The present invention provides methods and system for power generation using a high efficiency combustor in combination with a CO.sub.2 circulating fluid. The methods and systems advantageously can make use of a low pressure ratio power turbine and an economizer heat exchanger in specific embodiments. Additional low grade heat from an external source can be used to provide part of an amount of heat needed for heating the recycle CO.sub.2 circulating fluid. Fuel derived CO.sub.2 can be captured and delivered at pipeline pressure. Other impurities can be captured.

A method for obtaining one or more air products, wherein an air separation system having a rectification column system is used, in which pressurized air is processed in an adjustable total air volume, wherein the total air volume is set to a first value during a first operating period and set to a second value that is different from the first value during a second operating period, and wherein the setting of the total air volume is changed from the first value to the second value in a third operating period from a first time to a second time. The second operating period is after the first operating period, the third operating period is between the first operating period and the second operating period. In the third operating period, a setting of a volume of a fluid, is changed from a third time up to a fourth time.

In a method for separating air by cryogenic distillation using a column system consisting of a higher pressure column operating at a first pressure and a lower pressure column operating at a second pressure, a first air flow constituting between 75% and 98% of the air sent to the column system compressed to a third pressure above the first pressure, is sent to the higher pressure column, a second air flow constituting between 5% and 25% of the air sent to the column system is compressed to a fourth pressure above the second pressure but lower than the third pressure, is sent to the lower pressure column, a third column separates an argon-enriched flow and the air sent to the lower pressure column constitutes between 10% and 25% of the total air sent to the column system.

The present disclosure relates to systems and methods useful for power production. In particular, a power production cycle utilizing CO.sub.2 as a working fluid may be combined with a second cycle wherein a compressed CO.sub.2 stream from the power production cycle can be heated and expanded to produce additional power and to provide additional heating to the power production cycle.

An apparatus and method for cooling a gas stream is provided comprising at least one heat exchanger in which a gas stream is cooled against a cooling liquid, whereby the cooling liquid temperature increases from a first temperature to a second temperature, at least one air cooler for cooling the cooling liquid after passing though the at least one heat exchanger, surface area of the at least one air cooler being designed to decrease temperature of the cooling liquid to the first temperature; a pump; and conduits to form a closed-circuit for the cooling liquid to pass continuously through the at least one heat exchanger and the at least one air cooler. The ratio of surface area of the at least one air cooler to the surface area of the at least one heat exchanger is optionally 12 or lower, and the difference of temperature between the second temperature and first temperature being greater than 15° C.

An apparatus and method for cooling a gas stream is provided comprising at least one heat exchanger in which a gas stream is cooled against a cooling liquid, whereby the cooling liquid temperature increases from a first temperature to a second temperature, at least one air cooler for cooling the cooling liquid after passing though the at least one heat exchanger, surface area of the at least one air cooler being designed to decrease temperature of the cooling liquid to the first temperature; a pump; and conduits to form a closed-circuit for the cooling liquid to pass continuously through the at least one heat exchanger and the at least one air cooler. The ratio of surface area of the at least one air cooler to the surface area of the at least one heat exchanger is optionally 12 or lower, and the difference of temperature between the second temperature and first temperature being greater than 15° C.

A nitrogen generating device comprises: a main heat exchanger; a nitrogen distillation column; at least one nitrogen condenser; a compressor; an expansion turbine; a rotation control unit for controlling rotation with respect to a rotating shaft connecting the compressor and the expansion turbine; a pressure measuring unit for measuring a pressure value of product nitrogen gas; and an optimum rotational speed calculation command unit which inputs the pressure value measured by the pressure measuring unit into a pre-installed rotational speed calculation function to calculate the rotational speed of the rotating shaft, and issues a command to the rotation control unit.

The present disclosure relates to systems and methods that provide power generation using predominantly CO.sub.2 as a working fluid. In particular, the present disclosure provides for the use of a portion of the heat of compression from a CO.sub.2 compressor as the additive heating necessary to increase the overall efficiency of a power production system and method.

An air separation device according to the present invention is an air separation device in which air is distilled at a low temperature, and includes a high-pressure column which separates high-pressure raw material air into high-pressure nitrogen gas and high-pressure oxygen-enriched liquefied air; a low-pressure column which separates the high-pressure oxygen-enriched liquefied air into low-pressure nitrogen gas, low-pressure liquefied oxygen, and argon-enriched liquefied oxygen; an argon column which separates the argon-enriched liquefied oxygen having a pressure higher than the pressure into argon gas and medium-pressure liquefied oxygen; a first indirect heat-exchanger which heat-exchanges between the argon gas and the low-pressure liquefied oxygen; a second indirect heat-exchanger which heat-exchanges between the high-pressure nitrogen gas and the medium-pressure liquefied oxygen; a first gas-liquid separation chamber which separates the low-pressure oxygen gas which has been vaporized by the first indirect heat-exchanger and the low-pressure liquefied oxygen which has not been vaporized; a second gas-liquid separation chamber which separates the medium-pressure oxygen gas which has been vaporized by the second indirect heat-exchanger and the medium-pressure liquefied oxygen which has not been vaporized; a first passage which communicates the gas phase of the low-pressure column and the gas phase of the second gas-liquid separation chamber; a second passage which communicates the liquid phase of the low-pressure column and the second gas-liquid separation chamber; a first opening/closing mechanism located on the first passage; and a second opening/closing mechanism located on the second passage.

A chiller can be configured as a chiller for a gasification system or other type of system or plant. In some embodiments, the chiller can be configured to utilize a single heat source, such as low grade waste heat in the form of hot water, and/or low pressure steam to drive one or more absorption-based chillers to cool inlet air to one or more adsorbers of a pre-purification unit (PPU). In the event of the detection of an undesired impurity spike (e.g. carbon dioxide spike, etc.) an additional amount of heat source can be withdrawn from the gasification system to increase the level of cooling the absorption chiller can provide to improve the removal of impurities. An automated control loop can be utilized in some embodiments. The control loop can be configured to check for an impurity concentration and adjust operations accordingly.