied to the tower as its top feed.

To provide a process for separating hydrocarbons capable of recovering ethane or propane, including improved cold heat recovery enabling a reduction in compressor power. A process for separating hydrocarbons, in which a residual gas enriched with methane or ethane and a heavy fraction enriched with a lower volatile hydrocarbon are separated, includes: a) partially condensing the feed gas by cooling using the residual gas and another refrigerant as a refrigerant, followed by vapor-liquid separation; b) depressurizing and supplying the liquid obtained from step (a) to the distillation column; c) expanding a part or all of the gas obtained from step (a) by an expander to cause partial condensation, followed by vapor-liquid separation; d) feeding the liquid obtained from step (c) to the distillation column after using it as the further refrigerant in step (a); e) feeding a part or all of the gas obtained from step (c) to the distillation column; and f) obtaining the residual gas from the top of the distillation column and the heavy fraction from the bottom of the distillation column.

Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

A system and process that are configured to prepare incoming hydrocarbon feedstocks for storage. For incoming ethane gas, the embodiments can utilize a plurality of vessels to distill the incoming feedstock to vapor and liquid ethane that is suitable for storage. The embodiments can direct the vapor to a demethanizer column that is downstream of the vessels and other components. The process can include stages for distilling an incoming feedstock at a plurality of vessels to form a vapor and a liquid for storage; directing the vapor to a demethanizer column; and circulating liquid from the demethanizer column back to the plurality of vessels.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a single heat exchanger, multiple gas-liquid separators, multiple expander/compressor sets, and a rectifier attached to a liquid product drum.